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材料导报  2024, Vol. 38 Issue (15): 23050039-5    https://doi.org/10.11896/cldb.23050039
  金属与金属基复合材料 |
基于高磷铁矿制备Fe-P合金催化剂用于高效全解水反应
张华, 马帅帅, 张甜, 罗毅, 吴文洁, 任晓辉*, 刘涛, 倪红卫
武汉科技大学材料学部,耐火材料与冶金国家重点实验室,武汉 430081
Research on the Electrocatalytic Overall Water Splitting Performance of Fe-P Alloy Prepared by High-phosphate Iron Ore
ZHANG Hua, MA Shuaishuai, ZHANG Tian, LUO Yi, WU Wenjie, REN Xiaohui*, LIU Tao, NI Hongwei
The State Key Laboratory of Refractories and Metallurgy, Faculty of Materials, Wuhan University of Science and Technology, Wuhan 430081, China
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摘要 本工作首次报道了一种高磷铁矿协同纯Ca3(PO4)2熔融还原并结合单辊旋淬技术制备Fe-P合金带材催化剂的短流程冶金工艺,该工艺具有成本低、产品附加值高、易于工业化的优点。针对电催化析氢合金催化剂低成本高效制备难题,国内外学者进行了重点研究。因此,通过短流程冶金的方法制备Fe-P合金带材催化剂并将其用于电催化制氢(HER)领域,一方面降低了冶金过程中二氧化碳和其他大气污染物的排放,另一方面为冶金资源实现“大型化、清洁化、连续化、自动化”再利用平台搭建提供了指导方案,有望解决催化剂技术在发展中存在的"卡脖子"问题。
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张华
马帅帅
张甜
罗毅
吴文洁
任晓辉
刘涛
倪红卫
关键词:  高磷铁矿  Fe-P合金带材  电催化全解水  氢气  催化性能    
Abstract: Anovel strategy for the direct production of Fe-P alloy ribbon catalysts by smelting reduction of high-phosphate iron ore and apatite combined with single-roller melt-spinning technology was proposed. This short-metallurgical process demonstrates the advantages of low cost, high value-added and easy industrialization. Previous researches have been devoted to addressing the preparation of low-cost and efficient alloy-based catalysts for electrocatalytic hydrogen evolution (HER). Therefore, the preparation of Fe-P alloy ribbon catalysts through short-metallurgical process and their applications in the field of HER can not only reduce the emission of carbon dioxide and environment pollutants during the metallurgical process, but also provides a guidance to the construction of a ‘large-scale, clean, continuous, and automated’ reuse platform for metallurgical resources, which is highly expected to solve the ‘bottleneck’ problem in the development of catalyst technology.
Key words:  high-phosphate iron ore    Fe-P alloy ribbon    electrocatalytic overall water splitting    hydrogen    catalytic performance
出版日期:  2024-08-10      发布日期:  2024-08-29
ZTFLH:  TF64  
基金资助: 国家自然科学基金(52174217)
通讯作者:  * 任晓辉,武汉科技大学材料学部副教授、硕士研究生导师。2021年日本北海道大学综合化学院材料化学专业博士毕业后到武汉科技大学大学工作至今。主要从事低维材料光化学性质研究及过渡金属催化剂的研发工作,已发表学术论文60余篇,包括Advanced Energy Materials、 Advanced Functional Materials、 Applied Catalysis B:Environmental等材料科学领域国际知名期刊,累计引用次数达2 800余次。xhren@wust.edu.cn   
作者简介:  张华,2012年12月于武汉科技大学获得博士学位。现为武汉科技大学材料学部副主任、教授、博士研究生导师。目前主要研究领域为低碳冶金与洁净钢生产技术,在洁净钢生产、夹杂物控制及冶金数值模拟等方面做了大量的研究工作,完成了多项有关钢中非金属夹杂物控制方面的纵、横向科研课题,在夹杂物遗传特性及其调控方面发表文章200余篇。
引用本文:    
张华, 马帅帅, 张甜, 罗毅, 吴文洁, 任晓辉, 刘涛, 倪红卫. 基于高磷铁矿制备Fe-P合金催化剂用于高效全解水反应[J]. 材料导报, 2024, 38(15): 23050039-5.
ZHANG Hua, MA Shuaishuai, ZHANG Tian, LUO Yi, WU Wenjie, REN Xiaohui, LIU Tao, NI Hongwei. Research on the Electrocatalytic Overall Water Splitting Performance of Fe-P Alloy Prepared by High-phosphate Iron Ore. Materials Reports, 2024, 38(15): 23050039-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23050039  或          http://www.mater-rep.com/CN/Y2024/V38/I15/23050039
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