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材料导报  2023, Vol. 37 Issue (7): 21080091-7    https://doi.org/10.11896/cldb.21080091
  高分子与聚合物基复合材料 |
地聚物在重金属铅固化中的研究进展
孙滢斐1,2,3, 张攀1, 胡敬平1, 杨家宽1, 侯慧杰1,*
1 华中科技大学环境科学与工程学院,武汉 430074
2 清华-伯克利深圳学院,广东 深圳 518055
3 清华大学深圳国际研究生院,广东 深圳 518055
Research Progress of Using Geopolymers to Solidify Lead Element from Lead-containing Pollutants
SUN Yingfei1,2,3, ZHANG Pan1, HU Jingping1, YANG Jiakuan1, HOU Huijie1,*
1 School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
2 Tsinghua-Berkeley Shenzhen Institute, Shenzhen 518055, Guangdong, China
3 Tsinghua Shenzhen International Graduate School, Shenzhen 518055, Guangdong, China
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摘要 地聚物作为一种新型的硅铝酸盐无机聚合胶凝材料,因具有耐酸、耐热、耐腐蚀和低能耗、低排放等优良性能而受到多领域的广泛关注,其中地聚物对重金属的固化作用成为重金属污染处理的新兴研究方向。在众多重金属中,地聚物对铅污染物的固化效果优异,引起学者的广泛关注。文章首先回顾了重金属污染的处理方法,提出了水泥基材料固化重金属铅存在的问题。其次,文章从地聚物对铅的固化机制及改性地聚物对铅的固化等方面,重点阐述了地聚物通过物理包封、电荷平衡作用、形成氧化物和/或硅酸盐等方式对铅的固化机理,并对影响地聚物固化铅的因素和地聚物固化铅性能表征方法进行了总结。最后,文章对地聚物在重金属铅固化方面的问题和展望进行了概述,为地聚物在铅固化中的研究提供参考。
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孙滢斐
张攀
胡敬平
杨家宽
侯慧杰
关键词:  地聚物  铅  重金属固化  硅铝酸盐  基质改性    
Abstract: As a novel type of aluminosilicate inorganic polymeric cementitious material, geopolymer has been widely utilized in many fields due to its excellent properties of acid resistance, heat resistance, corrosion resistance, low energy consumption and low emission. Emerging research field for heavy metal pollution control involves the solidification of heavy metals with geopolymers. The curing effect of geopolymer on lead conta-minants has attracted much attention due to its superior curing effect on lead compared to many other heavy metals. First, the paper reviewed strategies of heavy metal pollution control and addressed the limits of cement-based materials with regard to lead immobilization. Second, we thoroughly elaborated the mechanism of lead solidification and the immobilization of modified geopolymer to lead. Third, we covered the principal ways for lead solidification in geopolymer, such as physical encapsulation, charge balancing, and oxides and/or silicate formation. Moreover, we summarized factors affecting the solidification of lead by geopolymer and the characterization methods. Finally, we described the challenges and prospects of geopolymer for lead solidification and provided references for the study of geopolymers in lead solidification.
Key words:  geopolymer    lead    heavy metal solidification    aluminosillicate    matrix modification
出版日期:  2023-04-10      发布日期:  2023-04-07
ZTFLH:  TB321  
基金资助: 国家重点研发计划(2018YFC1900105)
通讯作者:  * 侯慧杰,华中科技大学教授、博士研究生导师,2003年7月于浙江大学光电信息工程学系获得工学学士学位;2006年3月于浙江大学光电信息工程学系获得工学硕士学位;2011年12月于美国德州农工大学电子及计算机工程学系获得工学博士学位。主要研究领域为固废处理处置及资源化、环境电化学在水环境污染治理及环境传感等。作为第一作者或通信作者发表论文42篇,主持国家自然科学基金面上项目2项、青年项目1项,湖北省自然科学基金项目1项,作为项目骨干成员参与国家重点研发计划。houhuijie@hust.edu.cn   
作者简介:  孙滢斐,2018年6月于青岛理工大学获得环境工程工学学士学位;2020年6月于华中科技大学获得环境工程工学硕士学位。现为清华-伯克利深圳学院、清华大学深圳国际研究生院博士研究生,在侯慧杰教授的指导下进行研究,主要研究领域为地聚物对重金属铅的固化。
引用本文:    
孙滢斐, 张攀, 胡敬平, 杨家宽, 侯慧杰. 地聚物在重金属铅固化中的研究进展[J]. 材料导报, 2023, 37(7): 21080091-7.
SUN Yingfei, ZHANG Pan, HU Jingping, YANG Jiakuan, HOU Huijie. Research Progress of Using Geopolymers to Solidify Lead Element from Lead-containing Pollutants. Materials Reports, 2023, 37(7): 21080091-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21080091  或          http://www.mater-rep.com/CN/Y2023/V37/I7/21080091
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