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材料导报  2019, Vol. 33 Issue (2): 283-287    https://doi.org/10.11896/cldb.201902015
  金属与金属基复合材料 |
APS制备7YSZ热障涂层镀铝改性的抗氧化性
许世鸣1, 张小锋2, 刘敏1,2, 邓春明2, 邓畅光2, 牛少鹏2
1 中南大学材料科学与工程学院,长沙 410083
2 广东省新材料研究所,现代材料表面工程技术国家工程实验室及广东省现代表面工程技术重点实验室,广州 510650
Oxidation Resistance of Al-modified APS 7YSZ Thermal Barrier Coating
XU Shiming1, ZHANG Xiaofeng2, LIU Min1,2, DENG Chunming2, DENG Changguang2, NIU Shaopeng2
1 School of Materials Science and Engineering, Central South University, Changsha 410083
2 National Engineering Laboratory for Modern Materials Surface Engineering Technology & The Key Lab of Guangdong for Modern Surface Engineering Technology, Guangdong Institute of New Materials, Guangzhou 510650
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摘要 热障涂层(TBC)的使用对燃气轮机的寿命和效率都有明显提升,而TBC一般是由金属粘结层和ZrO2-7%(质量分数)Y2O3 (7YSZ) 陶瓷层组成。与飞行器推进系统的TBC相比,燃气轮机的服役环境有其特殊性。在工业燃气轮机服役过程中,TBC系统中金属粘结层的氧化是导致涂层过早失效最重要的原因之一。TGO(热生长氧化层)的形成不可避免,但抑制TGO的生长速率可以提高TBC的使用寿命,而7YSZ是一种对氧离子扩散几乎无阻碍作用的材料。因此,在7YSZ涂层上覆盖一层氧离子扩散障碍膜是阻止TGO生成的一种可行方法。本研究中,在7YSZ涂层表面沉积一层铝膜。经热处理后,在7YSZ涂层表面通过Al和ZrO2原位反应生成α-Al2O3层,该层可以作为氧离子扩散障碍层。此外,对热处理压力和铝改性的7YSZ涂层抗氧化性关系进行了研究。
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许世鸣
张小锋
刘敏
邓春明
邓畅光
牛少鹏
关键词:  铝改性热障涂层  氧化钇稳定氧化锆(7YSZ)涂层  抗氧化性  热生长氧化物    
Abstract: The use of TBC (thermal barrier coating) generally consisting of a 7YSZ (ZrO2-7wt%Y2O3) ceramic coating and a metallic bond coating has provided significant improvements in durability and efficiency for gas turbine engines to generate power, where the operation condition has its particularity compared with the TBC used in aircraft propulsion. During the service of industrial gas turbine engine, oxidation of metallic coating in TBC system is one of the most important failure factors leading to premature. Although TGO (thermally grown oxide) formation is inevitable, hindering grown rate of TGO contributes to prolong the operation lifetime of TBC. 7YSZ is a transparent material for oxygen ion diffusion. Thus, preparation of an oxygen ion diffusion barrier on 7YSZ surface is an alterative method for restraining TGO grown. In this investigation, an Al film was deposited on 7YSZ surface. After heat treatment, an α-Al2O3 layer was in situ synthesized on 7YSZ coating surface through the reaction of Al and ZrO2, where the formed α-Al2O3 overlay can act as an oxygen ion diffusion barrier. Moreover, the effect of heat treatment pressure on oxidation resistance for Al-modified 7YSZ TBC also had been investigated.
Key words:  Al-modified thermal barrier coating    yttria-stabilized zirconia(7YSZ) coating    oxidation resistance    thermally grown oxide
                    发布日期:  2019-01-31
ZTFLH:  TG178  
基金资助: 国家重点研究计划(2017YFB0306100); 广东省科学院项目 (2017GDASCX-0843;2017GDASCX-0202);广东省科技研究项目(2014B070706026);广东省自然科学基金 (2016A030312015;2017A030310315);广州市科技研究项目 (201605131008557;201707010385;201510010095)
作者简介:  许世鸣,2018年6月毕业于中南大学材料科学与工程学院,获得工程硕士学位。于2016年7月至2018年6月在广东省新材料研究所联合培养学习,主要从事热防护涂层的研究。刘敏,教授级高级工程师,博士生导师,现任广东省科学院副院长。liumin@gdas.gd.cn
引用本文:    
许世鸣, 张小锋, 刘敏, 邓春明, 邓畅光, 牛少鹏. APS制备7YSZ热障涂层镀铝改性的抗氧化性[J]. 材料导报, 2019, 33(2): 283-287.
XU Shiming, ZHANG Xiaofeng, LIU Min, DENG Chunming, DENG Changguang, NIU Shaopeng. Oxidation Resistance of Al-modified APS 7YSZ Thermal Barrier Coating. Materials Reports, 2019, 33(2): 283-287.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.201902015  或          http://www.mater-rep.com/CN/Y2019/V33/I2/283
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