Please wait a minute...
材料导报  2024, Vol. 38 Issue (12): 23010150-5    https://doi.org/10.11896/cldb.23010150
  无机非金属及其复合材料 |
水泥回转窑过渡带用尖晶石-方镁石-铝酸钙耐火材料的制备
左斌, 尹洪峰*, 刘云, 辛亚楼, 刘宇驰, 袁蝴蝶*
西安建筑科技大学材料科学与工程学院,西安 710055
Preparation of Spinel-Periclase-Calcium Aluminate Refractory Used in Transitional Zone of Cement Rotary Kiln
ZUO Bin, YIN Hongfeng*, LIU Yun, XIN Yalou, LIU Yuchi, YUAN Hudie*
College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
下载:  全 文 ( PDF ) ( 23590KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 水泥回转窑过渡带由于难以结窑皮和所用耐火材料热导率较高,使得窑体表面温度高,散热损失大。本工作以菱镁矿、白云石和煅烧氧化铝为原料合成了尖晶石-铝酸钙复相轻量骨料,以此为颗粒,以烧结镁砂细粉为基质制备出尖晶石-方镁石-铝酸钙耐火材料。借助扫描电子显微镜、X射线衍射仪等手段研究了合成原料物相组成对耐火材料常温物理性能、荷重软化温度和抗水泥物料侵蚀性能的影响,结果表明:利用菱镁矿、白云石和煅烧氧化铝为原料在1 650 ℃保温4 h可以合成吸水率较低的尖晶石-铝酸钙复相轻量耐火原料。以合成尖晶石-铝酸钙复相材料为骨料可以制备出常温耐压强度较高的尖晶石-方镁石-铝酸钙耐火材料,其高强度得益于合成骨料与方镁石基质的良好结合。尖晶石-方镁石-铝酸钙耐火材料具有较好的抗水泥物料侵蚀性能,可用于水泥回转窑过渡带。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
左斌
尹洪峰
刘云
辛亚楼
刘宇驰
袁蝴蝶
关键词:  尖晶石-铝酸钙轻量骨料  尖晶石-方镁石-铝酸钙  水泥回转窑  抗侵蚀  显微结构    
Abstract: The transitional zone of cement rotary kiln has a high surface temperature and large heat dissipation loss due to the difficulty to form the kiln skin and the high thermal conductivity of the refractory used. In this work, spinel-calcium aluminate multiphase lightweight aggregates were synthesized from magnesite, dolomite and industrial alumina, and spinel-periclase-calcium aluminate refractories were fabricated by using synthesized materials as aggregate and sintered magnesia fine powder as the matrix. With the help of scanning electron microscope, X-ray diffractometer and other means, the effects of phase composition of synthetic raw materials on their physical properties at room temperature, refractoriness under load and corrosion resistance of cement materials were investigated. The results show that spinel-aluminate mulitiphase lightweight refractory materials with low water absorption can be synthesized by using magnesite, dolomite and alumina as raw materials fired at 1 650 ℃ for 4 h. The synthetic spinel-calcium aluminate multiphase material can be used as aggregate to prepare spinel-periclase-calcium aluminate refractory with higher compressive strength at room temperature due to thier good combination between synthetic aggregate and magnesia matrix. Spinel-periclase-calcium aluminate refractory can be used in the transition zone of cement rotary kiln due to its good corrosion-resistance to cement.
Key words:  spinel-calcium aluminate lightweight aggregate    spinel-periclase-calcium aluminate    cement rotary kiln    corrosion resistance    microstructure
出版日期:  2024-06-25      发布日期:  2024-07-17
ZTFLH:  TQ175.71  
基金资助: 国家自然科学基金(51572213)
通讯作者:  *尹洪峰,西安建筑科技大学材料与工程学院教授、博士研究生导师。目前主要从事耐火材料、陶瓷基复合材料、固体废弃物综合利用、功能复合材料等方面的研究工作。发表论文150余篇。yinhf01@163.com
袁蝴蝶,博士,西安建筑科技大学材料与工程学院高级实验师,2007年西安建筑科技大学材料物理专业本科毕业,2010年西安建筑科技大学矿物加工工程专业硕士毕业后留校工作,2020年西安建筑科技大学材料学专业博士毕业。目前从事结构功能一体化材料方面的研究工作,发表学术论文30余篇。yuanhudie@xauat.edu.cn   
作者简介:  左斌,2019年6月于西安建筑科技大学本科毕业。现为西安建筑科技大学材料科学与工程学院硕士研究生,在尹洪峰教授的指导下进行研究。目前主要研究领域为轻量化耐火材料。
引用本文:    
左斌, 尹洪峰, 刘云, 辛亚楼, 刘宇驰, 袁蝴蝶. 水泥回转窑过渡带用尖晶石-方镁石-铝酸钙耐火材料的制备[J]. 材料导报, 2024, 38(12): 23010150-5.
ZUO Bin, YIN Hongfeng, LIU Yun, XIN Yalou, LIU Yuchi, YUAN Hudie. Preparation of Spinel-Periclase-Calcium Aluminate Refractory Used in Transitional Zone of Cement Rotary Kiln. Materials Reports, 2024, 38(12): 23010150-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23010150  或          http://www.mater-rep.com/CN/Y2024/V38/I12/23010150
1 https://www.chyxx.com/shuju/202101/924688.html.
2 Shen W G,Liu Y,Yan B L,et al. Renewable and Sustainable Energy Reviews,2017,75,618.
3 Jiang J J,Ye B,Liu J G,et al. Renewable and Sustainable Energy Reviews,2019,112,813.
4 Wu W N,Liu X Y,Hu Z,et al. Journal of Cleaner Production,2019,224,132.
5 Madlool N A,Saidur R,Rahim N A,et al. Renewable and Sustainable Energy Reviews,2013,19,18.
6 Atmaca A,Yumrutas R. Applied Thermal Engineering,2014,66,435.
7 https://www.ccement.com/news/content/4358436769825.html.
8 Yuan L,Chen S L,Wang J T,et al. Refractories,2017,51(5),366 (in Chinese).
袁林,陈松林,王俊涛,等. 耐火材料,2017,51(5),366.
9 Yin H F,Xin Y L,Dang J L,et al. Ceramics International,2018,44,20478.
10 Ma B Y,Zhang Y Z,Gao Z,et al. Refractories,2021,55(2),169 (in Chinese).
马北越,张誉忠,高陟,等. 耐火材料,2021,55(2),169.
11 Ma B Y,Ren X M. Ceramics International,2022,48,35525.
12 Ren X M,Ma B Y,Tang J H,et al. Construction and Building Materials,2022,342,128097
13 Zou Y S,Gu H Z,Huang A,et al. Ceramics International,2021,47,11063.
14 Zou Y S,Gu H Z,Huang A,et al. Ceramics International,2020,46,16956.
15 Chen Q L,Yan W,Schafföner S,et al. Journal of the European Ceramic Society,2023,43,2654.
16 Zhao F,Ge T Z,Zhang L X,et al. Ceramics International,2020,46,4762.
17 Liu K,Ma B Y,Zhou P,et al. Journal of the Chinese Ceramic Society,2023,51(3),628 (in Chinese).
刘坤,马北越,周萍,等. 硅酸盐学报,2023,51(3),628.
18 Ma S B,Yan W,Schafföner S,et al. Ceramics International,2017,43,17026.
19 Yin H F,Gao K,Wan Q F,et al. Ceramics International,2021,47(15),21310.
20 Yan J J,Dai Y J,Yan W,et al. Journal of the European Ceramic Society,2022,42,7648.
[1] 陈爽, 韦丽兰, 陈红梅, 关纪文. 海洋环境下BFRP筋增强珊瑚混凝土柱抗侵蚀性能[J]. 材料导报, 2024, 38(9): 22110088-10.
[2] 何思瑶, 魏闯, 康鑫, 李素平. 锂辉石含量对煅烧钴酸锂正极材料用匣钵材料性能的影响[J]. 材料导报, 2023, 37(22): 22040351-6.
[3] 陈该青, 刘凯, 徐幸, 吴瑛, 肖勇. 泡沫Ni/In-48Sn复合焊料钎焊Al合金接头显微结构及力学性能研究[J]. 材料导报, 2023, 37(17): 22100141-6.
[4] 石永恒, 芶立. 晶核剂对CMAS系微晶玻璃结构和性能的影响[J]. 材料导报, 2021, 35(5): 5027-5031.
[5] 贺文志, 邓承继, 丁军, 余超, 王杏, 祝洪喜. 多孔Mo2C/C复合陶瓷材料的制备及吸附性能[J]. 材料导报, 2021, 35(24): 24052-24056.
[6] 王杏, 陈洋, 曹桂莲, 邓承继, 丁军, 余超, 祝洪喜. 氮化温度对MgO-C耐火材料结构和性能的影响[J]. 材料导报, 2021, 35(12): 12053-12056.
[7] 刘显刚, 安建成, 孙佳佳, 张骞, 秦艳濛, 刘新红. 化学气相沉积法制备SiC纳米线的研究进展[J]. 材料导报, 2021, 35(11): 11077-11082.
[8] 尹雪亮, 刘洋, 李丽颖, 宫长伟, 杜成武, 毛榜玉, 彭可武. 添加ZrO2对CaAl4O7材料烧结的影响[J]. 材料导报, 2020, 34(Z1): 144-147.
[9] 李萌, 杨成博, 张静, 郑开宏. 轻质高熵合金的研究现状[J]. 材料导报, 2020, 34(21): 21125-21134.
[10] 石亮, 谢德擎, 王学明, 袁俊, 穆松, 魏鹏, 朱梦伟. 抗侵蚀抑制剂对混凝土吸水性能及抗盐结晶性能的影响[J]. 材料导报, 2020, 34(14): 14093-14098.
[11] 张庆, 侯德华, 史纪村. 橡胶沥青的微观表征方法及其微观特性综述[J]. 材料导报, 2019, 33(Z2): 247-253.
[12] 李红霞, 李保卫, 邓磊波, 徐鹏飞, 刘中兴. 微波热处理温度对尾矿微晶玻璃晶化过程及性能的影响[J]. 材料导报, 2019, 33(20): 3401-3407.
[13] 易帅, 曾鲁举, 邓丽娜, 薛飞, 谢金莉, 刘艳改, 房明浩, 吴小文, 黄朝晖. 液相浸渗法制备CaAl12O19/(MgAl2O4-Al2O3)复相陶瓷[J]. 材料导报, 2019, 33(18): 3166-3169.
[14] 薛宗伟, 李心慰, 栾旭, 罗旭东, 徐若梦, 吴锋. 纳米氧化锆对氧化镁陶瓷抗热震性的影响[J]. 材料导报, 2019, 33(10): 1630-1633.
[15] 尹雪亮, 陈敏, 王楠, 徐磊, 彭可武. Y2O3添加对MA-CA2-CA6复合材料烧结行为的影响[J]. 《材料导报》期刊社, 2018, 32(8): 1357-1361.
[1] Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[2] Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[3] Congshuo ZHAO,Zhiguo XING,Haidou WANG,Guolu LI,Zhe LIU. Advances in Laser Cladding on the Surface of Iron Carbon Alloy Matrix[J]. Materials Reports, 2018, 32(3): 418 -426 .
[4] Huaibin DONG,Changqing LI,Xiahui ZOU. Research Progress of Orientation and Alignment of Carbon Nanotubes in Polymer Implemented by Applying Electric Field[J]. Materials Reports, 2018, 32(3): 427 -433 .
[5] Xiaoyu ZHANG,Min XU,Shengzhu CAO. Research Progress on Interfacial Modification of Diamond/Copper Composites with High Thermal Conductivity[J]. Materials Reports, 2018, 32(3): 443 -452 .
[6] Anmin LI,Junzuo SHI,Mingkuan XIE. Research Progress on Mechanical Properties of High Entropy Alloys[J]. Materials Reports, 2018, 32(3): 461 -466 .
[7] Qingqing DING,Qian YU,Jixue LI,Ze ZHANG. Research Progresses of Rhenium Effect in Nickel Based Superalloys[J]. Materials Reports, 2018, 32(1): 110 -115 .
[8] Yaxiong GUO,Qibin LIU,Xiaojuan SHANG,Peng XU,Fang ZHOU. Structure and Phase Transition in CoCrFeNi-M High-entropy Alloys Systems[J]. Materials Reports, 2018, 32(1): 122 -127 .
[9] Changsai LIU,Yujiang WANG,Zhongqi SHENG,Shicheng WEI,Yi LIANG,Yuebin LI,Bo WANG. State-of-arts and Perspectives of Crankshaft Repair and Remanufacture[J]. Materials Reports, 2018, 32(1): 141 -148 .
[10] Xia WANG,Liping AN,Xiaotao ZHANG,Ximing WANG. Progress in Application of Porous Materials in VOCs Adsorption During Wood Drying[J]. Materials Reports, 2018, 32(1): 93 -101 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed