Please wait a minute...
《材料导报》期刊社  2018, Vol. 32 Issue (13): 2272-2277    https://doi.org/10.11896/j.issn.1005-023X.2018.13.018
  金属与金属基复合材料 |
高频感应熔覆TiN/Co涂层组织及性能研究
黄本生, 高钰枭, 陈鹏, 李杰, 李光文
西南石油大学材料科学与工程学院,成都 610500
Microstructural and Mechanical Properties of Co-based Coating by High-frequency Induction Cladding
HUANG Bensheng, GAO Yuxiao, CHEN Peng, LI Jie, LI Guangwen
School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500
下载:  全 文 ( PDF ) ( 2624KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 为提高抽油杆表面的硬度和耐磨性,利用高频感应加热熔覆技术成功地在35CrMo钢基体上制备了TiN强化Co基复合涂层。涂层组织均匀致密,未出现明显的气孔、裂纹等缺陷。通过金相显微镜、扫描电镜、X射线衍射仪等手段研究熔覆层的组织结构,利用维氏显微硬度计表征涂层的显微硬度,并对涂层进行大削盘摩擦副试验,分别测试其摩擦系数和磨损量。结果表明:熔覆层的组织主要是γ-Co过饱和固溶体,且Cr23C6、Cr2B以及TiN等硬质相弥散分布于Co基体上;熔覆层具有较高的硬度,TiN掺杂量为10%的涂层表面硬度达到了788HV0.1,且由结合面至涂层表面,硬度逐渐增加;在相同的磨损条件下,10%TiN/Co复合涂层的耐磨损性能最好,其摩擦系数和磨损量较未添加TiN的涂层分别降低了40%和45%;涂层的磨损机理为磨粒磨损和粘着磨损相结合。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
黄本生
高钰枭
陈鹏
李杰
李光文
关键词:  高频感应熔覆  钴基涂层  TiN  显微硬度  耐磨性    
Abstract: To improve the microhardness and wear resistance of the sucker rod steel, the TiN reinforced Co-based alloy coa-tings were prepared on the surface of 35CrMo steel by high-frequency induction cladding. The composite coatings were metallurgically bonded to the substrate, and the microstructures were compactness and uniformity with few defects such as pores and cracks. The microstructure of the coating layer was investigated by metalloscope, SEM and XRD, and the microhardness distribution of the coa-ting was tested by microhardness tester. The friction coefficient and wear mass loss were also investigated. The results show that the organization is mainly Co solid solution, and hard phases (Cr23C6,Cr2B and TiN) were dispersed distribution in Co-based substrate. The 10%TiN+Co cladding layer surface has the highest hardness of 788HV0.1, and hardness gradient increased from the interface to the surface. Under the same condition, the coating with 10% TiN additions has the least relative wear rate. Its wear resistance and wear quality were reduced by 40% and 45%, compared with the coating without TiN addition. The wear mechanisms of the compo-site coatings were mainly adhesive wear and abrasive wear.
Key words:  high-frequency induction cladding    Co-based coating    TiN    microhardness    wear resistance
               出版日期:  2018-07-10      发布日期:  2018-08-01
ZTFLH:  TG146.15  
基金资助: 四川高等学校油气田材料重点实验室资助项目(X151516KCL01);四川省教育厅重点项目(15ZA0057)
作者简介:  黄本生:男,1969年生,博士,教授,主要从事金属材料表面改性和管道焊接研究 E-mail:hbslxp@163.com
引用本文:    
黄本生, 高钰枭, 陈鹏, 李杰, 李光文. 高频感应熔覆TiN/Co涂层组织及性能研究[J]. 《材料导报》期刊社, 2018, 32(13): 2272-2277.
HUANG Bensheng, GAO Yuxiao, CHEN Peng, LI Jie, LI Guangwen. Microstructural and Mechanical Properties of Co-based Coating by High-frequency Induction Cladding. Materials Reports, 2018, 32(13): 2272-2277.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.13.018  或          http://www.mater-rep.com/CN/Y2018/V32/I13/2272
1 Yan Tingjun, Wang Kuisheng, Guo Liqian, et al. Study of wear test for anti-wear coating sucker rod and tubing string[J].Lubrication Engineering,2004(4):46(in Chinese).
颜廷俊,王奎升,郭立谦,等.抽油杆/油管耐磨涂层摩擦磨损特性试验研究[J].润滑与密封,2004(4):46.
2 Ma Weiguo, Yang Xinbing, Zhang Lihua, et al. Research summary of cause and solution for sucker rod and tubing side wear[J].Oil Field Equipment,2009,38(1):22(in Chinese).
马卫国,杨新冰,张利华,等.抽油杆管偏磨成因及解决措施研究综述[J].石油矿场机械,2009,38(1):22.
3 吴则中.有杆抽油设备与技术-抽油杆[M].北京:石油工业出版社,1994.
4 Wang Hanxiang, Sui Yunkang, Zhang Jinzhong, et al. Friction and wear behaviors of sucker rod and tubing string in the presence of oil-field wastewater as the lubricating medium[J].Tribology,2009,24(5):467(in Chinese).
王旱祥,隋允康,张金中.抽油杆和油管材料在油田污水介质中的摩擦磨损性能研究[J].摩擦学学报,2009,24(5):467.
5 Wu Zezhong, Chen Qiang, Zhong Yonghai, et al. Review and prospect of research and 29-years manufacturing of sucker rod in China[J].Oil Field Equipment,2012,41(1):62(in Chinese).
吴则中,陈强,钟永海,等.我国29年来抽油杆研制工作回顾与展望[J].石油矿场机械,2012,41(1):62.
6 Xu Aiyan, Chen Jutao, Yuan Liangshuai, et al. HL grade 35CrMOA sucker rod body failure analysis[J].Application and Development,2017,40(6):34(in Chinese).
徐蔼彦,陈举涛,袁良帅,等.HL级35CrMoA抽油杆杆体失效分析[J].焊管,2017,40(6):34.
7 Zeng Yubin, Xiang Chao, He Jianghong, et al. Mechanism analysis and prevention measures of eccentric wear of rods and tubing in yaerxia oil field[J].Inner Mongolia Petrochemical Industry,2010(3):38(in Chinese).
曾玉斌,向超,何将宏,等.鸭儿峡油田杆管偏磨机理分析与防治措施[J].内蒙古石油化工,2010(3):38.
8 Bai Qiang, Pang Bin, Lin Wei, et al. Fracture failure analysis of grade HL sucker rod[J].Heat Treatment of Metals,2016,4(7):187(in Chinese).
白强,庞斌,林伟,等.HL型抽油杆断裂失效分析[J].金属热处理,2016,4(7):187.
9 Shao Mingyu. Research on technology of hot-dipped aluminum of sucker rods and its properties[D].Qingdao:China University of Petroleum (East China),2013(in Chinese).
邵明雨.抽油杆热浸镀铝工艺及性能研究[D].青岛:中国石油大学(华东),2013.
10 Wang Gang, Zhang Yanmin, Bi Linlin, et al. Application of tungsten alloy technology for sucker rod[J].China Petroleum Machinery,2012,40(2):75(in Chinese).
王岗,张艳敏,毕琳琳,等.抽油杆镀钨合金工艺技术的应用[J].石油机械,2012,40(2):75.
11 Shi Guangping. Research and application on laser surface modification of sucker rod and tubing[D].Qingdao:China University of Petroleum(East China),2013(in Chinese).
石光平.抽油管杆激光表面改性研究及应用[D].青岛:中国石油大学(华东),2013.
12 Xie Liang. Research on the performance and process of laser cladding layer based of co base alloy[D].Qinhuangdao:Yanshan University,2016:5(in Chinese).
谢亮.激光熔覆Co基合金熔覆层工艺及其性能研究[D].秦皇岛:燕山大学,2016:5.
13 Gao Huhe, Ding Tingting, Ma Shujin, et al. Microstrucure and wear resistance of Cr3C2/Cobalt-based alloy coating ceposited by plasma transferred arc surfacing[J].Chinese Journal of Rare Metals,2016,40(11):1119(in Chinese).
高胡鹤,丁婷婷,马淑谨,等.等离子堆焊Cr3C2/钴基合金涂层的组织结构与耐磨性研究[J].稀有金属,2016,40(11):1119.
14 Li Mingxi, Gu Fenglin, Li Diankai. Microstructure and mechanic properties of SiC reinforced cobalt-based alloy coatings deposited by plasma transferred arc wel-ding[J].Transactions of the China Wel-ding Institution,2015,36(12):35(in Chinese).
李明喜,顾凤麟,李殿凯.碳化硅增强钴基合金等离子喷焊层组织与力学性能[J].焊接学报,2015,36(12):35.
15 Huang Xinbo, Jia Jianyuan, Lin Huachun. Corrosion resistance of Co based alloy-tungsten carbide composite coating[J].Materials for Mechanical Engineering,2003,27(11):49(in Chinese).
黄新波,贾建援,林华春.钴基合金-碳化物复合涂层的耐蚀性能[J].机械工程材料,2003,27(11):49.
16 Tao Hongfang, Tao Hongwei, et al. Performance analysis of cobalt-based, nickel-based alloy coating micro-hardness with high-frequency induction cladding[J].Journal of Qingdao Technological University,2013,34(6):96(in Chinese).
陶红芳,陶洪伟,等.高频感应熔覆钴基、镍基合金涂层显微硬度分析[J].青岛理工大学学报,2013,34(6):96.
17 Zhang Zengzhi, Han Guiquan, et al. Analysis on microstructure of Ni60 coating by high and medium frequency induction cladding[J].Journal of Material Engineering,2003(4):3(in Chinese).
张增志,韩圭泉,等.高中频感应熔涂Ni60涂层组织分析[J].材料工程,2003(4):3.
18 Chen Pengrong. Study on microstructure and properties of Co-base coating prepared by plasma spray[D].Harbin:Harbin Institute of Technology,2010(in Chinese).
陈鹏荣.等离子喷涂制备钴基涂层及组织性能研究[D].哈尔滨:哈尔滨工业大学,2010.
19 Wang Cunshan, Yu Qun. Mircrostructure and properties of nano-TiN-Ni45A composite coatings prepared by laser cladding[J].Laser Machining,2016(19):39(in Chinese).
王存山,于群.激光熔覆纳米TiN-Ni45A复合涂层组织与性能[J].航空制造技术,2016(19):39.
[1] 薛艺, 田青超. 硬质合金切削刀具研究进展[J]. 材料导报, 2019, 33(z1): 353-357.
[2] 郭宝超, 蒋恩, 陈亮. 压水堆驱动机构钩爪激光与GTAW钴基合金堆焊层组织分析及性能表征[J]. 材料导报, 2019, 33(z1): 416-419.
[3] 胡建伟, 谢永江, 刘子科, 翁智财, 王月华, 何龙. 两阶段变速搅拌对高强混凝土稳定性的影响[J]. 材料导报, 2019, 33(z1): 229-233.
[4] 程国君, 产爽爽, 陈晨, 钱家盛, 丁国新, 王周锋. 改性剂对TiN/PS纳米复合材料流变行为的影响[J]. 材料导报, 2019, 33(14): 2444-2449.
[5] 陈玉静, 沙爱民, 胡魁, 刘状壮, 曹世豪, 张华. 青藏地区路用遮热涂层的制备及性能[J]. 材料导报, 2019, 33(14): 2319-2325.
[6] 蔡惠坤, 翁泽钜, 顾开选, 王凯凯, 郑建朋, 王俊杰. 硬质合金深冷处理研究进展[J]. 材料导报, 2019, 33(1): 175-182.
[7] 李振伟, 狄士春. 纳米TiO2微粒对2214铝合金微弧氧化膜微观结构及耐磨性能的影响[J]. 《材料导报》期刊社, 2018, 32(8): 1294-1299.
[8] 王虎, 王智慧. 等离子熔覆法制备AlxCoCrFeNi高熵合金微观组织与性能研究[J]. 《材料导报》期刊社, 2018, 32(4): 589-592.
[9] 汪倡, 庞学佳, 高宗鸿, 刘金娜, 房永超, 崔秀芳, 刘二宝, 金国. YSZ纤维增强等离子喷涂Al2O3/8YSZ涂层耐磨性能研究[J]. 《材料导报》期刊社, 2018, 32(4): 563-568.
[10] 肖轶, 徐呈艺, Ryou Min, 曹健. Cr3C2粒径对等离子堆焊铁基合金层组织与耐磨性能的影响[J]. 材料导报, 2018, 32(24): 4329-4333.
[11] 王晶, 史雪婷, 冯利邦, 强小虎, 刘艳花. 长效超疏水铜表面的构建及耐磨性和自清洁性能[J]. 材料导报, 2018, 32(24): 4314-4318.
[12] 缪倩倩, 陈海燕, 顾伟, 蒋永锋, 宋亓宁. 钛合金表面阳极微弧等离子体渗硼层的研究[J]. 材料导报, 2018, 32(18): 3161-3165.
[13] 马妞, 黄佳木, 苏俊, 尹凌毅. MgO纳米颗粒对AZ31B镁合金微弧氧化涂层耐磨和耐蚀性的影响[J]. 材料导报, 2018, 32(16): 2768-2772.
[14] 夏法锋, 杨安娜, 马春阳. 工艺参数对脉冲电沉积Ni-TiN纳米镀层微观组织和性能的影响[J]. 《材料导报》期刊社, 2018, 32(14): 2448-2451.
[15] 张天刚, 孙荣禄, 张雪洋, 刘亚楠. Ti811表面激光熔覆原位合成TiC-TiB2复合Ti基涂层的微观组织分析[J]. 《材料导报》期刊社, 2018, 32(13): 2208-2213.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed