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材料导报  2024, Vol. 38 Issue (3): 22040272-6    https://doi.org/10.11896/cldb.22040272
  无机非金属及其复合材料 |
ZnIn2S4基光催化剂的制备及改性研究进展
李冠琼1,2, 梁海欧1,2, 李春萍1,2, 白杰1,2,*
1 内蒙古工业大学化工学院,呼和浩特 010051
2 内蒙古工业催化重点实验室,呼和浩特 010051
Research Progress on Preparation and Modification of ZnIn2S4-based Photocatalyst
LI Guanqiong1,2, LIANG Haiou1,2, LI Chunping1,2, BAI Jie1,2,*
1 Collage of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China
2 Inner Mongolia Key Laboratory of Industrial Catalysis, Hohhot 010051, China
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摘要 近年来,硫锌铟(ZnIn2S4)作为层状结构的三元金属硫化物,是一种典型的可见光响应光催化剂,由于其无毒,易于合成,具有可调的带隙、较好的物理化学稳定性以及优异的光催化活性等一系列优势,一度被应用于光催化的不同领域。本文着眼于ZnIn2S4的晶体结构和生长机理,综述了ZnIn2S4常用的制备工艺。此外,基于ZnIn2S4存在的弊端,总结了提高ZnIn2S4光催化性能的各种调控策略,包括形貌和结构工程、空位工程、掺杂工程以及半导体异质结的构建,并深入分析了不同调控方式对ZnIn2S4光催化性能增强的内在原因。最后,提出ZnIn2S4基光催化剂目前面临的挑战和未来的应用前景。
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李冠琼
梁海欧
李春萍
白杰
关键词:  ZnIn2S4  制备工艺  改性策略  光催化    
Abstract: In recent years, as the ternary metal sulfide with the layered structure, sulfur zinc indium (ZnIn2S4) is a typical visible light responsive photocatalyst. Due to a series of advantages such as non-toxic, easy synthesis, adjustable band gap, good physicochemical stability and good photocatalytic activity, it has been used in different fields of photocatalysis. This paper focuses on the crystal structure and growth mechanism of ZnIn2S4, and summarizes the common preparation processes of ZnIn2S4. In addition, based on the disadvantages of ZnIn2S4, various modification strategies to improve the photocatalytic performance of ZnIn2S4 are also summarized, including morphology and structure engineering, vacancy engineering, doping engineering and semiconductor heterojunction construction. And intrinsic reasons for the enhancement photocatalytic performance of ZnIn2S4 by different modification methods are analyzed deeply. Finally, present challenges and future application prospects of ZnIn2S4 based photocatalyst are proposed.
Key words:  ZnIn2S4    preparation methods    modification strategy    photocatalytic
出版日期:  2024-02-10      发布日期:  2024-02-19
ZTFLH:  O643  
基金资助: 国家自然科学基金(51772158)
通讯作者:  *白杰,内蒙古工业大学化工学院教授、博士研究生导师。2003年7月本科毕业于内蒙古师范大学化学系,2008年7月在吉林大学化学学院有机合成专业,获得博士学位。目前主要从事碳纤维基纳米复合催化剂的制备与催化性能研究;分子筛基复合催化剂的制备研究;一维功能纳米材料的制备与性能研究;可见光响应型纳米复合光催化材料的开发。先后公开发表研究论文40余篇,包括Journal of Catalysis、Inorganic Chemistry Frontiers、Organic Chemistry Frontiers、Chemical Engineering Journal等。baijie@imut.edu.cn   
作者简介:  李冠琼,2020年毕业于内蒙古工业大学,获得工学硕士学位。现为内蒙古工业大学化工学院在读博士研究生,在白杰教授的指导下进行研究。目前主要研究领域为光催化分解水制氢材料。
引用本文:    
李冠琼, 梁海欧, 李春萍, 白杰. ZnIn2S4基光催化剂的制备及改性研究进展[J]. 材料导报, 2024, 38(3): 22040272-6.
LI Guanqiong, LIANG Haiou, LI Chunping, BAI Jie. Research Progress on Preparation and Modification of ZnIn2S4-based Photocatalyst. Materials Reports, 2024, 38(3): 22040272-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22040272  或          http://www.mater-rep.com/CN/Y2024/V38/I3/22040272
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