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材料导报  2023, Vol. 37 Issue (7): 21060197-10    https://doi.org/10.11896/cldb.21060197
  无机非金属及其复合材料 |
非线性光学碳点的调控及应用研究进展
曹哲勇1, 刘兴华1, 郑静霞1,*, 杨永珍1,*, 刘旭光1,2
1 太原理工大学新材料界面科学与工程教育部重点实验室,太原 030024
2 太原理工大学材料科学与工程学院,太原 030024
Regulation and Application of Carbon Dots with Nonlinear Optical Properties:a Review
CAO Zheyong1, LIU Xinghua1, ZHENG Jingxia1,*, YANG Yongzhen1,*, LIU Xuguang1,2
1 Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China
2 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
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摘要 碳点(Carbon dots,CDs)作为一种新型零维碳纳米材料,具有优良的荧光和磷光等光学特性。随着对CDs光学性能的不断探索,学者们发现其不仅在弱光下表现出优异的线性光学特性,在强光下也表现出良好的非线性光学特性,如非线性极化率较高、非线性吸收方式可变、光限幅阈值较低以及对飞秒等超快激光具有较快的响应等,在军事、通信和医疗等领域中展现出巨大潜力。据此,本文对CDs非线性光学性质的调控及应用进行综述。首先,总结出CDs本体(CDs尺寸、掺杂元素和表面官能团等)及其外部环境(液态分散基质、固态分散基质和入射激光能量等)对其非线性光学性质的影响;其次,介绍其在光限幅、光开关、生物应用和物质检测等非线性光学方面的应用研究进展;最后,提出目前CDs在非线性光学领域中面临的问题,并对其进行展望。
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曹哲勇
刘兴华
郑静霞
杨永珍
刘旭光
关键词:  非线性光学  零维碳纳米材料  碳点  光限幅  光开关  生物应用    
Abstract: Carbon dots (CDs), as a novel type of zero-dimensional carbon nanomaterials, have excellent optical properties such as fluorescence and phosphorescence. With the continuous exploration of the optical properties of CDs, it is found that CDs not only exhibit excellent linear optical properties under weak light, but also exhibit outstanding nonlinear optical properties under strong light. These advantages of CDs include high nonlinear susceptibility, variable nonlinear absorption mode, low optical limiting threshold, and quick response to femtosecond and other ultrafast lasers. Thus, CDs exhibit great potential in the military, communication and medical fields. Herein, this review summarizes the regulation modes of CDs with nonlinear optical properties and their applications. Firstly, the influences from CDs themselves (CDs size, doping elements, surface functional groups, etc.) and their external environments (liquid matrix, solid matrix, laser energy, etc.) on their nonlinear optical properties are discussed. Secondly, the applications of CDs in nonlinear optical fields including optical limiting, optical switching, biology, and detection are introduced. Finally, the current problems and future potentials for applying CDs to nonlinear optics are proposed and prospected.
Key words:  nonlinear optics    zero-dimensional carbon nanomaterials    carbon dots    optical limiting    optical switching    biological application
出版日期:  2023-04-10      发布日期:  2023-04-07
ZTFLH:  O613.71  
  TB383  
  TP212.2  
基金资助: 国家自然科学基金(51972221);山西省回国留学人员科研资助项目(2020-051;HGKY2019027);山西浙大新材料与化工研究院科技研发项目(2021SX-TD012);山西省基础研究计划项目(20210302123164;20210302124604)
通讯作者:  * 杨永珍,太原理工大学新材料界面科学与工程教育部重点实验室教授、博士研究生导师。英国赫特福德大学校外博士研究生导师。“纳米光电材料及器件核心技术”山西省科技创新重点团队核心成员。1992年太原理工大学材料科学与工程专业本科毕业后到山西焦化集团有限公司工作,2004年太原理工大学化学工程专业硕士毕业,2007年太原理工大学材料学专业博士毕业。2017年6月至2018年6月在英国赫特福德大学访学一年。目前主要从事纳米碳功能材料、碳基光电材料和生物医药材料等方面的研究工作。主持并参与国家和省部级项目26项,在国内外期刊和会议上发表论文386篇,授权国家发明专利60项,授权美国发明专利1项,出版专著1部和教材2部。yyztyut@126.com
郑静霞,太原理工大学新材料界面科学与工程教育部重点实验室讲师。2010年太原理工大学金属材料工程专业本科毕业,2013年太原理工大学材料科学与工程专业硕士毕业,2018年太原理工大学材料科学与工程专业博士毕业后到太原理工大学新材料界面科学与工程教育部重点实验室工作至今。目前主要从事碳纳米光电功能材料的制备和应用研究,主持并参与国家和省部级项目12项,在国内外学术期刊上发表相关学术论文33篇,其中26篇被SCI收录,以第一作者或共同第一作者发表论文14篇,授权专利12项。zhengjingxia@tyut.edu.cn   
作者简介:  曹哲勇,2019年6月毕业于太原理工大学,获得工学学士学位。现为太原理工大学新材料界面科学与工程教育部重点实验室硕士研究生,在杨永珍教授和郑静霞老师的指导下进行研究。目前主要研究领域为碳纳米功能材料。
引用本文:    
曹哲勇, 刘兴华, 郑静霞, 杨永珍, 刘旭光. 非线性光学碳点的调控及应用研究进展[J]. 材料导报, 2023, 37(7): 21060197-10.
CAO Zheyong, LIU Xinghua, ZHENG Jingxia, YANG Yongzhen, LIU Xuguang. Regulation and Application of Carbon Dots with Nonlinear Optical Properties:a Review. Materials Reports, 2023, 37(7): 21060197-10.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21060197  或          http://www.mater-rep.com/CN/Y2023/V37/I7/21060197
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