电弧离子镀NiCrAlY和NiCoCrAlYHfSi涂层抗高温氧化性能

doi:10.11896/j.issn.1005-023X.2018.13.017

《材料导报》期刊社

2018, Vol. 32

Issue (13): 2267-2271 https://doi.org/10.11896/j.issn.1005-023X.2018.13.017

金属与金属基复合材料

电弧离子镀NiCrAlY和NiCoCrAlYHfSi涂层抗高温氧化性能

杜伟^1,2, 石倩², 代明江², 易健宏¹, 林松盛², 侯惠君²

1 昆明理工大学材料科学与工程学院,昆明 650093;
2 广东省新材料研究所,现代材料表面工程技术国家工程实验室,广东省现代表面工程技术重点实验室,广州 510650

High Temperature Oxidation Resistance Performance of NiCrAlY andNiCoCrAlYHfSi Arc Ion Plating Coating

DU Wei^1,2, SHI Qian², DAI Mingjiang², YI Jianhong¹, LIN Songsheng², HOU Huijun²

1 Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093;
2 National Engineering Laboratory for Modern Materials Surface Engineering Technology, The Key Laboratory ofGuangdong for Modern Surface Engineering Technology, Guangdong Institute of New Materials,Guangzhou 510650

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摘要采用电弧离子镀技术在镍基高温合金DZ22B表面包覆一层NiCrAlY和NiCoCrAlYHfSi涂层,对比了两种涂层的微观形貌、结构和抗高温氧化性能,并讨论了不同活性元素在氧化中的作用。结果表明:NiCrAlY涂层主要由γ′-Ni₃Al/γ-Ni、β-NiAl和α-Cr相组成,而NiCoCrAlYHfSi除上述组成外还形成了NiCoCr合金相,两种涂层热处理期间均发生β-NiAl向γ′-Ni₃Al的转变过程。NiCrAlY和NiCoCrAlYHfSi涂层1 050 ℃恒温氧化200 h的平均氧化速率分别为0.072 3 g/(m²·h)和0.052 7 g/(m²·h)。NiCrAlY氧化初期直接形成α-Al₂O₃、NiCr₂O₄ 和Cr₂O₃,随后出现裂纹、孔洞等缺陷,氧化物沿孔洞向涂层内部延伸,同时由于基材中的Ti元素发生外扩散,涂层中还形成了TiO₂。NiCoCrAlYHfSi氧化初期形成了亚稳态的θ-Al₂O₃,随后慢慢转变为α-Al₂O₃,氧化物层比NiCrAlY均匀致密,抗高温氧化性能更优异。

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关键词: 电弧离子镀镍基高温合金涂层抗高温氧化性能

Abstract: NiCrAlY and NiCoCrAlYHfSi coatings were deposited on nickel-based superalloy DZ22B by arc ion plating. The microstructure, composition and high temperature oxidation resistance was compared, and the action of active elements in oxidation was discussed. Results show that the as-deposited coatings were mainly composed of γ′-Ni₃Al/γ-Ni,β-NiAl, and α-Cr, and the addition of NiCoCr in NiCoCrAlYHfSi. After the heat treatment, the transformation of β-NiAl to γ′-Ni₃Al occurred. The average oxidation rates of NiCrAlY and NiCoCrAlYHfSi coatings after 200 h were 0.072 3 g/(m²·h) and 0.052 7 g/(m²·h) at constant tempe-rature of 1 050 ℃. The α-Al₂O₃,NiCr₂O₄ and Cr₂O₃ phase firstly formed at the initial stage of oxidation of NiCrAlY. Cracks, holes and other defects were subsequently observed and the oxide extended to the interior of the coating along those defects. At the same time, TiO₂ formed as a result of the diffusion of Ti in substrate. For NiCoCrAlYHfSi oxidation, metastable θ-Al₂O₃ formed at the initial stage and then transferred to stable α-Al₂O₃. The oxide layer is more uniform and dense compared to NiCrAlY, thus has better oxidation resistance.

Key words: arc ion plating nickel base superalloy coating high temperature oxidation resistance

出版日期: 2018-07-10 发布日期: 2018-08-01

ZTFLH:

TG174.444

基金资助: 广东省自然科学基金团队项目(2016A030312015);广东省科学院科技创新发展专项(2017GDASCX-0202);广东省科学院平台建设项目(2016GDASPT-0206)

通讯作者: 代明江:通信作者,男,1964年生,博士,教授,主要研究方向为真空镀膜技术 E-mail:daimingjiang@tsinghua.org.cn

作者简介: 杜伟:男,1990年生,硕士研究生,主要从事抗高温氧化防护涂层方面的研究 E-mail:308889833@qq.com

引用本文:

杜伟, 石倩, 代明江, 易健宏, 林松盛, 侯惠君. 电弧离子镀NiCrAlY和NiCoCrAlYHfSi涂层抗高温氧化性能[J]. 《材料导报》期刊社, 2018, 32(13): 2267-2271.
DU Wei, SHI Qian, DAI Mingjiang, YI Jianhong, LIN Songsheng, HOU Huijun. High Temperature Oxidation Resistance Performance of NiCrAlY andNiCoCrAlYHfSi Arc Ion Plating Coating. Materials Reports, 2018, 32(13): 2267-2271.

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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.13.017 或 http://www.mater-rep.com/CN/Y2018/V32/I13/2267

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