Research Progress on Preparation and Fluoride Removal of Alumina-based Adsorbents
XU Naicai1,*, HUANG Guoyong2, SHI Dandan3, BIAN Shaoju1, LI Sixia1
1 School of Chemistry and Chemical Engineering, Qinghai Normal University, Xining 810008, China 2 College of New Energy and Materials, China University of Petroleum-Beijing, Beijing 102249, China 3 Institute Company Limited of Science and Technology Information of Qinghai Province, Xining 810008, China
Abstract: Fluorine is one of the indispensable trace elements in the human body, but intake of excessive fluoride will cause skeletal diseases and seriously affect the growth of plants and animals as well as human life and health. At present, the methods of treating fluoride wastewater mainly include precipitation, membrane separation, ion exchange, and adsorption. Among these, adsorption highly concerns researchers because of its simple operation, high efficiency of fluoride removal, low cost, environmental friendliness, and other advantages. Alumina-based adsorption materials have large specific surface area, large pore volume, rich surface active sites, and strong affinity with F-, which is one of the most widely studied fluorine-removal materials. In this paper, the preparation of alumina-based adsorption materials, mechanism of fluoride removal, and latest research progress are reviewed, and future development trends forecast to provide reference for the subsequent preparation and application of alumina-based adsorption materials.
1 Xu N C, Shi D D, Dang L, et al. Materials Reports, 2017, 31(8), 36 (in Chinese). 许乃才, 史丹丹, 党力, 等. 材料导报, 2017, 31(8), 36. 2 He J, Yang Y, Wu Z, et al. Journal of Environmental Chemical Engineering, 2020, 8(6), 104516. 3 Zhang X D, Zhao F Y, Wang Y W, et al. Inorganic Chemicals Industry, 2019, 51(12), 6 (in Chinese). 张小东, 赵飞燕, 王永旺, 等. 无机盐工业, 2019, 51(12), 6. 4 Wan K, Huang L, Yan J, et al. Science of the Total Environmental, 2021, 773, 145535. 5 Du P X. Technological conditions of treatment of tantalum and nibium industrial wastewater by electrodialysis and recycling of fluorine. Master's Thesis, Guangdong University of Technology, China, 2020 (in Chinese). 杜璞欣. 电渗析法处理钽铌生产废水的工艺条件与氟的回收利用. 硕士学位论文, 广东工业大学, 2020. 6 Li X Y. Shanxi Chemical Industry, 2017, 37(6), 73 (in Chinese). 李先元. 山西化工, 2017, 37(6), 73. 7 Ge D, Lv X B, Wang Y L, et al. Environmental Ecology, 2021, 3(5), 75 (in Chinese). 格旦, 吕学斌, 王依琳, 等. 环境生态学, 2021, 3(5), 75. 8 Shi H P. Research on preparation of new alumina and its adsorption pro-perty for fluoride. Master's Thesis, Suzhou University of Science and Technology, China, 2010 (in Chinese). 时海平. 新型活性氧化铝的制备及吸附除氟性能研究. 硕士学位论文, 苏州科技学院, 2010. 9 Mondal P, George S. Reviews in Environmental Science and Bio/Techno-logy, 2015, 14, 195. 10 Zhang T. Preparation of modified biological activated carbon and its treatment of poor Water containing fluorine. Master's Thesis, Chang'an University, 2018 (in Chinese). 张涛. 改性生物活性炭的制备及对高氟劣质水的处理研究. 硕士学位论文, 长安大学, 2018. 11 Liao Y Q. Removal of fluoride from aqueous solution using activated alumina and its regeneration study. Master's Thesis, Beijing University of Chemical Technology, 2018 (in Chinese). 廖艳清. 活性氧化铝对水中氟离子的吸附及再生研究. 硕士学位论文, 北京化工大学, 2018. 12 Ghosh S, Malloum A, Lgwegbe C A, et al. Journal of Molecular Liquids, 2022, 346(15), 118257. 13 Zhang T, Liu G H, Chen B B, et al. Materials Reports, 2020, 34(4), 4020 (in Chinese). 张婷, 刘桂华, 陈斌斌, 等. 材料导报, 2020, 34(4), 4020. 14 McHale J M, Auroux A, Perrotta A J, et al. Science, 1997, 277, 788. 15 Wang F. Study on preparation, adsorption and in-situ doping color performance of alumina with controllable morphology. Ph. D. Thesis, Shaanxi University of Science and Technology, China, 2018 (in Chinese). 王芳. 可控形貌氧化铝的制备及吸附与原位掺杂呈色性能研究. 博士学位论文, 陕西科技大学, 2018. 16 Busca G. Catalysis Today, 2014, 226, 2. 17 Yan Y C. Guangdong Chemical Industry, 2020, 47(23), 8 (in Chinese). 燕云程. 广东化工, 2020, 47(23), 8. 18 Liu F, Zheng X H, Chen J B, et al. RSC Advances, 2015, 5(114), 93917. 19 Zhang W, Cheng R C, Bi H H, et al. New Carbon Materials, 2021, 36(1), 69. 20 Zhang Y. Synthesis of mesoporous alumina and its application in diesel hydrodesulphurization. Master's Thesis, Wuhan Institute of Technology, China, 2019 (in Chinese). 张严. 介孔氧化铝的合成及其在柴油加氢脱硫中的应用. 硕士学位论文, 武汉工程大学, 2019. 21 Xu N C. Research on preparation, characterization and fluoride removal performences of aluminium based adsorbents. Ph. D. Thesis. University of Chinese Academy of Sciences (Qinghai Institute of Salt Lakes, Chinese Academy of Sciences), China, 2017 (in Chinese). 许乃才. 铝基吸附剂的制备、表征及对F-的吸附性能研究. 博士学位论文, 中国科学院大学(中国科学院青海盐湖研究所), 2017. 22 Lin J, Yang Z, Zhao X, et al. Chemical Engineering Sciences, 2021, 244(23), 116817. 23 Dubey S P, Dwivedi A D, Sillanpää M, et al. Chemosphere, 2017, 169, 99. 24 Huang Z R, Li P Y. Materials for Mechanical Engineering, 2011, 35(7), 58 (in Chinese). 黄志荣, 李攀瑜. 机械工程材料, 2011, 35(7), 58. 25 Zhan T T. Study on the gas flow field in the reaction chamber for prepa-ring alumina nanometer powders. Master's Thesis, Suzhou University, China, 2018 (in Chinese). 詹停停. 制备氧化铝纳米粉体的反应室中气体流场研究. 硕士学位论文, 苏州大学, 2018. 26 Piao L Y, Liu X Z, Mao L J, et al. Acta Physico-Chimica Sinica, 2009, 25(11), 2232 (in Chinese). 朴玲钰, 刘祥志, 毛立娟, 等. 物理化学学报, 2009, 25(11), 2232. 27 Zhang C X, Luo X Y, Wu S Y. Inorganic Chemicals Industry, 2006(10), 26 (in Chinese). 张彩霞, 罗序燕, 吴速英. 无机盐工业, 2006(10), 26. 28 Frary F C. Industrial and Engineering Chemistry, 1946, 38(2), 129. 29 Mekhemer G A H, Nohman A K H, Fouad N E, et al. Colloids and Surfaces A-physicochemical and Engineering Aspects, 2000, 161, 439. 30 Gu W W. Research of modified alumina prepared through gelification. Master's Thesis, Tianjin University, China, 2007 (in Chinese). 顾伟伟. 凝胶法制备改性活性氧化铝研究. 硕士学位论文, 天津大学, 2007. 31 Inchaurrondo N, di Luca C, Mori F, et al. Journal of Environmental Chemical Engineering, 2019, 7, 102901. 32 Sun X F, Wu Y S, Li L S, et al. Journal of Functional Materials, 2018, 49(9), 9078 (in Chinese). 孙雪峰, 吴玉胜, 李来时, 等. 功能材料, 2018, 49(9), 9078. 33 Daynanada D, Sarva V R, Prasad S V, et al. Chemical Engineering Journal, 2014, 248, 430. 34 He Y, Zhang L, An X, et al. Science of the Total Environment, 2019, 688, 184. 35 Fan F Y, Deng X C, Tang Z L, et al. Journal of Salt Lake Research, 2020, 28(3), 18 (in Chinese). 樊发英, 邓小川, 唐志雷, 等. 盐湖研究, 2020, 28(3), 18. 36 Wu P. Preparing calcined Mg/Fe/La hydrotalcite-like compound for adsorption of fluoride and arsenate in water. Master's Thesis, Wuhan University of Technology, China, 2017 (in Chinese). 吴鹏. 焙烧态Mg-Fe-La类水滑石的制备及其吸附氟、砷的研究. 硕士学位论文, 武汉理工大学, 2017. 37 Chi Y, Chen Y, Hu C, et al. Journal of Molecular Liquids, 2017, 242, 416. 38 Kumari U, Siddiqi H, Bal M, et al. Advanced Powder Technology, 2020, 31, 2045. 39 Li X. Research on the technology of the fluoride adsorption capacity and regeneration of alumina. Master's Thesis, Xi'an University of Architecture and Technology, China, 2013 (in Chinese). 李潇. 氧化铝除氟与再生技术研究. 硕士学位论文, 西安建筑科技大学, 2013. 40 Tripathy S S, Bersillon J L, Gopal K. Separation and Purification Technology, 2006, 50, 310. 41 Xu N C, Li S X, Li W, et al. ChemistrySelect, 2020, 5, 1818. 42 Xu N C, Liu Z, Dong Y P, et al. Ceramics International, 2016, 42, 15253. 43 Hongyun J, Zheng J, Yuan J, et al. Journal of Alloys and Compounds, 2015, 620, 361. 44 Lin J, Chen J, Hong X, et al. Journal of Colloid and Interface Science, 2020, 561, 275. 45 Kang D, Yu X, Ge M, et al. Chemical Engineering Journal, 2018, 345, 252. 46 Yang K, Li Y, Tian Z, et al. Hydrometallurgy, 2020, 197, 105455. 47 Ma J, Zhang Y, Zhao B, et al. Analytical Chimica Acta, 2020, 1122, 97. 48 Chen X F, Jiang D W, Shi L, et al. Journal of Chemical Education, 2009, 30(8), 6 (in Chinese) 陈晓峰, 姜大炜, 施莉. 化学教育, 2009, 30(8), 6. 49 Liang P. Study on the preparation, characterization and fluoride adsorption properties by rare earth-modified chitosan resin. Ph. D. Thesis, Ocean University of China, China, 2013 (in Chinese). 梁鹏. 稀土改性壳聚糖树脂的制备、表征及对氟离子的吸附特性研究. 博士学位论文, 中国海洋大学, 2013. 50 Chen X, Wan C, Yu R, et al. Journal of Hazardous Materials, 2021, 411, 125113. 51 Yang W, Tian S, Tang Q, et al. Journal of Colloid and Interface Science, 2017, 496, 496. 52 Huang L, Yang Z, He Y, et al. Journal of Hazardous Materials, 2020, 394, 122555. 53 Kamble S P, Deshpande G, Barve P P, et al. Desalination, 2010, 264(1), 15. 54 Dang D. Fluoride removal by modified granular activated alumina and its regeneration. Master's Thesis, Beijing University of Chemical Technology, China, 2011 (in Chinese). 党丹. 除氟活性氧化铝改性及再生过程研究. 硕士学位论文, 北京化工大学, 2011. 55 Zhao B X, Cui R P, Wang X F, et al. Yunnan Chemical Technology, 2019, 46(2), 121 (in Chinese). 赵炳翔, 崔瑞璞, 王晓凤, 等. 云南化工, 2019, 46(2), 121. 56 Xu N C, Hong T Z, Liu Z, et al. Materials Reports, 2017, 31(6), 45 (in Chinese). 许乃才, 洪天增, 刘忠, 等. 材料导报, 2017, 31(6), 45. 57 Zhang Y X, Jia Y. Ceramics International, 2016, 42, 17472. 58 Chunduri L A, Rattan T M, Molli M, et al. Materials Express, 2014, 4 (7), 235. 59 Zhu J, Lin X, Wu P, et al. Applied Surface Science, 2015, 357, 91. 60 Liu D K, Liu H, Yang L, et al. Materials Reports, 2019, 33(4), 590 (in Chinese). 刘德坤, 刘航, 杨柳, 等. 材料导报, 2019, 33(4), 590. 61 Mondal P, Purkait M K. Chemosphere, 2019, 235, 391. 62 Xu N, Liu Z, Bian S, et al. Particuology, 2016, 27, 66. 63 Guo Y. The adsorption of fluoride ion by hydrotalcite-like compounds. Master's Thesis, Taiyuan University of Technology, China, 2015 (in Chinese). 郭宇. 类水滑石化合物对氟离子吸附性研究. 硕士学位论文, 太原理工大学, 2015. 64 Lv T F. The sorption behavior of Ca/Mg/Al hydrotalcite-like compounds towards removal of fluoride from protein solution. Master's Thesis, Dalian University of Technology, China, 2013 (in Chinese). 吕腾飞. Mg/Ca/Al类水滑石蛋白质体系中选择吸附氟特性研究. 硕士学位论文, 大连理工大学, 2013. 65 Han X F, Li H Y, Meng Q L, et al. Environmental Engineering, 2015, 33(7), 56 (in Chinese). 韩晓峰, 李红艳, 孟庆兰, 等. 环境工程, 2015, 33(7), 56. 66 Rohinikumar P, Sarath C K, Durga P C, et al. Materials Today, 2021, 46, 198. 67 Wu X, Zhang Y, Dou X, et al. Chemosphere, 2007, 69, 1758. 68 Tian Z, Zhang Z, Lu M, et al. Chemical Industry and Engineering Progress, 2022, 41(6), 3051(in Chinese). 田追, 张震, 卢嫚, 等. 化工进展,2022, 41(6), 3051. 69 Zhang X D, Zhao F Y, Wang Y W, et al. Inorganic Chemicals Industry, 2019, 51(12), 6 (in Chinese). 张小东, 赵飞燕, 王永旺, 等. 无机盐工业, 2019, 51(12), 6. 70 Cong F Y. A study on fluoride removal by electrosorption. Master's Thesis, Xi'an University of Architecture and Technology, 2007 (in Chinese). 丛凤英. 电吸附技术去除水中氟离子的研究. 硕士学位论文, 西安建筑科技大学, 2007. 71 Su L M. Experimental research of pretreatment technology of reverse osmosis used in removing fluorine. Master's Thesis, Shandong Agricultural University, 2007 (in Chinese). 宿立明. 反渗透除氟预处理技术的实验研究. 硕士学位论文, 山东农业大学, 2012. 72 Wang X W. Study on excessive fluoride & arsenic removal from ground-water by nanofiltration membrane. Master's Thesis, Lanzhou Jiaotong University, 2010 (in Chinese). 王晓伟. 纳滤膜净化高氟高砷地下水的试验研究. 硕士学位论文, 兰州交通大学, 2010.