Please wait a minute...
材料导报  2024, Vol. 38 Issue (7): 22090034-5    https://doi.org/10.11896/cldb.22090034
  高分子与聚合物基复合材料 |
聚醚接枝丙烯酸树脂基凝胶聚合物电解质的制备及在电致变色器件中的应用
王海萍, 陈必华, 陶益杰*, 黄凯兵, 张世国
湖南大学材料科学与工程学院,长沙 410082
Preparation of Polyether-connecting Acrylic Resin Base Gel Polymer Electrolyte and Its Application in Electric Discoloration Devices
WANG Haiping, CHEN Bihua, TAO Yijie*, HUANG Kaibing, ZHANG Shiguo
College of Materials Science and Engineering, Hunan University, Changsha 410082, China
下载:  全 文 ( PDF ) ( 5666KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 本工作以甲氧基聚乙二醇丙烯酸酯(PEGMEA)和聚氨酯丙烯酸树脂(PUA)为预聚体,离子液体1-丁基-3-甲基咪唑鎓双三氟甲磺酰亚胺盐(BMimTFSI)为添加剂,通过紫外光固化,构建了一种新型聚醚接枝丙烯酸树脂基凝胶聚合物电解质。通过傅里叶变换红外光谱(FTIR)、热重分析(TG)、紫外-可见吸收光谱(UV-Vis)和电化学测试(循环伏安)等方法对该凝胶聚合物电解质进行表征。结果表明,该类凝胶聚合物电解质不仅拥有优良的离子电导率,还具有高热稳定性、易封装和不易泄漏的优点。其中,BMimTFSI含量为59.5%(质量分数)、PUA/PEGMEA配比为4.96∶2.96(质量比)时凝胶聚合物的电解质综合性能最好,可见光透过率大于90%,热分解温度达到300 ℃,30 ℃时离子电导率达到2.17×10-5 S/cm。基于该类凝胶聚合物电解质的电致变色器件展现出优良的性能,经36 000 s循环后,依然保持着稳定的蓝色态—透明态切换,且着色、褪色态的可见光透过率对比度仍高达48%,电解质质地柔软,热稳定性良好,可应用于电致变色器件。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
王海萍
陈必华
陶益杰
黄凯兵
张世国
关键词:  紫外固化  凝胶电解质  聚氨酯  电致变色器件    
Abstract: In this work, a novel polyether grafted acrylic resin-based gel polymer electrolyte was prepared by UV curing with methoxy polyethylene glycol acrylate (PEGMEA) and polyurethane acrylic resin (PUA) as monomers and ionic liquid 1-butyl-3-methylimidazoliumbis (BMimTFSI) as additives. The gel polymer electrolyte was characterized by FTIR, TG, UV-Vis, and cyclic voltammetry. The results show that this kind of gel polymer electrolyte not only has excellent ionic conductivity but also has the advantages of high thermal stability, easy encapsulation, and non-lea-kage. Among them, the gel polymer electrolyte with BMimTFSI content of 59.5% and PUA/PEGMEA ratio of 4.96∶2.96 has the best comprehensive performance, the visible light transmittance of more than 90%, the thermal decomposition temperature of 300 ℃, and ionic conductivity of 2.17×10-5 S/cm at 30 ℃. Electrochromic devices based on this kind of gel polymer electrolyte show excellent performance. After 36 000 s, it still maintains color switching which is from a blue state to a transparent state, and the visible light transmittance contrast of colored and faded states is still as high as 48%. The electrolyte is soft and has good thermal stability. It can be applied to electrochromic devices.
Key words:  UV-cured    gel electrolyte    polyurethane    electric discoloration device
出版日期:  2024-04-10      发布日期:  2024-04-11
ZTFLH:  TB34  
基金资助: 国家自然科学基金(52003080; 21872046; 52072118)
通讯作者:  陶益杰,湖南大学材料科学与工程学院助理教授、硕士研究生导师。目前主要从事伪装隐身材料、电致变色材料等方面的研究工作。发表论文20余篇,包括Optics Express、Chemial Engineering Journal、Polymer等,主持国家自然科学基金、湖南省自然科学基金、173基础加强项目子课题等项目10余项。taoyijie@hnu.edu.cn   
作者简介:  王海萍,现为湖南大学材料科学与工程学院硕士研究生,在陶益杰助理教授、黄凯兵副教授的指导下进行研究。目前主要研究领域为光固化聚合物电解质、电致变色器件。
引用本文:    
王海萍, 陈必华, 陶益杰, 黄凯兵, 张世国. 聚醚接枝丙烯酸树脂基凝胶聚合物电解质的制备及在电致变色器件中的应用[J]. 材料导报, 2024, 38(7): 22090034-5.
WANG Haiping, CHEN Bihua, TAO Yijie, HUANG Kaibing, ZHANG Shiguo. Preparation of Polyether-connecting Acrylic Resin Base Gel Polymer Electrolyte and Its Application in Electric Discoloration Devices. Materials Reports, 2024, 38(7): 22090034-5.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.22090034  或          https://www.mater-rep.com/CN/Y2024/V38/I7/22090034
1 Li X B, Zhang L P, Xu G P, et al. Materials Reports, 2021, 35(10), 10171 (in Chinese).
李晓白, 张雷鹏, 徐高平, 等. 材料导报, 2021, 35(10), 10171.
2 Alesanco Y, Vinuales A, Tena-Zaera R. Materials (Basel), 2018, 11, 414.
3 Thakur V K, Ding G, Ma J, et al. Advanced Materials, 2012, 24, 4071.
4 Huang B, et al. RSC Advances, 2017, 7, 54391.
5 Bachman J C,Muy S, Grimaud A, et al. Chemical Reviews, DOI:10. 1021/acs. chemrev. 5b00563.
6 Danine A, Manceriu L, Rougier A. Electrochim Acta, 2017, 258, 200.
7 Zhou J, Wang J, Li H. Organic Electronics, 2018, 62, 516,
8 Hosseinioun A, Paillard E. Journal of Membrane Science, 2020, 594, 117456.
9 Zhang F, Guan X H, Ma X, et al. Acta Polymerica Sinica, 2015(7), 852.
张帆, 管兴华, 马晓燕, 等. 高分子学报, 2015(7), 852.
10 Yun T Y, Moon H C. Organic Electronics, DOI:10. 1016/j. orgel. 2018. 02. 018.
11 Xu C, Ma C, Kong X. Polymers for Advanced Technologies, 2009, 20, 178.
12 Li B, Xu X T, Zheng X Q. Materials Reports, 2018, 32(23), 4116.
李博, 徐晓婷, 郑雪晴. 材料导报, 2018, 32(23), 4116 .
13 Yang Z Y. Preparation and properties of UV-curing polyurethane acrylate matting material. Master’s Thesis, Taiyuan University of Technology, China, 2021 (in Chinese).
杨自远. 紫外光固化聚氨酯丙烯酸酯哑光材料的制备及性能研究. 硕士学位论文, 太原理工大学, 2021.
[1] 张文霞, 贾岩, 程海峰, 刘东青. 全固态电致变色器件研究进展[J]. 材料导报, 2025, 39(1): 24100119-11.
[2] 路正楠, 张鹏, 盛扬, 孙一新, MarkBradley, 张嵘. 鲁米诺自发光在聚氨酯光敏剂介导光动力治疗中的应用[J]. 材料导报, 2025, 39(1): 23110275-7.
[3] 阎格, 张慧娟, 蔡利海, 邵伟光, 刘文言. 燃料油与紫外光共同作用下热塑性聚氨酯结构与性能演变规律[J]. 材料导报, 2024, 38(6): 22050216-6.
[4] 郑孝源, 任志英, 吴乙万, 白鸿柏, 黄健萌, 谭桂斌. 金属橡胶-聚氨酯复合材料减振性能研究[J]. 材料导报, 2024, 38(6): 22050144-7.
[5] 唐建辉, 白银, 陈徐东, 张伟. 温度对水性聚氨酯-混凝土宏微观粘结特性的影响[J]. 材料导报, 2024, 38(4): 22060045-6.
[6] 刘宜娜, 杨荣杰, 冯文静, 王坤, 欧良, 陈兆恒, 陈昱隆. 聚氨酯软质泡沫制品阻燃性能检测分析[J]. 材料导报, 2024, 38(3): 22060066-4.
[7] 张超, 潘旺, 方宏远, 王娟, 王翠霞, 杜明瑞, 赵鹏, 王磊, 王复明. 聚氨酯泡沫注浆修复材料泡孔结构特征及抗压性能研究进展[J]. 材料导报, 2024, 38(3): 22070007-14.
[8] 刘世盟, 郭乃胜, 崔世超, 褚召阳, 赵近川. PDA/GO/PUF聚氨酯泡沫的力学与隔热性能及其微观机理[J]. 材料导报, 2024, 38(22): 23110080-9.
[9] 向顺成, 郑廷祥, 高英力, 史威, 蒋震, 何彦琪, 曾维. 聚氨酯改性聚羧酸盐的合成及与水泥净浆的相互作用[J]. 材料导报, 2024, 38(21): 23040167-7.
[10] 田小革, 李光耀, 陈功, 姚世林, 黄雪梅, 王俊杰, 陆劲州. TPU/Nano-ZnO复合改性沥青的性能研究及微观机制[J]. 材料导报, 2024, 38(16): 23050071-10.
[11] 王琦胜, 何发旺, 刘振国, 王经伟, 李红玉. 不同聚酯二元醇合成聚氨酯对导电银浆性能的影响[J]. 材料导报, 2024, 38(13): 22110234-6.
[12] 鲁雯雨, 宁志华, 彭焘, 陈海燕, 金延. 聚氨酯蘑菇状仿生微纤维的混合黏附破坏分析[J]. 材料导报, 2024, 38(10): 22120085-7.
[13] 安绍都, 邵伟光, 樊桂琪, 李万利, 王建超, 杨建雄, 蔡利海. 热塑性聚氨酯耐油抗紫外老化性能改进研究[J]. 材料导报, 2024, 38(10): 23020156-5.
[14] 刘亚豪, 王源升, 杨雪, 黄威, 李科, 王轩. 自修复聚氨酯材料的研究进展[J]. 材料导报, 2024, 38(1): 22050280-10.
[15] 冒海燕, 朱淼, 朱雪峰, 郭子怡, 廖成成, 何雪梅, 宋晓蕾. 基于刚果红的高分子染料制备及pH响应变色性能[J]. 材料导报, 2023, 37(9): 21040018-6.
[1] Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .
[2] Haoqi HU,Cheng XU,Lijing YANG,Henghua ZHANG,Zhenlun SONG. Recent Advances in the Research of High-strength and High-conductivity CuCrZr Alloy[J]. Materials Reports, 2018, 32(3): 453 -460 .
[3] Yanchun ZHAO,Congyu XU,Xiaopeng YUAN,Jing HE,Shengzhong KOU,Chunyan LI,Zizhou YUAN. Research Status of Plasticity and Toughness of Bulk Metallic Glass[J]. Materials Reports, 2018, 32(3): 467 -472 .
[4] Xinxing ZHOU,Shaopeng WU,Xiao ZHANG,Quantao LIU,Song XU,Shuai WANG. Molecular-scale Design of Asphalt Materials[J]. Materials Reports, 2018, 32(3): 483 -495 .
[5] Yongtao TAN, Lingbin KONG, Long KANG, Fen RAN. Construction of Nano-Au@PANI Yolk-shell Hollow Structure Electrode Material and Its Electrochemical Performance[J]. Materials Reports, 2018, 32(1): 47 -50 .
[6] Ping ZHU,Guanghui DENG,Xudong SHAO. Review on Dispersion Methods of Carbon Nanotubes in Cement-based Composites[J]. Materials Reports, 2018, 32(1): 149 -158 .
[7] Fangyuan DONG,Shansuo ZHENG,Mingchen SONG,Yixin ZHANG,Jie ZHENG,Qing QIN. Research Progress of High Performance ConcreteⅠ:Raw Materials and Mix Proportion Design Method[J]. Materials Reports, 2018, 32(1): 159 -166 .
[8] Guiqin HOU,Yunkai LI,Xiaoyan WANG. Research Progress of Zinc Ferrite as Photocatalyst[J]. Materials Reports, 2018, 32(1): 51 -57 .
[9] Jianxiang DING,Zhengming SUN,Peigen ZHANG,Wubian TIAN,Yamei ZHANG. Current Research Status and Outlook of Ag-based Contact Materials[J]. Materials Reports, 2018, 32(1): 58 -66 .
[10] Jing WANG,Hongke LIU,Pingsheng LIU,Li LI. Advances in Hydrogel Nanocomposites with High Mechanical Strength[J]. Materials Reports, 2018, 32(1): 67 -75 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed