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材料导报  2024, Vol. 38 Issue (18): 23020095-8    https://doi.org/10.11896/cldb.23020095
  金属与金属基复合材料 |
海洋工程用铜镍合金的腐蚀与防护研究进展
韩秋丽1, 安士忠1,2,3,*, 宋克兴1,4,*, 刘海涛1,2,3, 周延军1,2,3, 程楚1,2,3, 张彦敏1,2,3
1 河南科技大学材料科学与工程学院,河南 洛阳 471023
2 有色金属新材料与先进加工技术省部共建协同创新中心,河南 洛阳 471023
3 河南省有色金属材料科学与加工技术重点实验室,河南 洛阳 471023
4 河南省科学院,郑州 450046
Research Progress on Corrosion and Protection of Copper-Nickel Alloys for Marine Engineering
HAN Qiuli1, AN Shizhong1,2,3,*, SONG Kexing1,4,*, LIU Haitao1,2,3, ZHOU Yanjun1,2,3,
CHENG Chu1,2,3, ZHANG Yanmin1,2,3
1 School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, Henan, China
2 Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology, Luoyang 471023, Henan, China
3 Henan Key Laboratory of Non-ferrous Materials Science& Processing Technology, Luoyang 471023, Henan, China
4 Henan Academy of Sciences, Zhengzhou 450046, China
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摘要 铜镍合金因具有良好的耐海水腐蚀性能、高的传热系数、优良的抗微生物附着性能和冷热加工性能,被广泛应用于船舶海水冷凝系统、滨海电厂的热交换器等海洋工程领域。本文围绕海洋工程用铜镍合金的腐蚀行为,首先概述了铜镍合金铸态、变形态及热处理的组织结构特点,接着归纳分析了合金元素、温度、pH值和硫离子对铜镍合金耐蚀性的影响,重点综述了合金化法、牺牲阳极法、缓蚀剂法、防腐涂料法和膜技术等铜镍合金耐蚀性的提升方法,最后展望了海洋工程用铜镍合金的发展趋势。
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韩秋丽
安士忠
宋克兴
刘海涛
周延军
程楚
张彦敏
关键词:  海洋工程  耐蚀铜合金  铜镍合金  腐蚀行为    
Abstract: Cu-Ni alloys are widely used in marine engineering fields such as marine water condensation systems, and heat exchangers of coastal power plants due to they have good corrosion resistance to seawater, high heat transfer coefficient, excellent anti-microbial adhesion performance and cold and hot processing performance. In this paper, the corrosion behavior of copper-nickel alloys used in marine engineering is reviewed. Firstly, the microstructure characteristics of copper-nickel alloys in as-cast, deformed and heat treated are summarized, and then the effects of alloying elements, temperature, pH and sulfur ions on the corrosion resistance of copper-nickel alloys are summarized and analyzed. The methods of improving the corrosion resistance of copper-nickel alloys such as alloying, sacrificial anode, corrosion inhibitor, anticorrosive coating and film technology are reviewed. Finally, the development trend of copper-nickel alloys for marine engineering is prospected.
Key words:  marine engineering    corrosion resistant copper alloys    copper-nickel alloys    corrosion behavior
发布日期:  2024-10-12
ZTFLH:  TG146.11  
基金资助: 国家自然科学基金(52071133)
通讯作者:  *安士忠,通信作者,河南科技大学材料科学与工程学院副教授。2009年北京航空航天大学材料科学与工程专业本科毕业,2014年北京航空航天大学信息功能材料专业博士毕业,2016年至今在河南科技大学材料科学与工程学院从事教学和科研工作。研究方向为磁、电及电化学功能材料。发表论文26篇,包括Journal of the American Chemical Society、Scripta Materialia、Rare Metals等;出版专著1部;授权国家发明专利10件、实用新型专利2件;参与制定国家标准2项。 宋克兴,通信作者,河南科技大学材料科学与工程学院教授、博士研究生导师。1989年毕业于重庆大学获学士学位,1997年毕业于洛阳工学院(现河南科技大学)获硕士学位,2005年毕业于西安交通大学获博士学位,第十四届全国人大代表,国家“万人计划”科技创新领军人才,国务院政府特殊津贴专家,教育部黄大年式教师团队带头人,科技部重点领域创新团队带头人,河南省中原学者,河南省科学院党委副书记、执行院长。目前主要从事高性能铜合金及先进制备加工技术的相关基础理论研究和技术开发工作。获国家科技进步二等奖2项、省部级一等奖5项;发表论文128篇,包括Acta Materialia、Scripta Materialia、JMST等;出版专著7部;授权发明专利65件;制定国家/行业标准7项、团体标准4项。anshizhong@sina.com;kxsong@haust.edu.cn   
作者简介:  韩秋丽,2021年6月于河南城建学院获得工学学士学位。现为河南科技大学材料科学与工程学院硕士研究生。目前主要研究领域为铜合金材料。
引用本文:    
韩秋丽, 安士忠, 宋克兴, 刘海涛, 周延军, 程楚, 张彦敏. 海洋工程用铜镍合金的腐蚀与防护研究进展[J]. 材料导报, 2024, 38(18): 23020095-8.
HAN Qiuli, AN Shizhong, SONG Kexing, LIU Haitao, ZHOU Yanjun,
CHENG Chu, ZHANG Yanmin. Research Progress on Corrosion and Protection of Copper-Nickel Alloys for Marine Engineering. Materials Reports, 2024, 38(18): 23020095-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23020095  或          http://www.mater-rep.com/CN/Y2024/V38/I18/23020095
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