Effects of Hot Processing on Sulfide and Oxide Inclusions
ZHENG Hao1, LIU Lihua2, ZHANG Zhongwu1,*
1 College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150000, China 2 Nanjing Iron & Steel Co., LTD, Nanjing 210035, China
Abstract: With the development of industry, higher and higher requirements are set on the quality of steels. Inclusions are one of the most important factors that affect the quality of steels. Especially for high-strength steels, the toughness is more sensitive to inclusions. Therefore, it is an important topic to investigate the effects of processing parameters on inclusion evolution during smelting, hot rolling and heat treatment processes. Inclusions have a significant impact on all the strength, plastic, toughness, fatigue resistance and corrosion resistance of steels. To reduce the disadvantageous effects of inclusions on the properties of steels, updating and optimizing the smelting methods are the prerequisite. With the application of bubble removal technology, vacuum carbon deoxidation technology, and tundish electromagnetic stirring technology in the smelting process, the contents of inclusions in steels have been significantly reduced. However, in the current industrialized environment, it is still impossible to eliminate non-metallic inclusions completely in steels. Some research results have shown that hot rolling and heat treatment processes also have an important influence on the evolution of inclusions, which is of great significance to further control the size, distribution and morphology of the inclusions after smelting. Therefore, in addition to the development of new smelting processes to reduce the content of inclusions, Clarifying the effects of hot processing on the evolution of inclusions is another important research direction. In this paper, the advanced inclusion control technologies and their principles in the smelting process are summarized first. The effects of thermomechanical processing and heat treatment on the number, size, distribution, morphology, and types of inclusions are then reviewed carefully.
Tervo H, Kaijalainen A, Pikkarainen T, et al. Materials Science and Engineering,2017,697,184.
2
Li X Y, Shi J, Dong H. Heat Treatment Technology of Materials,2012,41(18),59(in Chinese).
李晓源,时捷,董瀚.材料热处理技术,2012,41(18),59.
3
Yang W, Yang X G, Zhang L F, et al. Steelmaking,2013,29(6),71(in Chinese).
杨文,杨小刚,张立峰,等.炼钢,2013,29(6),71.
4
Liu J H, Liu H B. Henan Metallurgy,2015,6(3),1(in Chinese).
刘建华,刘洪波.河南冶金,2015,6(3),1.
5
Ward R G. An introduction to the physical chemistry of iron and steel ma-king, Martin’s Press, New York, USA,1962.
6
Hino M,Ito K. Thermodynamic data for steelmaking, Tohoku University Press, Japan,2010.
7
Kang Y, Thunman M, Sichen D, et al. ISIJ International,2009,49(10),1483.
8
Costa e Silva A, Beneduce F, Avillez R R. Tecnologia em Metallurgia Materiais e Minerao,2015,12(4),267.
9
Paek M K, Do K H, Kang Y B, et al. In: Proceeding of Clean Steel in Future-Prof Hae-Geon Lee Symposium. Pohang, Korea,2012.
10
Silva C E, A. Revue de Métallurgie,2008,105(4),181.
11
Kang Y B, Kim H S, Zhang J, et al. Journal of the Physics and Chemistry of Solids,2005,66(2-4),219.
12
Jung I H, Decterov S A, Pelton A D. Metallurgical and Materials Tran-sactions B,2004,35(3),493.
13
Jung I H. CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,2010,34(3),332.
14
Costa S A. Rare Metals,2006,25(5),412.
15
Costa S A. Journal of Phase Equilibria and Diffusion,2017,38(6),916.
16
Wu K X, Fu C, Zheng Y. Steelmaking,2010,26(4),8(in Chinese).
吴康夏,富春,郑毅.炼钢,2010,26(4),8.
17
Li N, Wang L, Xue Z L, et al. Results in Physics,2020,16,1.
18
Ren Y, Zhang L F, Fang W, et al. Metallurgical and Materials Transactions B,2016,47(2),1024.
19
Yu Z, Liu C J. Metals,2019,9(7),1.
20
Yang C Y, Luan Y K, Li D Z, et al. Journal of Materials Science & Technology,2019,7,1298.
21
Liu Y Q, Wang L J, Chou K C, et al. Journal of Rare Earths,2014,32(8),759.
22
Li H, Yu Y C, Ren X, et al. Journal of Iron and Steel Research, International,2017,24(9),925.
23
Ma Q, Wu C, Cheng G, et al. Materials Today,2015,2,S300.
24
Huang J, Min Y, Jiang M F, et al. Dongbei Daxue Xuebao/Journal of Northeastern University,2013,34(3),368.
25
Tabatabaei Y, Coley K S, Irons G A, et al. Steel Research International,2019,90(10),1900155.
26
Bao Y P, Liu J H, Xu B M. Journal of University and Technology Beijing,2003,10(4),20.
27
Li K W, Liu J H, Zhou J B, et al. Journal of University of Science and Technology Beijing,2015,37(9),1124(in Chinese).
李康伟,刘建华,周剑波,等.北京科技大学学报,2015,37(9),1124.
28
Wang L, Lee H, Hayes P. ISIJ International,1996,36(1),17.
29
Turkdogan E T. Ironmaking ＆ Steeling,2004,31(2),131.
30
Tang F P, Li Z, Wang X F, et al. Steel,2010,45(8),28.
唐复平,李镇,王晓峰,等.钢铁,2010,45(8),28.
31
Beskow K, Ladle G. Ironmaking and Steelmaking,2004,5(31),393.
32
Beskow K, Tripathi N N, Nzotta M. Molten Slags Fluxes and Salts,2004,6(31),320.
33
Tsunehiro U, Akihiko O, Mitsuru S. E.U. patent, EP84301814,1988.
34
Mao B, Tao J M, Sun L J. Continuous Casting,2008(2),8(in Chinese).
毛斌,陶金明,孙丽娟.连铸,2008(2),8.
35
Cui H, Bao Y P, Liu J H. Steelmaking,2010,26(2),45(in Chinese).
崔衡,包燕平,刘建华.炼钢,2010,26(2),45.
36
Zhang L F, Wang X H. Shandong Metallurgy,2005,27(2),1(in Chinese).
张立峰,王新华.山东冶金,2005,27(2),1.
37
Zhan D P, Zhang H S, Jiang Z H, et al. Foundry Technology,2007,28(1),110(in Chinese).
战东平,张慧书,姜周华,等.铸造技术,2007,28(1),110.
38
Asano K, Nakano T. Journal of the Iron and Steel Institute of Japan,1971,57(13),1943.
39
Braun T B, Elliott J F, Flemings M C. Metallurgical Transactions B:Process Metallurgy,1979,10(2),171.
40
You D L, Susanne K M, Peter P, et al. Metals,2017,7(11),460.
41
Gupta A, Cecen A, Goyal S, et al. Acta Materialia,2015,91,239.
42
Bartosiaki B G, Pereira J A M, Bielefeldt W V, et al. Journal of Mate-rials Research and Technology,2015,4(3),235.
43
Susumu I, Koichiro O, Rie S, et al. Materials Characterization,2017,131,210.
44
Fujita S, Murakami Y. Metallurgical and Materials Transactions A,2013,44(1),303.
45
Jacques Poirier. Metallurgical Research & Technology,2015,112(410),1.
46
Costa S A. Journal of Materials Research and Technology,2018,7(3),283.
47
Deng X, Ji C, Cui Y, et al. Ironmaking and Steelmaking,2017,44(10),739.
48
Yin H B, Shibata H, Emi T, et al. ISIJ International,1997,37(10),936.
49
Yin H B, Shibata H, Emi T, et al. ISIJ International,1997,37(10),946.
50
Luo C H. Computational Materials Science,2001,21(3),360.
51
Fuhr F, Torga G, Medina F, et al. Ironmaking and Steelmaking,2007,34(6),463.
52
Kang Y, Mikael T, Du S C, et al. ISIJ International,2009,49(10),1483.
53
Luo C H, Stahlberg U. Scandinavian Journal of Metallurgy,2002,31(3),184.
54
Song M, Nzotta M, Sichen D. Ironmaking and Steelmaking,2011,38(8),584.
55
Malkiewicz T, Rudnik S. Journal of the Iron and Steel Institute of Japan,1963,201(1),33.
56
Kiessling R. Journal of Metals,1969,21(10),48.
57
Lou D C, Cui K, Wu X C, et al. Foundry Technology,1996,8(6),11(in Chinese).
娄德春,崔昆,吴晓春,等.钢铁研究学报,1996,8(6),11.
58
Lou D C, Cui K, Wu X C. Iron and Steel Research,1996(5),26(in Chinese).
娄德春,崔昆,吴晓春.钢铁研究,1996(5),26.
59
Huang F Y, Su Y H F, Kuo J C. Metals and Materials International,2018,24,1333.
60
Shao X J, Lv L G, Du Q, et al.Heat Treatment of Metals,2018,43(5),144(in Chinese).
邵肖静,吕利鸽,杜倩,等.金属热处理,2018,43(5),144.
61
Gove K B, Charles J A. Metals Technology,1974,1(1),425.
62
Jian L, Chen W Q, Meng J X, et al.Steel,2006,41(10),74(in Chinese).
简龙,陈伟庆,孟金霞,等.钢铁,2006,41(10),74.
63
Wikstrm J, Nakajima K, Shibata H, et al. Materials Science and Engineering A,2008,495(1-2),316.
64
Vodopivec F, Gabrovek M. Metals Technology,1980,7(1),186.
65
Bernard G, Riboud P V, Urbain G. Metallurgical Research & Technology,1981,78(5),421
66
Yang W, Guo C B, Zhang L F, et al. Metallurgical and Materials Tran-sactions B,2017,48,2717.
67
Zhang L F, Guo C B, Yang W, et al. Metallurgical and Materials Transactions B,2018,49,803.
68
Luo C H, Stahlberg U. Journal of Materials Processing Technology,2001,114(1),87.
69
Xiao G H, Dong H, Wang M Q, et al. Journal of University of Science and Technology Beijing,2010,32(6),735(in Chinese).
肖国华,董瀚,王毛球,等.北京科技大学学报,2010,32(6),735.
70
Nozomi M, Motoki T, Takahiro I, et al. Procedia Engineering,2014,81,120.
71
Pickering F B. British Corrosion Journal,1978,13(2),55.
72
Ototani T, Kataura Y. Transactions of the Iron and Steel Institute of Japan,1972,12(5),334.
73
Zhang L, Guo C, Yang W, et al. Metallurgical and Materials Transactions B,2017,48(5),2267.
74
Matsuoka N, Terano M, Ishiguro T, et al. Procedia Engineering,2014,81,120.
75
Faraji M, Wilcox D P, Thackray R P, et al. Materials Science and Technology,2014,30(10),1177.
76
Li B, Chen W Q, Zheng H G, et al. Heat Treatment of Metals,2017,42(1),144.
李兵,陈伟庆,郑宏光,等.金属热处理,2017,42(1),144.
77
Fu C T, Xia Y J, Wang S J. Journal of Materials Heat Treatment,2015,36(1),117.
伏存田,夏云进,王世俊.材料热处理学报,2015,36(1),117.
78
Shao X J, Wang X H, Jiang M, et al. ISIJ International,2011,51(21),1995.
79
Choi W, Matsuura H, Tsukihashi F. ISIJ International,2011,51(21),1951.
80
Liu C S. Solid-phase reaction mechanism of inclusions and steel matrix interface in 1473K heat treatment process. Ph.D. Thesis,University of Science and Technology Beijing, China,2015(in Chinese).
刘成松.1473K热处理过程夹杂物与钢基体界面固相反应机理.博士学位论文,北京科技大学,2015.
81
Chen W B, Ren Y, Xu H K, et al. Steel,2018,53(10),38(in Chinese).
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