二氧化锰基催化剂催化氧化甲苯的进展

doi:10.11896/cldb.23030015

材料导报

2024, Vol. 38

Issue (13): 23030015-11 https://doi.org/10.11896/cldb.23030015

无机非金属及其复合材料

二氧化锰基催化剂催化氧化甲苯的进展

宋杰¹, 丁红蕾^1,2,3,*, 潘卫国^1,2,3,*, 张凯¹, 马骏驰¹, 张子沂¹

1 上海电力大学能源与机械工程学院,上海 200090
2 上海发电环保工程技术研究中心,上海 201600
3 机械工业清洁发电环保技术重点实验室,上海 200090

Advances in the Catalytic Oxidation of Toluene by MnO₂-based Catalysts

SONG Jie¹, DING Honglei^1,2,3,*, PAN Weiguo^1,2,3,*, ZHANG Kai¹, MA Junchi¹, ZHANG Ziyi¹

1 College of Energy and Mechanical Engineering, Shanghai University of Electric Power, Shanghai 200090, China
2 Shanghai Power Environmental Protection Engineering Technology Research Center, Shanghai 201600, China
3 Key Laboratory of Environmental Protection Technology for Clean Power Generation in Machinery Industry, Shanghai 200090, China

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摘要随着我国产业升级和能源消费的增加,甲苯污染已成为一个重要的环境问题。现有甲苯处理方法中,催化氧化技术无疑是最为经济且有效的技术手段。而作为催化反应核心的催化剂,其性能尤为重要。贵金属催化剂虽然拥有活性优势,但烧结、毒化带来的活性下降以及高昂的价格阻碍了其在工业领域的广泛应用。过渡金属氧化物催化剂中,二氧化锰(MnO₂)由于其高催化活性、热稳定性、价格低廉、易于合成以及多种晶体形态可用的特点,近年来在甲苯催化氧化领域备受关注。但单一MnO₂的催化活性很难令人满意,对其改性优化就成为当前工作的重点。本文分析了MnO₂的晶体结构、表面特性和特定晶面等结构特点对甲苯催化效率的影响,重点探讨了通过掺杂、复合以及负载等改性手段提升MnO₂催化氧化甲苯的性能,并阐述了甲苯在MnO₂上的催化氧化机理,对制备用于催化甲苯的新型MnO₂催化剂的未来研究方向进行了展望。

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	宋杰
	丁红蕾
	潘卫国
	张凯
	马骏驰
	张子沂

关键词: MnO₂ 催化甲苯催化机理影响因素改性优化

Abstract: Owing to industrial development and increasing energy consumption in China, toluene pollution has become a serious environmental concern. Among the existing toluene treatment methods, catalytic oxidation is undoubtedly the most economical and effective technical approach. The performance of the catalyst, which is the core of the catalytic reaction, is particularly essential. Although noble metal catalysts possess excellent catalytic activity, their high cost and the decrease in activity due to sintering and poisoning hinder their widespread application in industry. In recent years, manganese dioxide (MnO₂) has attracted much attention as a transition metal oxide catalyst for the catalytic oxidation of toluene owing to its high catalytic activity, thermal stability, low cost, and easy synthesis, as well as the availability of various crystal forms. However, the catalytic activity of single MnO₂ is unsatisfactory, prompting the present study on its modification and optimization. We analyzed the effects of the structural characteristics of MnO₂, such as the crystal structure, surface properties, and specific crystalline surfaces, on the catalytic efficiency of toluene. Further, we aimed to improve the performance of MnO₂ for the catalytic oxidation of toluene through modification approaches like doping and composite loading and to elucidate the catalytic oxidation mechanism of toluene on MnO₂. The direction of future research on the preparation of novel MnO₂ catalysts for toluene catalysis is outlined herein.

Key words: MnO₂ catalyzing toluene catalytic mechanism influencing factor modification and optimization

出版日期: 2024-07-10 发布日期: 2024-08-01

ZTFLH:	X511
	TQ-9

基金资助: 国家重点研发计划项目(2018YFB0604204);上海市科技攻关项目(21DZ1207203)

通讯作者: ^*潘卫国,1987年于上海电力大学取得学士学位,1994年于浙江大学取得硕士学位,1997年于浙江大学取得博士学位,目前任能源与机械工程学院党委书记,兼任中国动力工程学会环保专委会主任委员。目前主要研究方向为能源清洁高效利用和光催化过程的能源转化与环境保护。主持并参与了国家“973”“863”、科技支撑计划、重点研发计划、国家自然科学基金。发表含 ESI 高被引论文、SCI论文在内的国内外学术论文160余篇,申请发明专利60余项。pweiguo@163.com
丁红蕾,1990 年于中国石油大学取得学士学位,1997 年于中国石油大学取得硕士学位,2010 年于浙江大学取得博士学位,目前主要从事燃煤烟气污染物控制方面的相关研究。主持或参与了多项科研项目的研究工作。近年来已在国内外学术期刊上发表论文20余篇,其中 SCI检索10篇,EI检索14篇。申请/授权专利多项。hlding2005@163.com

作者简介: 宋杰,2018年7月于山西大学获得工学学士学位。现为上海电力大学大学能源与机械学院硕士由丁红蕾副教授和潘卫国教授联合培养。目前主要研究领域为VOCs的热催化氧化。

引用本文:

宋杰, 丁红蕾, 潘卫国, 张凯, 马骏驰, 张子沂. 二氧化锰基催化剂催化氧化甲苯的进展[J]. 材料导报, 2024, 38(13): 23030015-11.
SONG Jie, DING Honglei, PAN Weiguo, ZHANG Kai, MA Junchi, ZHANG Ziyi. Advances in the Catalytic Oxidation of Toluene by MnO₂-based Catalysts. Materials Reports, 2024, 38(13): 23030015-11.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23030015 或 http://www.mater-rep.com/CN/Y2024/V38/I13/23030015

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