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材料导报  2021, Vol. 35 Issue (Z1): 378-380    
  金属与金属基复合材料 |
钴的相变织构及微观结构研究
王书明1, 张华2, 左玉婷1, 曹瑞军3
1 国标(北京)检验认证有限公司 北京 100088
2 中国有色金属工业协会再生金属分会,北京 100037
3 北京有色金属研究总院工程技术研究院,北京 650106
Study on Texture and Microstructure of Co During Phase Transformation
WANG Shuming1, ZHANG Hua2, ZUO Yuting1, CAO Ruijun3
1 Guobiao (Beijing) Testing & Certification Co., Ltd, Beijing 100088, China
2 China Nonferrous Metals Industry Associaton Recycling Metal Branch, Beijing 100037, China
3 General Research Institute for Nonferrous Metals, Beijing 650106, China
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摘要 本研究以纯钴为参考试样,通过原位X射线衍射、扫描电镜显微镜及背散射电子衍射技术,系统分析了相变温度、相变组织微观形貌及取向的变化,探讨了钴的相变及影响因素。结果显示,Co相变需要较大的过冷度,其As点约400 ℃,Af点约500 ℃,Ms点约350 ℃,Mf点低于室温,主要原因是相变热焓难以克服较大的界面能和应变能。各向异性线应变的累积促使晶内形成平行于{0002}β切变面的片层组织,同时促使变体选择随机,织构强度弱化。但难以消除的体应变(约0.6%)促使晶内形成70°〈1120〉的板片状及90°〈1120〉的楔形孪生组织。
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王书明
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曹瑞军
关键词:    相变  应变  片层组织  孪生    
Abstract: The phase transformation temperature, microstructure and texturein pure Co block were analyzed using in situ X-ray diffraction (XRD), scanning electron microscope (SEM) and electron backscattering diffraction(EBSD) in the paper. The results showed that, As was about 400 ℃, Af was about 500 ℃, Ms was about 350 ℃, and Mf was below room temperature. The more undercooling degree and longer duration were needed during α→β phase transformation could be deduced. The main reason was the thermal enthalpy could not satisfy the interface and strain energy. Lamellar structure parallel to {0002}β formed as the stacking fault and anisotropy line strain. Meanwhile, the 70°〈1120〉 lath and 90°〈1120〉 wedge twin structure were born in order to eliminate the 0.6% bulk strain. The macro texture weakened correspondingly as more variants were occurred and twin structure was born.
Key words:  cobalt    phase transformation    strain    lamellar    twin
                    发布日期:  2021-07-16
ZTFLH:  TG111.2  
基金资助: 国家新材料测试评价平台-主中心;国家新材料测试评价平台-有色金属材料行业中心;江西省重大课题研发专项(20194ABC28004)
通讯作者:  wangshuming@gbtc.cn   
作者简介:  王书明,国标(北京)检验认证有限公司,高级工程师。2006年6月毕业于北京有色金属研究总院,材料学硕士。同年加入北京有色金属研究总院分析测试中心(现:国标(北京)检验认证有限公司)组织结构部工作至今,主要从事XRD,晶体结构分析,微观组织表征。 发表论文约20篇,申报发明专利近10项。
引用本文:    
王书明, 张华, 左玉婷, 曹瑞军. 钴的相变织构及微观结构研究[J]. 材料导报, 2021, 35(Z1): 378-380.
WANG Shuming, ZHANG Hua, ZUO Yuting, CAO Ruijun. Study on Texture and Microstructure of Co During Phase Transformation. Materials Reports, 2021, 35(Z1): 378-380.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2021/V35/IZ1/378
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