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材料导报  2019, Vol. 33 Issue (4): 607-610    https://doi.org/10.11896/cldb.201904008
  无机非金属及其复合材料 |
凝胶-发泡法制备多孔Al2O3陶瓷及其力学性能
何秀兰,杜闫,巩庆东,郑威,柳军旺
哈尔滨理工大学材料科学与工程学院,哈尔滨 150040
Fabrication and Mechanical Properties of Porous Al2O3 Ceramics by Gel-foaming Process
HE Xiulan, DU Yan, GONG Qingdong, ZHENG Wei, LIU Junwang
School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150040
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摘要 以无毒琼脂糖为单体,十二烷基磺酸钠为发泡剂,MgO+TiO2为烧结助剂,利用凝胶注模及无压烧结工艺制备Al2O3多孔陶瓷。研究了发泡剂含量和固相含量对Al2O3多孔陶瓷显微结构和力学性能的影响规律以及琼脂糖凝胶体系的固化机理。结果表明:冷却过程中随温度下降,琼脂糖通过形成三维网状结构使陶瓷粉体原位固化;十二烷基磺酸钠具有较好的发泡性能及稳泡性能,适量的固相含量和发泡剂含量有助于制备高气孔率及适中抗压强度的多孔陶瓷;Al2O3多孔陶瓷的气孔率最高达到85.2%。
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何秀兰
杜闫
巩庆东
郑威
柳军旺
关键词:  氧化铝(Al2O3)多孔陶瓷  凝胶注模  琼脂糖  发泡剂  力学性能    
Abstract: Alumina porous ceramics were fabricated by gelcasting and pressureless sintering method by using agarose as monomer, sodium dodecyl sulfonate as foaming agent and MgO+TiO2 as sintering aids. The effects of different contents of foaming agent and solid phase on the microstructure and mechanical properties of Al2O3 porous ceramic were investigated. The curing mechanism of agarose gel system was also studied. The results showed that the formation of 3D network structure of agarose during cooling process causes the in-situ solidification of the raw ceramic powders. The sodium dodecyl sulfonate displays satisfactory foaming ability and foam stabilizing ability. The appropriate solid content and foaming agent content were beneficial to the fabrication of porous Al2O3 ceramics with high porosity and moderate compressive strength. The highest porosity of Al2O3 porous ceramic in this work reached 85.2%.
Key words:  alumina(Al2O3) porous ceramic    gelcasting    agarose    foaming agent    mechanical property
               出版日期:  2019-02-25      发布日期:  2019-03-11
ZTFLH:  TB34  
基金资助: 国家自然科学基金青年基金(51302053);哈尔滨市优秀学科带头人项目(2017RAXXJ078)
作者简介:  何秀兰,哈尔滨理工大学材料科学与工程学院,副教授,2011年10月毕业于哈尔滨工业大学,获工学博士学位。主要从事陶瓷基复合材料及多孔陶瓷材料的研究。在国内外期刊上发表文章20余篇。
引用本文:    
何秀兰, 杜闫, 巩庆东, 郑威, 柳军旺. 凝胶-发泡法制备多孔Al2O3陶瓷及其力学性能[J]. 材料导报, 2019, 33(4): 607-610.
HE Xiulan, DU Yan, GONG Qingdong, ZHENG Wei, LIU Junwang. Fabrication and Mechanical Properties of Porous Al2O3 Ceramics by Gel-foaming Process. Materials Reports, 2019, 33(4): 607-610.
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http://www.mater-rep.com/CN/10.11896/cldb.201904008  或          http://www.mater-rep.com/CN/Y2019/V33/I4/607
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