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材料导报  2023, Vol. 37 Issue (24): 22060249-7    https://doi.org/10.11896/cldb.22060249
  无机非金属及其复合材料 |
YSZ多孔陶瓷的孔隙结构特征及压缩强度研究
李萌, 艾建平*, 胡丽玲, 程丽红, 帅亚萍, 罗司玲, 周泽华, 陈智琴, 李文魁
江西科技师范大学材料与机电学院,江西省材料表面工程重点实验室,南昌 330038
Study on Pore Structure and Compressive Strength of Porous YSZ Ceramics
LI Meng, AI Jianping*, HU Liling, CHENG Lihong, SHUAI Yaping, LUO Siling, ZHOU Zehua, CHEN Zhiqin, LI Wenkui
Jiangxi Key Laboratory of Materials Surface Engineering, School of Materials and Mechanical & Electrical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330038, China
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摘要 以3%(摩尔分数)Y2O3稳定的ZrO2为原料、异丁烯与马来酸酐共聚物(Isobam-104)为分散剂和凝胶剂、十二烷基三甲基氯化铵(DTAC)为发泡剂,采用球磨发泡法制备出氧化钇稳定的氧化锆(YSZ)多孔陶瓷。研究浆料固含量对YSZ多孔陶瓷制品孔隙结构和压缩强度的影响规律,以及压缩失效机制变化特点。结果表明:在相近发泡率的条件下,固含量在30.5%～33.5%(体积分数)范围内小幅度增加时,所制备的YSZ多孔陶瓷的总孔隙率和平均孔胞尺寸逐渐减小,压缩强度增加;所制备的样品的总孔隙率为79.9%～88.4%,压缩强度为4.7～17.2 MPa,材料的压缩强度与总孔隙率之间的关系同Rice模型相符合;在压缩载荷作用下YSZ多孔陶瓷呈现伪塑性变形,失效破坏的主要形式为剪切破坏。
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李萌
艾建平
胡丽玲
程丽红
帅亚萍
罗司玲
周泽华
陈智琴
李文魁
关键词:  氧化锆  多孔陶瓷  球磨发泡法  压缩失效机制    
Abstract: The porous YSZ ceramics were prepared by ball milling foam method using 3% (in mole) Y2O3 stabilized ZrO2 as a raw material, Isobam-104 as a dispersing and gel agent, dodecyl trimethyl ammonium chloride (DTAC) as a foaming agent and foam stabilizing. The effect of solid content on the microstructure, compressive strength and compressive failure mechanism of the porous YSZ ceramics was investigated. This result shows that the total porosity and the average cell size of as-prepared porous YSZ ceramics gradually decrease and the compressive strength increases when the solid content slightly increases in the range of 30.5vol%—33.5vol% under the similar foaming rate. The total porosity of as-prepared porous YSZ sample was 79.9%—88.4% and the compressive strength was 4.7—17.2 MPa. The relationship between the compressive strength and total porosity was consistent with Rice model. Porous YSZ ceramics exhibit pseudo-plastic deformation under compressive load. And the main failure mode is shear failure.
Key words:  zirconia    porous ceramics    ball milling foaming    compression failure mechanism
发布日期:  2023-12-19
ZTFLH:  TQ174  
基金资助: 国家自然科学基金(51862009);江西省自然科学基金(20202BABL204016;20212BAB204019); 江西省教育厅科技类重点项目(GJJ190585);江西科技师范大学研究生创新专项资金(YC2021-X04)
通讯作者:  *艾建平,江西科技师范大学材料与机电学院校聘教授、硕士研究生导师。2010年6月从湖南大学材料科学与工程学院专业本科毕业,2015年中国科学院上海硅酸盐研究所材料学专业博士毕业后到江西科技师范大学工作至今。目前主要从事多孔材料功能化设计及其催化领域应用、3D打印和分形理论模拟等方面的研究工作。发表论文20余篇,包括Ceramics International、《稀有金属材料与工程》《陶瓷学报》《硅酸盐学报》等,已申请专利6项,获授权发明专利2项。ai861027@163.com;1020151005@jxstnu.edu.cn   
作者简介:  李萌,2020年9月毕业于咸阳师范学院,获得理学学士学位。现为江西科技师范大学材料与机电学院硕士研究生。目前主要从事YSZ多孔陶瓷和氮化铝流延成型工艺研究。
引用本文:    
李萌, 艾建平, 胡丽玲, 程丽红, 帅亚萍, 罗司玲, 周泽华, 陈智琴, 李文魁. YSZ多孔陶瓷的孔隙结构特征及压缩强度研究[J]. 材料导报, 2023, 37(24): 22060249-7.
LI Meng, AI Jianping, HU Liling, CHENG Lihong, SHUAI Yaping, LUO Siling, ZHOU Zehua, CHEN Zhiqin, LI Wenkui. Study on Pore Structure and Compressive Strength of Porous YSZ Ceramics. Materials Reports, 2023, 37(24): 22060249-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22060249  或          http://www.mater-rep.com/CN/Y2023/V37/I24/22060249
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