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材料导报  2024, Vol. 38 Issue (5): 22090259-10    https://doi.org/10.11896/cldb.22090259
  高分子与聚合物基复合材料 |
聚苯胺红外电致变色器件研究进展
陈渊泽, 牛春晖, 王雷*, 杨明庆, 张世玉, 吕勇
北京信息科技大学仪器科学与光电工程学院,北京 100192
Advances in Polyaniline Based Infrared Electrochromic Devices
CHEN Yuanze, NIU Chunhui, WANG Lei*, YANG Mingqing, ZHANG Shiyu, LYU Yong
School of Instrument Science and Optoelectronic Engineering, Beijing Information Science and Technology University, Beijing 100192, China
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摘要 电致变色是材料反射、吸收等光学性质在外加电场驱动下发生稳定、可逆变化的现象,在不同波段可表现为颜色、红外发射率等变化。红外电致变色器件(IR-ECDs)能够动态调节物体的红外光学特性,在自适应伪装、热管理等应用中受到广泛关注。作为最有代表性的有机电致变色材料,聚苯胺(PANI)制备方法简单,电化学性能优异,在多波段电致变色领域有着巨大的潜在应用价值。本文从电致变色器件结构出发,介绍了从可见电致变色到红外电致变色的原理和器件结构的演变,对近年来增强聚苯胺红外电致变色器件性能的策略和最新进展进行了归纳和分析,讨论了其多功能化应用的拓展方向,最后对所面临的挑战与未来的发展方向进行了总结与展望,为今后发展优异性能的IR-ECDs提供了参考,希望能够对本领域研究者有所启发,促进电致变色领域的发展。
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陈渊泽
牛春晖
王雷
杨明庆
张世玉
吕勇
关键词:  聚苯胺  红外  电致变色  器件结构  多功能    
Abstract: Electrochromism refers to the phenomenon of stable and reversible changes in the optical properties of materials under the driving of an external electric field. Electrochromism shows the changes of color, infrared emission rate etc. in different wavelength ranges. Infrared electrochromic devices (IR-ECDs) are capable of modulating the infrared optical properties of objects dynamically, and have received much attention in applications such as thermal management and adaptive camouflage. Polyaniline (PANI), as the most representative organic electrochromic material, has easy fabrication processes and excellent electrochemical properties. It has great potential application value in multi-band electrochromism. In this review, we first present the evolution of the device structures from visible electrochromism to infrared electrochromism. And then we summarize recent advances to improve PANI-based IR-ECDs performance in terms of different functional layers. The frontier applications of multifunctional IR-ECDs are discussed. Finally, the challenges of IR-ECDs are discussed and prospects for further development are proposed. This review provides a reference for the development of IR-ECDs with excellent performance. We hope it would be useful for researchers in this field to promote the development of the electrochromic field.
Key words:  polyaniline    infrared    electrochromism    device structure    multifunction
出版日期:  2024-03-10      发布日期:  2024-03-18
ZTFLH:  O649  
基金资助: 北京信息科技大学“勤信人才”培育计划 (QXTCP C202105);北京信息科技大学校基金 (2021XJJ11; 2021XJJ09)
通讯作者:  *王雷,北京信息科技大学仪器科学与光电工程学院副教授、硕士研究生导师。2017年北京理工大学博士毕业,随后于北京理工大学材料学院进行博士后研究,2020年9月加入北京信息科技大学仪器科学与光电工程学院,工作至今。目前主要从事光电材料与器件、量子点激光等方面的研究工作,发表论文20余篇,包括Science China Materials、J. Phys. Chem. Lett.、Opt. Mater. Express、Opt. Express等。 wanglei20202452@bistu.edu.cn   
作者简介:  陈渊泽,2020年于深圳大学获得工学学士学位。现为北京信息科技大学仪器科学与光电工程学院硕士研究生,在牛春晖教授的指导下进行研究。目前主要研究领域为电致变色有机材料的合成和应用。
引用本文:    
陈渊泽, 牛春晖, 王雷, 杨明庆, 张世玉, 吕勇. 聚苯胺红外电致变色器件研究进展[J]. 材料导报, 2024, 38(5): 22090259-10.
CHEN Yuanze, NIU Chunhui, WANG Lei, YANG Mingqing, ZHANG Shiyu, LYU Yong. Advances in Polyaniline Based Infrared Electrochromic Devices. Materials Reports, 2024, 38(5): 22090259-10.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22090259  或          http://www.mater-rep.com/CN/Y2024/V38/I5/22090259
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