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材料导报  2024, Vol. 38 Issue (2): 22050182-8    https://doi.org/10.11896/cldb.22050182
  高分子与聚合物基复合材料 |
废机油残留物再生剂对老化沥青动态力学性能和组分迁移的影响
况栋梁1, 马小军1,2, 马晓燕1,*, 袁斌3, 侯俊鹏1, 蔡军4
1 长安大学材料科学与工程学院,西安 710064
2 青海交通规划设计研究院有限公司,西宁 810000
3 甘肃路桥集团养护科技有限公司,兰州 730050
4 青海西互高速公路管理有限公司,西宁 810000
Effect of Waste Oil Residue Regenerators on Dynamic Mechanical Properties and Component Migration of Aged Asphalt
KUANG Dongliang1, MA Xiaojun1,2, MA Xiaoyan1,*, YUAN Bin3, HOU Junpeng1, CAI Jun4
1 School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China
2 Qinghai Transportation Planning and Design Institute Co., Ltd., Xining 810000, China
3 Gansu Road and Bridge Construction Group Maintenance Technology Co., Ltd., Lanzhou 730050, China
4 Qinghai Xihu Highway Management Co., Ltd., Xining 810000, China
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摘要 目前,再生沥青的研究主要集中在老化沥青性能的恢复上,而对老化后再生沥青性能变化的研究较少。本研究以自制的两种废机油残留物再生剂(REOB1、REOB2)对老化基质沥青进行再生,并对再生沥青进行短期老化(TFOT)和长期老化(PAV)。采用动态剪切流变仪(DSR)和薄层棒状色谱仪(TLC-FID)分析再生沥青及其老化后的动态力学性能和化学组分变化情况。结果表明,两种REOB再生剂均能使老化基质沥青的性能恢复至原样沥青水平,并且REOB2再生剂与老化基质沥青的相容性优于REOB1再生剂;采用CAM模型对沥青复数模量、相位角主曲线进行拟合,并以原样沥青主曲线为参考,对老化与再生沥青拟合数据进行归一化处理,发现两种REOB再生剂均可以恢复老化基质沥青的复数模量和相位角。在二次老化过程中,RA+REOB再生沥青的归一化复模量指标(NCMI)在低频和中频范围内逐渐增大,即使经过长期老化,其复模量仍低于长期老化的基质沥青;而归一化相角指标(NPAI)在中频范围内的下降幅度明显大于低频范围和高频范围内的下降幅度,RA+REOB1再生沥青经过PAV老化后的NPAI低于长期老化后的基质沥青;随着老化程度的加深,RA+REOB再生沥青的化学组分从芳烃组分向胶质迁移,REOB1再生沥青经PAV老化后轻组分损失最大。
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况栋梁
马小军
马晓燕
袁斌
侯俊鹏
蔡军
关键词:  道路工程  再生沥青  再生剂  二次老化  动态力学性能  化学组分    
Abstract: The study of recycled asphalt is currently primarily focused on the recovery of aging asphalt properties, with little attention paid to the aging of recycled asphalt. In this study, two types of recycled engine oil bottom (REOB1 and REOB2) were used to regenerate the aged matrix asphalt, and short-term (TFOT) and long-term (PAV) aging were performed on the recycled asphalt. The dynamic mechanical properties and chemical component changes of recycled asphalt and its aged condition were evaluated using the dynamic shear rheometer (DSR) and the thin layer chromatography-flame ionization detector (TLC-FID). The results show that both REOB regenerants can restore the performance of aging matrix asphalt to that of the original asphalt, and that REOB2 regenerant is more compatible with aging matrix asphalt than REOB1 regenerant;the complex modulus and phase angle of the aging matrix asphalt could be retrieved by both REOB regenerants, according to master curve fitting with the CAM model and normalization of the fitting data. During the secondary aging process, the normalized complex modulus index (NCMI) of RA+REOB reclaimed asphalt gradually increases in the low and medium frequency range, and even after long-term aging, its complex modulus is still lower than that of long-term aging matrix asphalt. The normalized phase angle index (NPAI) in the middle frequency range is significantly higher than in the low and high frequency ranges, and the NPAI of the RA+REOB1 recycled asphalt after PAV aging is lower than the matrix asphalt after long-term aging. The chemical components of the RA+REOB recycled asphalt migrate from the aromatic components to the resins as the aging degree increases, and the REOB1 reclaimed asphalt loses the most light components after PAV aging.
Key words:  road engineering    regenerated asphalt    rejuvenator    secondary aging    dynamic mechanical property    chemical component
出版日期:  2024-01-25      发布日期:  2024-01-26
ZTFLH:  U414  
基金资助: 青海省科技厅重点研发与转化计划项目(2021-SF-165);中国博士后面上基金项目(2020M683401);陕西省自然科学基金项目(2021JQ-262);中央高校基金项目(300102311402);国家自然科学基金(52208417)
通讯作者:  *马晓燕,长安大学材料科学与工程学院讲师。2008年南京林业大学土木工程专业本科毕业,2012年长安大学材料学硕士研究生毕业,2012—2015年在甘肃路桥集团养护科技有限公司担任研发中心主任,2019年长安大学道路材料科学与工程专业博士毕业,2020年至今在长安大学公路学院进行博士后研究。目前主要从事道路建筑材料和多尺度沥青材料结构和力学性能的计算。发表论文20余篇,包括Journal of Materials in Civil Engineering、Construction and Building Materials、《材料导报》等。xiaoyanma@chd.edu.cn   
作者简介:  况栋梁,长安大学材料科学与工程学院教授、博士研究生导师。2004年武汉理工大学化学工程与工艺专业本科毕业,2012年武汉理工大学复合材料学专业博士毕业。目前主要从事沥青材料改性与评价、固体废弃物高质化制备道路材料与高性能绿色铺装技术研究。发表论文50余篇,包括Construction and Building Materials、《中国公路学报》等。
引用本文:    
况栋梁, 马小军, 马晓燕, 袁斌, 侯俊鹏, 蔡军. 废机油残留物再生剂对老化沥青动态力学性能和组分迁移的影响[J]. 材料导报, 2024, 38(2): 22050182-8.
KUANG Dongliang, MA Xiaojun, MA Xiaoyan, YUAN Bin, HOU Junpeng, CAI Jun. Effect of Waste Oil Residue Regenerators on Dynamic Mechanical Properties and Component Migration of Aged Asphalt. Materials Reports, 2024, 38(2): 22050182-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22050182  或          http://www.mater-rep.com/CN/Y2024/V38/I2/22050182
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