Please wait a minute...
材料导报  2018, Vol. 32 Issue (18): 3161-3165    https://doi.org/10.11896/j.issn.1005-023X.2018.18.011
  金属与金属基复合材料 |
钛合金表面阳极微弧等离子体渗硼层的研究
缪倩倩, 陈海燕, 顾伟, 蒋永锋, 宋亓宁
河海大学机电工程学院,常州 213022
The Anode Micro-arc Plasma Boriding Layer on Titanium Alloy
MIAO Qianqian, CHEN Haiyan, GU Wei, JIANG Yongfeng, SONG Qining
College of Mechanical and Electrical Engineering, Hohai University, Changzhou 213022
下载:  全 文 ( PDF ) ( 2268KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 采用阳极微弧等离子体技术研究了钛合金表面渗硼层的微观组织和性能。通过光学显微镜、扫描电镜(SEM)、X射线衍射仪(XRD)、能谱仪(EDS)表征分析了渗硼层的表面和截面的微观组织、形貌、相结构、渗层元素分布。借助摩擦磨损试验机测试了渗硼层的耐磨性,运用电化学工作站对渗硼后的TC4材料进行了耐腐蚀性测试。结果表明,钛合金表面阳极微弧等离子体渗硼技术制备的渗硼层连续致密。渗硼层主要由金属间化合物TiB2和TiB组成,其与氧化层共同作用,能显著提高钛合金表面的耐磨性。渗硼后的TC4钛合金耐腐蚀性较基体有所降低。表面阳极微弧等离子体技术是一种新型的钛合金表面改性方法。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
缪倩倩
陈海燕
顾伟
蒋永锋
宋亓宁
关键词:  钛合金  渗硼  显微组织  耐磨性    
Abstract: An anode micro-arc plasma boriding technique was performed on titanium alloy to investigate the microstructure and properties of boriding layer. The morphology and microstructure of the surface and section of boriding layer, phase composition and elements distribution were examined using optical microscopy (SEM), scanning electron microscopy, X-ray diffractometer (XRD) and the energy dispersion spectrum (EDS). And the wear resistance of layer was assessed by conducting pin-on-disk wear tests and friction coefficient tests. Furthermore, the corrosion resistance was investigated by measuring polarization curves. The results showed that the boriding layer prepared by the anodic micro-arc plasma boriding on the titanium alloy was continuous and compact. Moreover, the boriding layer was mainly composed of intermetallic compounds TiB2 and TiB combined with the oxide layer, which could significantly improve its surface wear resistance. But the corrosion resistance of boriding layer was lower than that of the substrate. Anode micro-arc plasma technology is a kind of novel method of titanium alloy surface modification.
Key words:  titanium alloy    boriding    microstructure    wear resistance
                    发布日期:  2018-10-18
ZTFLH:  TG174.445  
  TG156.8+7  
基金资助: 苏省研究生科研与实践创新计划项目(KYCX17_0535);中央高校基本科研业务费专项资金(2017B676X14)
通讯作者:  蒋永锋:男,1974年生,博士,教授,博士研究生导师,研究方向为材料表面处理 E-mail:jiangyf@hhuc.edu.cn   
作者简介:  缪倩倩:女,1994年生,硕士研究生,研究方向为钛合金表面强化 E-mail:miaoqianqian66@163.com
引用本文:    
缪倩倩, 陈海燕, 顾伟, 蒋永锋, 宋亓宁. 钛合金表面阳极微弧等离子体渗硼层的研究[J]. 材料导报, 2018, 32(18): 3161-3165.
MIAO Qianqian, CHEN Haiyan, GU Wei, JIANG Yongfeng, SONG Qining. The Anode Micro-arc Plasma Boriding Layer on Titanium Alloy. Materials Reports, 2018, 32(18): 3161-3165.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.18.011  或          http://www.mater-rep.com/CN/Y2018/V32/I18/3161
1 Atar E, Kayali E S, Cimenoglu H. Characteristics and wear performance of borided Ti6Al4V alloy[J]. Surface and Coatings Technology,2008,202(19):4583.
2 Ye Y, Wang J Y. An overview on application status and processing technology development of titanium alloy[J].Materials Review,2012(S2):360(in Chinese).
叶勇,王金彦.钛合金的应用现状及加工技术发展概况[J].材料导报,2012(S2):360.
3 Yi X H, Fan Z G, Zhang J L, et al. Solid-state pack boronizing of TC4 titanium alloy[J]. Rare Metal Materials and Engineering,2010,39(9):1631(in Chinese).
衣晓红,樊占国,张景垒,等.TC4钛合金的固体渗硼[J].稀有金属材料与工程,2010,39(9):1631.
4 Aliev M K, Saboor A. Pulsed nanocrystalline plasma electrolytic boriding as a novel method for corrosion protection of CP-Ti (Part 1: Different frequency and duty cycle)[J]. Bulletin of Materials Science,2007,30(6):601.
5 Belkin P N, Kusmanov S A, Zhirov A V, et al. Anode plasma electrolytic saturation of titanium alloys with nitrogen and oxygen[J]. Journal of Materials Science & Technology,2016,32(10):1027.
6 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 3620.1-2007钛及钛合金牌号和化学成分[S].北京:中国标准出版社,2007:1.
7 Li Q H, Fan B F, Wang W K. Research on the technique of plasma electrolysis boronizing of magnesium alloy[J]. Plating and Finis-hing,2013,35(10):36(in Chinese).
李奇辉,樊斌锋,王文科.镁合金液相等离子体电解渗硼技术的研究[J].电镀与精饰,2013,35(10):36.
8 Kaestner P, Olfe J, Rie K T. Plasma-assisted boriding of pure titanium and TiAl6V4[J]. Surface & Coatings Technology,2001,142(3):248.
9 Yi X H, Fan Z G, Zhang J L, et al. Effects of rare earth on boroni-zing of TC4 titanium alloy[J]. Journal of the Chinese Society of Rare Earths,2010,28(5):607(in Chinese).
衣晓红,樊占国,张景垒,等.稀土对TC4钛合金固体渗硼的影响研究[J].中国稀土学报,2010,28(5):607.
10 Wu G L, Ge X L, Xu X J, et al. Optimization of lanthanum oxide catalytic boronizing on surface of TC4 titanium alloy[J]. Heat Treatment of Metals,2014,39(9):24(in Chinese).
吴桂兰,戈晓岚,许晓静,等.TC4钛合金表面氧化镧催渗渗硼工艺优化[J].金属热处理,2014,39(9):24.
11 Cui C X, Wu R J, Wang H W. Thermodynamic characteristics of rare-earth element and its application in metals matrix composites[J]. Rare Metal Materials and Engineering,1997(3):53(in Chinese).
崔春翔,吴人洁,王浩伟.稀土元素的热力学特性及在金属基复合材料中的应用[J].稀有金属材料与工程,1997(3):53.
12 Chen D, Li J. Textural construction of shared diffusion layers of boron and rare earths[J]. Journal of Liaoning Institute of Science and Technology,1999(2):20(in Chinese).
陈丹,李杰.硼稀土共渗渗层组织结构[J].辽宁科技学院学报,1999(2):20.
13 Li F H, Wang L N, Yi X H, et al.The research status and reaction mechanism of boronizing on titanium and its alloys[J]. Journal of Materials and Metallurgy,2013,12(3):212(in Chinese).
李凤华,王丽娜,衣晓红,等.钛及钛合金渗硼的研究现状与反应机理[J].材料与冶金学报,2013,12(3):212.
14 Chang Y W, Xu Z. Discussion on the catalytic mechanism of rare earths in chemical heat treatment[J]. Shanghai Metals,2001,23(5):14(in Chinese).
常延武,徐洲.稀土对化学热处理催渗作用的机理探讨[J].上海金属,2001,23(5):14.
15 Tang H F, Zhao Y Q, Hong Q, et al. Effects of rare earth elements on the structure and properties of high-temperature titanium alloy[J]. Titanium Industry Progress,2010,27(1):16(in Chinese).
汤海芳,赵永庆,洪权,等.稀土元素对高温钛合金组织和性能的影响[J].钛工业进展,2010,27(1):16.
16 Liu Y H, Xu X J, Wang H Y, et al. Effects of ZrO2 on solid-state boronizing of TC4 titanium alloy[J]. Hot Working Technology,2013,42(18):109(in Chinese).
刘云辉,许晓静,王宏宇,等.氧化锆对TC4钛合金固体渗硼的影响[J].热加工工艺,2013,42(18):109.
17 Belkin P N, Kusmanov S A, Dyakov I G, et al. Anode plasma electrolytic carburizing of commercial pure titanium[J]. Surface & Coa-tings Technology,2016,307:1303.
18 Kusmanov S A, Smirnov A A, Silkin S A, et al. Plasma electrolytic nitriding of alpha- and beta-titanium alloy in ammonia-based electrolyte[J]. Surface & Coatings Technology,2016,307:1291.
19 Guo C, Zhou J, Zhao J, et al. Microstructure and friction and wear behavior of laser boronizing composite coatings on titanium substrate[J]. Applied Surface Science,2011,257(9):4398.
20 Ding X B. Anti-wear ceramic coating prepared on the surface of TC4 titanium alloy [D]. Harbin: Harbin Institute of Technology,2007(in Chinese).
丁显波.TC4钛合金表面原位生长耐磨损陶瓷膜研究[D].哈尔滨:哈尔滨工业大学,2007.
21 Kusmanov S A, Smirnov A A, Kusmanova Y V, et al. Anode plasma electrolytic nitrohardening of medium carbon steel[J]. Surface & Coatings Technology,2015,269(1):308.
22 Belkin P N, Kusmanov S A, Belkin V S, et al. Increase in corrosion resistance of commercial pure titanium by anode plasma electrolytic nitriding[J]. Materials Science Forum,2016,844:125.
23 Liu R, Xue X X, Jiang T, et al. The current situation and development of boron and boride[J]. Materials Review,2006,20(6):1(in Chinese).
刘然,薛向欣,姜涛,等.硼及其硼化物的应用现状与研究进展[J].材料导报,2006,20(6):1.
24 Zhang M. Study on the boride layer by solid boronizing method on Ti6Al4V alloy [D]. Taiyuan: Taiyuan University of Technology,2012(in Chinese).
张敏.采用固体渗硼法在Ti6Al4V合金表面制备渗硼层的研究[D].太原:太原理工大学,2012.
[1] 洪起虎, 燕绍九, 陈翔, 李秀辉, 舒小勇, 吴廷光. GO添加量对RGO/Cu复合材料组织与性能的影响[J]. 材料导报, 2019, 33(z1): 62-66.
[2] 康凤, 陈文, 胡传凯, 林军, 夏祥生, 吴洋. 时效参数对Ti12LC钛合金组织及性能的影响[J]. 材料导报, 2019, 33(z1): 326-328.
[3] 薛艺, 田青超. 硬质合金切削刀具研究进展[J]. 材料导报, 2019, 33(z1): 353-357.
[4] 肖健, 刘锦平, 刘先斌, 邱贵宝. 泡沫钛表面改性研究进展[J]. 材料导报, 2019, 33(9): 1558-1566.
[5] 平学龙, 符寒光, 孙淑婷. 激光熔覆制备硬质颗粒增强镍基合金复合涂层的研究进展[J]. 材料导报, 2019, 33(9): 1535-1540.
[6] 王川, 李德富. 冷轧变形量对5A02铝合金管材组织和性能的影响[J]. 材料导报, 2019, 33(8): 1361-1366.
[7] 王应武, 左孝青, 冉松江, 孔德昊. TiB2含量及T6热处理对原位TiB2/ZL111复合材料显微组织和硬度的影响[J]. 材料导报, 2019, 33(8): 1371-1375.
[8] 阴中炜, 孙彦波, 张绪虎, 王亮, 徐桂华. 粉末钛合金热等静压近净成形技术及发展现状[J]. 材料导报, 2019, 33(7): 1099-1108.
[9] 杜娟, 刘青茂, 王付胜, 宋肖肖, 胡雪兰. Ti-6Al-4V钛合金在氢氟酸-硝酸体系下的缓蚀行为及机理[J]. 材料导报, 2019, 33(6): 1000-1005.
[10] 刘强, 惠松骁, 宋生印, 叶文君, 于洋. 油气开发用钛合金油井管选材及工况适用性研究进展[J]. 材料导报, 2019, 33(5): 841-853.
[11] 温丽, 薛松柏, 马超力, 龙伟民, 钟素娟. 钎焊温度对纳米银焊膏真空钎焊Ni200合金接头组织与性能的影响[J]. 材料导报, 2019, 33(3): 386-389.
[12] 方振邦, 张志强, 李颖, 尹华, 邢艳双, 何长树. 7N01S-T5铝合金厚板搅拌摩擦焊接头的晶间腐蚀行为[J]. 材料导报, 2019, 33(2): 304-308.
[13] 曹聪聪, 李文亚, 杨康, 李成新, 纪纲. 基体硬度和热学性质对冷喷涂TC4钛合金涂层组织和力学性能的影响[J]. 材料导报, 2019, 33(2): 277-282.
[14] 陈永城, 罗子艺, 张宇鹏, 易耀勇, 李明军. 紫铜/304不锈钢激光焊接接头显微组织及力学性能[J]. 材料导报, 2019, 33(2): 325-329.
[15] 产玉飞, 陈长军, 张敏. 金属增材制造过程的在线监测研究综述[J]. 材料导报, 2019, 33(17): 2839-2846.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed