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材料导报  2023, Vol. 37 Issue (13): 21100209-10    https://doi.org/10.11896/cldb.21100209
  无机非金属及其复合材料 |
高性能新型Mg3(Sb,Bi)2基热电材料的发展现状
徐晨辉1,2, 孔栋1,2, 况志祥1,2, 陈卓1,2, 马燕1,2, 邹富祥1,2, 陈昕1,2, 胡晓明1,2, 冯波1,2, 樊希安1,2,*
1 武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室,武汉 430081
2 武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉 430081
Development of High Performance Mg3(Sb, Bi)2-based Thermoelectric Materials
XU Chenhui1,2, KONG Dong1,2, KUANG Zhixiang1,2, CHEN Zhuo1,2, MA Yan1,2, ZOU Fuxiang1,2, CHEN Xin1,2, HU Xiaoming1,2, FENG Bo1,2, FAN Xi'an1,2,*
1 Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China
2 The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
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摘要 热电材料能够实现热能与电能的相互转换,是一种可以应用于余热回收及半导体制冷等相关领域的功能性材料。传统热电材料的发展目前已趋于成熟,但仍然面临着高昂的原料成本及较低的热电转换效率等问题。Mg3(Sb,Bi)2基热电材料自被发现以来就以其低成本的元素组成和作为Zintl相具备的本征低热导率受到广泛关注。其中n型传导样品由于高能带简并度的优势更是有着较高的塞贝克系数,相较于传统中低温热电材料具备更大的发展潜力。然而,较大的带隙使得Mg3(Sb,Bi)2基热电材料载流子浓度整体偏低,同时还存在着由Mg空位引起的热稳定性较差的问题。为此,在保证该材料低热导率的同时,研究者们尝试了不同的制备工艺,并通过组分优化和结构优化来不断改善其电输运性能及热稳定性。目前Mg3(Sb,Bi)2基热电材料的最大ZT值已经达到1.8以上,同时其器件化后的热电转换效率也可媲美于传统Bi2Te3基热电器件。本文总结了Mg3(Sb,Bi)2基热电材料的基础物理性能与制备方法,从不同的优化手段出发依次介绍了现阶段该材料的研究成果,并展望了其在未来可行的发展方向。
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徐晨辉
孔栋
况志祥
陈卓
马燕
邹富祥
陈昕
胡晓明
冯波
樊希安
关键词:  热电材料  镁合金  Mg3(Sb,Bi)2  热电性能优化    
Abstract: Thermoelectric materials that convert electric energy and thermal energy are applied as functional materials in waste heat recovery and semiconductor refrigeration. Research on conventional thermoelectric materials has reached maturity; further development of such materials is hampered by the high cost of raw materials and low thermoelectric conversion efficiency. To overcome these limitations, Mg3(Sb, Bi)2Zintl phases have attracted extensive attention since their discovery and have been widely applied as thermoelectric materials because of their low cost and intrinsic low thermal conductivity. In addition, N-type Mg3(Sb, Bi)2-based conduction materials, having a high Seebeck coefficient owing to high energy band degeneracy, are hypothesized to be more effective than conventional medium- and low-temperature thermoelectric materials. However, the application of Mg3(Sb, Bi)2-based thermoelectric materials is limited because of the low carrier concentration caused by the large bandgap and the low thermal stability due to Mg vacancies. In addition to the maintenance of initial low thermal conductivity of such materials, researchers have continually tried to improve the electrical transport performance and thermal stability by employing different preparation processes and by conducting component and structure optimization. At present, the maximum ZT value of Mg3(Sb, Bi)2-based thermoelectric materials is above 1.8, and the conversion efficiency of the Mg3(Sb, Bi)2-based thermoelectric devices has been comparable to that of conventional low-temperature thermoelectric materials. This paper summarizes the physical properties and preparation methods of Mg3(Sb, Bi)2-based thermoelectric materials. The research progress on different optimization methods to prepare Mg3(Sb, Bi)2-based thermoelectric materials is discussed in detail, and possible future developments of the materials are presented.
Key words:  thermoelectric material    magnesium alloy    Mg3(Sb    Bi)2    optimization of thermoelectric performance
发布日期:  2023-07-10
ZTFLH:  TB34  
基金资助: 湖北省支持企业技术创新发展项目(QYJSCX2021000321);国家重点研发计划(SQ2020YFF0404755);湖北省“双创战略团队”项目(CYTDC2018000094);鄂州市科技计划项目(EZ01-001-20190001);湖北省自然科学基金青年项目(2021CFB009)
通讯作者:  *樊希安,武汉科技大学材料与冶金学院教授、博士研究生导师。1999年安徽工业大学钢铁冶金专业本科毕业,2004年昆明理工大学冶金物理化学专业硕士毕业,2007年华中科技大学材料学专业博士毕业,2009年从武汉理工大学材料复合新技术国家重点实验室博士后出站。目前主要从事热-电转换温差发电技术、磁-电能量转换技术、辐射换热技术及其关键新材料等方面的研究工作。发表论文100余篇,包括Journal of Materials Chemistry、Materials & Design、Journal of Physics D:Applied Physics、Journal of Alloys and Compounds、Ceramics International、Journal of Magnetism and Magnetic Materials等。groupfxa@163.com   
作者简介:  徐晨辉,2019年6月毕业于武汉科技大学,获得工学学士学位。现为武汉科技大学材料与冶金学院硕士研究生,在樊希安教授的指导下进行研究。目前主要研究领域为热电材料。
引用本文:    
徐晨辉, 孔栋, 况志祥, 陈卓, 马燕, 邹富祥, 陈昕, 胡晓明, 冯波, 樊希安. 高性能新型Mg3(Sb,Bi)2基热电材料的发展现状[J]. 材料导报, 2023, 37(13): 21100209-10.
XU Chenhui, KONG Dong, KUANG Zhixiang, CHEN Zhuo, MA Yan, ZOU Fuxiang, CHEN Xin, HU Xiaoming, FENG Bo, FAN Xi'an. Development of High Performance Mg3(Sb, Bi)2-based Thermoelectric Materials. Materials Reports, 2023, 37(13): 21100209-10.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21100209  或          http://www.mater-rep.com/CN/Y2023/V37/I13/21100209
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