具有光子晶体结构的电致变色器件的研究进展

doi:10.11896/cldb.23070230

材料导报

2024, Vol. 38

Issue (21): 23070230-13 https://doi.org/10.11896/cldb.23070230

无机非金属及其复合材料

具有光子晶体结构的电致变色器件的研究进展

俞朱敏, 李琳, 赵凯^*, 吴梦悦, 叶常青^*

苏州科技大学材料科学与工程学院,绿色印刷纳米光子工程技术研究中心,江苏苏州 215009

Research Progress of Electrochromic Devices with Photonic Crystal Structures

YU Zhumin, LI Lin, ZHAO Kai^*, WU Mengyue, YE Changqing^*

Research Center for Green Printing Nanophotonic Materials, School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China

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摘要光子晶体(Photonic crystals,PCs)是一种周期性排列有序的微结构材料,由于具有独特的周期结构、灵活的光调控能力等特点被广泛应用于电致变色(Electrochromicsm, EC)领域。具有光子晶体结构的电致变色器件可利用其产生的结构色与电致变色的化学色相结合,进而丰富和拓展器件的色域,为电致变色的色彩调控提供新的策略。此外,多维光子晶体结构可以为电致变色器件(Electrochromic devices, ECDs)提供有序离子传输通道和多离子活性反应位点,促进离子的注入/脱出,从而提升器件的电致变色性能。本文扼要介绍了评价电致变色材料与器件性能的参数,着重归纳了不同维度光子晶体在电致变色领域的应用策略,并详细总结了具有光子晶体结构的电致变色器件在智能窗、显示、伪装等领域的潜在应用。最后,针对目前光子晶体结构在电致变色领域中仍存在的问题,对其未来的发展趋势进行了展望。

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	俞朱敏
	李琳
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	叶常青

关键词: 光子晶体电致变色周期性结构结构色色域拓展

Abstract: Photonic crystals (PCs)are artificially ordered microstructure materials. In recent years, photonic crystals have been gradually used in the electrochromism (EC) field because of unique characteristics, such as continuous periodic structures, and the ability of light regulation. Electrochromism devices (ECDs) with photonic crystal structures can enrich the color gamut by combining photonic band gaps with electrochromism, which provides a novel way to adjust electrochromism color. In addition, multidimensional photonic crystals can provide ordered ion transport channels and rich ion-active reaction sites for electrochromic devices, thus promoting ion insertion/extraction and improving electrochromism performance. Herein, this paper firstly clarfies the performance parameters to evaluate electrochromism materials and devices and the manufacturing strategies of different dimensional photonic crystals in the electrochromism field. It summarized in detail the applications of electrochromism materials and devices with photonic crystal structures including smart windows, displays, and camouflage. It ends with a discussion on the limitations and prospects of photonic crystals in the field of electrochromism, and regarding problems existing in their development.

Key words: photonic crystal electrochromism periodic structure structural color gamut extension

出版日期: 2024-11-10 发布日期: 2024-11-11

ZTFLH:

TB332

基金资助: 国家自然科学基金 (51873145);江苏省自然科学基金优秀青年基金项目(BK20170065);江苏省自然科学基金青年项目(BK20230655);江苏省六大人才高峰项目(XCL-79);江苏省第五期333工程项目(BRA2018340);江苏省青蓝工程

通讯作者: *赵凯,苏州科技大学材料科学与工程学院讲师。2015年太原理工大学本科毕业,2022年大连理工大学博士毕业后到苏州科技大学工作至今。目前主要从事仿生结构色/光子晶体材料、光/电智能可穿戴器件的构筑等研究工作。在Chem. Eng. J.、Ind. Eng. Chem. Res.、Adv. Mater. Technol.等发表论文10余篇。zhaokai@usts.edu.cn;
叶常青,苏州科技大学材料科学与工程学院教授、硕士研究生导师。2007年南京大学本科毕业,2012年中国科学院化学所博士毕业后到苏州科技大学工作至今。目前主要从事光子晶体材料、上转换发光材料和柔性印刷光电器件应用等研究工作。发表论文100余篇,包括J. Am. Chem. Soc.、Angew. Chem. Int. Edit.、Energy Environ. Sci.等。yechangqing@mail.usts.edu.cn

作者简介: 俞朱敏,2021年6月于苏州科技大学获得工学学士学位。现为苏州科技大学材料科学与工程学院硕士研究生,在叶常青教授的指导下进行研究。目前主要研究领域为光子晶体结构电致变色材料与器件的制备及电致变色性能。

引用本文:

俞朱敏, 李琳, 赵凯, 吴梦悦, 叶常青. 具有光子晶体结构的电致变色器件的研究进展[J]. 材料导报, 2024, 38(21): 23070230-13.
YU Zhumin, LI Lin, ZHAO Kai, WU Mengyue, YE Changqing. Research Progress of Electrochromic Devices with Photonic Crystal Structures. Materials Reports, 2024, 38(21): 23070230-13.

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http://www.mater-rep.com/CN/10.11896/cldb.23070230 或 http://www.mater-rep.com/CN/Y2024/V38/I21/23070230

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