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材料导报  2026, Vol. 40 Issue (4): 24070182-7    https://doi.org/10.11896/cldb.24070182
  金属与金属基复合材料 |
冲刷速率与压力耦合作用对X70管线钢腐蚀行为的影响机制
覃祖安1, 任鹏炜1, 唐兴颖1,*, 朱日广1, 陈积权2
1 广西大学广西南海珊瑚礁研究重点实验室/珊瑚礁研究中心/海洋学院,南宁 530004
2 广西大学资源环境与材料学院,南宁 530004
Mechanism of Scouring Rate and Pressure Coupling on the Corrosion Behaviour of X70 Pipeline Steel
QIN Zu’an1, REN Pengwei1, TANG Xingying1,*, ZHU Riguang1, CHEN Jiquan2
1 Guangxi Laboratory on the Study of Coral Reefs in the South China Sea, Coral Reef Research Center of China, School of Marine Sciences, Guangxi University, Nanning 530004, China
2 School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China
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摘要 X70管线钢在深海的安全运行对海洋油气开发至关重要。自主设计并搭建了深海冲刷腐蚀反应装置,通过腐蚀失重实验、电化学测试、微观表征等测试方法,研究了深海环境(5 MPa)下X70管线钢的冲刷腐蚀行为以及耦合作用的腐蚀机制。结果表明,X70管线钢在压力与冲刷耦合作用下,其腐蚀形貌为均匀腐蚀与点蚀相结合,且随着冲刷速率的升高,阻抗值降低,抗腐蚀性降低;腐蚀产物主要为γ-FeOOH、β-FeOOH、α-Fe2O3与Fe3O4,高压促进腐蚀,加快腐蚀产物的整体生长,冲刷促进α-Fe2O3和γ-FeOOH生成,阻碍β-FeOOH生成;高压与低冲刷速率耦合产生削弱作用,与高冲刷速率耦合则呈现加强作用,该过程的临界冲刷速率为2.25 m/s,临界冲击能为0.762 J。揭示了不同冲刷速率与深海压力耦合作用下X70管线钢的腐蚀行为及影响机制,为海底管线钢的腐蚀防护与寿命预测提供数据支撑与理论指导。
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覃祖安
任鹏炜
唐兴颖
朱日广
陈积权
关键词:  X70管线钢  冲刷速率  压力  耦合作用  腐蚀行为    
Abstract: The safe operation of X70 pipeline steel in deep ocean environments is crucial for the development of offshore oil and gas resources. An experimental setup for simulating deep ocean scouring corrosion reactions was independently designed and constructed. Through weight-loss corrosion tests, electrochemical tests, and microscopic characterization, the scouring corrosion behavior of X70 pipeline steel under deep ocean conditions (5 MPa) and the corrosion mechanisms of their coupling effects were studied. The results show that under the combined effects of pressure and scouring, the corrosion morphology of X70 pipeline steel consists of a combination of uniform corrosion and pitting corrosion. As the scouring rate increases, the impedance value decreases, and the corrosion resistance deteriorates. The corrosion products are primarily γ-FeOOH, β-FeOOH, α-Fe2O3, and Fe3O4. High pressure promotes corrosion and accelerates the overall growth of corrosion products. Scouring promotes the formation of α-Fe2O3 and γ-FeOOH while inhibiting the formation of β-FeOOH. High pressure coupled with low scouring rate produces a weakening effect, while coupling with high scouring rate results in a strengthening effect. The critical scouring rate is 2.25 m/s, and the critical impact energy is 0.762 J. This study reveals the corrosion behavior and influencing mechanisms of X70 pipeline steel under different scouring rates and deep ocean pressure coupling, providing data support and theoretical guidance for the corrosion protection and lifespan prediction of subsea pipeline steel.
Key words:  X70 pipeline steel    scouring rate    pressure    coupling effect    corrosion behaviour
出版日期:  2026-02-25      发布日期:  2026-02-13
ZTFLH:  TG178  
基金资助: 国家自然科学基金(22068003)
通讯作者:  * 唐兴颖,博士,广西大学海洋学院讲师、硕士研究生导师。主要从事海洋材料腐蚀与防控技术方向的研究工作。tangxingying@gxu.edu.cn   
作者简介:  覃祖安,广西大学海洋学院硕士研究生,在唐兴颖讲师的指导下进行研究。目前主要研究领域为海洋材料腐蚀。
引用本文:    
覃祖安, 任鹏炜, 唐兴颖, 朱日广, 陈积权. 冲刷速率与压力耦合作用对X70管线钢腐蚀行为的影响机制[J]. 材料导报, 2026, 40(4): 24070182-7.
QIN Zu’an, REN Pengwei, TANG Xingying, ZHU Riguang, CHEN Jiquan. Mechanism of Scouring Rate and Pressure Coupling on the Corrosion Behaviour of X70 Pipeline Steel. Materials Reports, 2026, 40(4): 24070182-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24070182  或          https://www.mater-rep.com/CN/Y2026/V40/I4/24070182
1 Yang Z X, Kan B, Li J X, et al. Materials, 2017, 10(11), 1307.
2 Yang Z X, Kan B, Li J X, et al. International Journal of Hydrogen Energy, 2017, 42(44), 27446.
3 Yang Z X, Kan B, Li J X, et al. Journal of Electroanalytical Chemistry, 2018, 822, 123.
4 Sun F L, Ren S, Li Z, et al. Materials Science and Engineering A, 2017, 685, 145.
5 Li Q S, Luo S Z, Xing X T, et al. Acta Metallurgica Sinica-English Letters, 2019, 32(8), 972.
6 Xu C C, Zhu Y X, Liu W L, et al. Corrosion Engineering, Science, and Technology, 2021, 56(4), 383.
7 Islam M A, Farhat Z. Wear, 2017, 376, 533.
8 Al-Yasiri M, Al-Khateeb M, Wen D. Corrosion Engineering, Science, and Technology, 2018, 53(3), 183.
9 Zheng Q B, Zhang L Y, Jie X H, et al. International Journal of Electrochemical Science, 2017, 12(3), 2593.
10 Xu Y Z, Liu L, Xu C B, et al. Journal of Solid State Electrochemistry, 2020, 24(10), 2511.
11 Ren P W, Tang X Y, Qin Z A, et al. ACS Omega, 2022, 7(48), 440336.
12 Zhang Q L, Cui X, Zhou J, et al. Materials Protection, 2017, 50(4), 35 (in Chinese).
张秋利, 崔兴, 周军, 等. 材料保护, 2017, 50(4), 35.
13 Pan C C, Zhang X, Yang F, et al. Acta Metallurgica Sinica, 2022, 58(5), 599(in Chinese).
潘成成, 张翔, 杨帆, 等. 金属学报, 2017, 50(4), 35.
14 Gong K, Wu M, Liu G X. Construction and Building Materials, 2020, 235, 117440.
15 Wang S X, Liu D X, Du N, et al. International Journal of Electrochemical Science, 2016, 11(4), 2534.
16 Kiosidou E D, Karantonis A, Sakalis G N, et al. Corrosion Science, 2018, 137, 127.
17 Su H Y, Wei S C, Liang Y, et al. Chinese Journal of Engineering, 2019, 41(8), 1029 (in Chinese).
苏宏艺, 魏世丞, 梁义, 等. 工程科学学报, 2019, 41(8), 1029.
18 Su H Y, Liang Y, Wang Y J, et al. International Journal of Electroche-mical Science, 2019, 14(5), 4812.
19 Yamashita T, Hayes P. Applied Surface Science, 2008, 254(8), 2441.
20 Liu X D, Chen H, Liu S S, et al. Materials Research Bulletin, 2015, 62, 217.
21 Zhang Z. Preparation of β-FeOOH/Fe3O4/biochar photo-induced composite material and mechanism investigation of removal of azo dye. Master’s Thesis, Wuhan University of Science and Technology, China, 2021(in Chinese).
张政. β-FeOOH/Fe3O4/生物炭光致型复合材料的研制及脱除偶氮染料机理研究. 硕士学位论文, 武汉科技大学, 2021.
22 Han W, Pan C, Wang Z Y, et al. Corrosion Science, 2014, 88, 89.
23 Ma Y T, Li Y, Wang F H. Materials Chemistry and Physics, 2008, 112(3), 844.
24 Sun C Z, Zhou R F, Zhao Z X, et al. Chemical Physics Letters, 2021, 778, 138808.
25 Chen L J, Xu X H, Wei B. Pressure Vessel Technology, 2021, 38(1), 23(in Chinese).
陈丽娟, 徐向红, 魏博. 压力容器, 2021, 38(1), 23.
26 Lu B T, Luo J L. Tribology International, 2015, 83, 146.
27 Guo H X, Lu B T, Luo J L. Electrochimica Acta, 2006, 51(25), 5341.
28 Lu B T, Luo J L. Electrochimica Acta, 2010, 56(1), 559.
29 Aminul I M, Farhat Z N. Journal of Bio- and Tribo-Corrosion, 2015, 1(4), 26.
30 Liu K Z, Jiang W H, Chen W B, et al. Lubricants, 2022, 10(12), 345.
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