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材料导报  2024, Vol. 38 Issue (10): 23050035-9    https://doi.org/10.11896/cldb.23050035
  无机非金属及其复合材料 |
双极膜水解离性能改进研究进展
赵冬梅1,2,3, 赵有璟1,2, 王敏1,2,*
1 中国科学院青海盐湖研究所,盐湖资源绿色高值利用重点实验室,西宁 810008
2 青海省盐湖资源化学重点实验室,西宁 810008
3 中国科学院大学化学科学学院,北京 100049
Recent Progress in Modification of Bipolar Membranes Water Dissociation Performance
ZHAO Dongmei1,2,3, ZHAO Youjing1,2, WANG Min1,2,*
1 Key Laboratory of Green and Highly-end Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
2 Qinghai Provincial Key Laboratory of Resources and Chemistry of Salt Lakes, Xining 810008, China
3 School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
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摘要 双极膜因其独特的水解离性能、易与其他电化学技术集成等优势,在碳捕获、节能减排和资源综合利用等领域具有重要的应用。现有双极膜存在水解离效率低、选择渗透性和稳定性差等问题,严重制约其广泛应用,因此近年来,大量研究工作致力于提升双极膜水解离性能。本文从离子交换层性能优化、中间层催化剂及几何结构调控三方面,梳理了国内外双极膜水解离性能改进及优化策略,重点评述了水解离催化剂、膜结构调控规律等方面的研究进展,并对该领域面临的主要挑战和未来发展方向进行展望,以期为高水解离性能双极膜的开发提供借鉴,从而促进其在能源转化和资源再利用等领域的应用。
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赵冬梅
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王敏
关键词:  双极膜  离子交换层  中间层  水解离  催化剂  几何结构    
Abstract: Bipolar membrane is important for application in the fields of carbon capture, energy conservation, comprehensive utilization of resources, etc, due to its unique water dissociation properties and easy integration with other technologies. However, the existing bipolar membranes suffer from low water dissociation efficiency, poor selective permeability and stability, which severely limit the wide application. Therefore, a lot of research works have been carried out in recent years on the improvement of water dissociation performance. In this paper, the performances improvement and optimization strategies of bipolar membranes, have been reviewed from both domestic and international aspects including optimization of bipolar membrane ion exchange layers and interface layer catalyst and geometry control of bipolar membrane. The research progress of water dissociation catalysts, laws governing membrane structure were emphasized, providing outlook on the major challenges and future development directions in this field. The aim is to provide a reference for the development of bipolar membranes with high water dissociation performance, so as to promote their application in energy conversion and resource reuse.
Key words:  bipolar membrane    ion exchange layer    interface layer    water dissociation    catalyst    geometric structure
出版日期:  2024-05-25      发布日期:  2024-05-28
ZTFLH:  TB383  
基金资助: 国家自然科学基金(U20A20138);中国科学院“西部之光”人才培养计划
通讯作者:  *王敏,博士研究生导师,研究员,国务院政府“特殊津贴”、青海省“千人计划”领军人才,国家科技部专家。主持和参与完成国家重点研发、联合基金、工信部绿色制造等重大科技项目10余项。获中国科学院科技促进发展奖、中国专利优秀奖等奖项。目前主要从事盐湖战略资源有效提取与利用及熔盐储能等方面的研究工作。申请发明专利70余件,授权40余件,参与制定国家标准5项,团体标准1项;发表论文90余篇,其中SCI、EI收录40余篇。wangmin@isl.ac.cn   
作者简介:  赵冬梅,2013年7月毕业于中国科学院大学,现为中国科学院大学博士研究生。目前主要研究领域为离子交换膜材料制备与应用。
引用本文:    
赵冬梅, 赵有璟, 王敏. 双极膜水解离性能改进研究进展[J]. 材料导报, 2024, 38(10): 23050035-9.
ZHAO Dongmei, ZHAO Youjing, WANG Min. Recent Progress in Modification of Bipolar Membranes Water Dissociation Performance. Materials Reports, 2024, 38(10): 23050035-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23050035  或          http://www.mater-rep.com/CN/Y2024/V38/I10/23050035
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