氧化石墨烯添加量对MoSe2复合rGO电极材料电化学性能的影响

doi:10.11896/cldb.23060178

材料导报

2024, Vol. 38

Issue (16): 23060178-8 https://doi.org/10.11896/cldb.23060178

无机非金属及其复合材料

氧化石墨烯添加量对MoSe₂复合rGO电极材料电化学性能的影响

郑栋浩¹, 贺格平^1,*, 弥元梅¹, 皇甫慧君², 张慧敏¹, 李彦霞¹, 袁蝴蝶¹

1 西安建筑科技大学材料科学与工程学院,西安 710055
2 陕西化工研究院有限公司,西安 710069

Effect of the Amount of Graphene Oxide on the Electrochemical Properties of MoSe₂ Composite rGO Electrode Materials

ZHENG Donghao¹, HE Geping^1,*, MI Yuanmei¹, HUANGFU Huijun², ZHANG Huimin¹, LI Yanxia¹, YUAN Hudie¹

1 College of Materials Science and Engineering,Xi’an University of Architecture and Technology,Xi’an 710055,China
2 Shaanxi Chemical Reserch Institute Co.Ltd,Xi’an 710069,China

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摘要开发高性能超级电容器电极材料在促进可再生能源的有效利用上起着重要作用,本工作采用简单一步水热法合成超级电容器用MoSe₂-还原氧化石墨烯(rGO)复合电极材料(MoSe₂ -rGO)。研究表明,氧化石墨烯(GO)添加量影响着复合材料的电化学性能,随着GO添加量增加,复合材料比电容呈现先增大后减小的趋势,GO添加量为30 mg的复合材料MoSe₂-rGO-30在1 A·g^-1条件下具有最佳比电容(558.2 F·g^-1),在功率密度为990 W·kg^-1时能量密度高达84.4 Wh·kg^-1。反应动力学揭示出扩散电容主导MoSe₂-rGO的电化学储能过程。Randles-Sevcik 方程计算的MoSe₂-rGO-30离子扩散系数是纯MoSe₂离子扩散系数的6.2倍。MoSe₂与高导电性rGO的协同作用赋予MoSe₂-rGO复合材料优异的电化学性能,表明MoSe₂ -rGO复合材料具有作为高性能超级电容器电极材料的潜力。

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	郑栋浩
	贺格平
	弥元梅
	皇甫慧君
	张慧敏
	李彦霞
	袁蝴蝶

关键词: 二硒化钼还原氧化石墨烯超级电容器电化学性能

Abstract: The development of high-performance supercapacitor electrode materials plays an important role in promoting the effective use of renewable energy.In this work,MoSe₂-reduced graphene oxide (rGO) composite electrode materials (MoSe₂-rGO) for supercapacitors were synthesized by a simple one-step hydrothermal method.It was found that the addition amount of graphene oxide (GO) affected the electrochemical properties of the composites.As the amount of GO added increases,the specific capacitance of the composites increased first and then decreased.The MoSe₂-rGO-30 composite with GO addition of 30 mg has the best specific capacitance of 558.2 F·g^-1 at 1 A·g^-1,and the energy density is as high as 84.4 Wh·kg^-1 at a power density of 990 W·kg^-1.The reaction kinetics reveals that the diffusion capacitance dominates the electrochemical energy storage process of MoSe₂-rGO.The ion diffusion coefficient of MoSe₂-rGO-30 calculated according to the Randles-Sevcik equation is 6.2 times that of pure MoSe₂.The synergistic effect of MoSe₂ and highly conductive rGO endows MoSe₂-rGO composites with good electrochemical performance,indicating that MoSe₂-rGO composites have the potential as electrode materials for high-performance supercapacitors.

Key words: molybdenum diselenide reduction of graphene oxide supercapacitor electrochemical performance

出版日期: 2024-08-25 发布日期: 2024-09-10

ZTFLH:

TB34

基金资助: 陕西省石油精细化学品重点实验室开放基金(SH1420SKF0003;SH1516SKF0002);陕西省大学生创新创业训练计划(4191;4602);西北工业大学凝固技术国家重点实验室基金(SKLSP201749);陕西省重点研发计划(2024GX-YBXM-394)

通讯作者: *贺格平,西安建筑科技大学材料科学与工程学院副教授、硕士研究生导师。1995年沈阳理工大学材料科学与工程专业本科毕业,2006年西安电子科技大学材料科学与工程专业硕士学位毕业后到西安建筑科技大学工作至今;2016年西北工业大学材料学专业博士毕业。目前主要从事纳米材料结构设计、制备、表征及性能研究,超级电容器电极材料及储能研究,纳米结构气敏传感器传感机理研究等方面的研究工作。近年来发表学术论文30篇,主编教材2部。hgping2013@126.com

作者简介: 郑栋浩,2018年7月南昌航空大学获得工学学士学位。现为西安建筑科技大学材料科学与工程学院硕士研究生,在贺格平老师的指导下进行研究。目前主要研究领域为超级电容器电极材料。

引用本文:

郑栋浩, 贺格平, 弥元梅, 皇甫慧君, 张慧敏, 李彦霞, 袁蝴蝶. 氧化石墨烯添加量对MoSe₂复合rGO电极材料电化学性能的影响[J]. 材料导报, 2024, 38(16): 23060178-8.
ZHENG Donghao, HE Geping, MI Yuanmei, HUANGFU Huijun, ZHANG Huimin, LI Yanxia, YUAN Hudie. Effect of the Amount of Graphene Oxide on the Electrochemical Properties of MoSe₂ Composite rGO Electrode Materials. Materials Reports, 2024, 38(16): 23060178-8.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23060178 或 http://www.mater-rep.com/CN/Y2024/V38/I16/23060178

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