球磨转速对含钆ODS钢中M23C6析出的影响研究

doi:10.11896/cldb.22030003

材料导报

2023, Vol. 37

Issue (17): 22030003-6 https://doi.org/10.11896/cldb.22030003

金属与金属基复合材料

球磨转速对含钆ODS钢中M₂₃C₆析出的影响研究

杨新异^1,2, 黄群英^1,2,*

1 中国科学院合肥物质科学研究院,核能安全技术研究所,合肥 230031
2 中国科学技术大学研究生院科学岛分院,合肥 230026

Effect of Ball Milling Speed on Precipitation of M₂₃C₆ in Gadolinium-containing ODS Steel

YANG Xinyi^1,2, HUANG Qunying^1,2,*

1 Institute of Nuclear Energy Safety Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China
2 Science Island Branch, Graduate School of University of Science and Technology of China, Hefei 230026, China

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摘要以“结构/屏蔽一体化”为研发目标的含钆ODS合金具有较优的中子屏蔽性能与高温力学性能,可作为小型模块化铅冷快堆中子屏蔽材料的研发方向之一。在机械合金化-放电等离子体烧结工艺制备含钆ODS-316L钢的研究中发现,球磨转速影响材料的析出相种类,如在220 r/min低球磨转速下,ODS-316L钢中仅存在纳米尺寸的Gd-Si-O析出相,而在300 r/min高球磨转速下,除纳米尺寸的Gd-Si-O析出相外,材料内还分布着大量百纳米尺寸的片层堆叠状M₂₃C₆型碳化物,且M₂₃C₆内同样存在纳米含钆氧化物颗粒。高球磨转速使球磨粉内元素的偏析与内应力的累积促进了M₂₃C₆的形核,随后的粉末烧结温度则为M₂₃C₆的生长提供了驱动力。此研究可为粉末冶金含钆ODS-316L钢的微观组织调控奠定一定的实验与理论基础。

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关键词: 中子屏蔽合金含钆氧化物弥散强化(ODS)钢粉末冶金球磨转速 M₂₃C₆型碳化物

Abstract: The gadolinium-containing oxide dispersion strengthening (ODS) alloy, which will promisingly be with good neutron shielding performance and elevated-temperature mechanical properties, can be used as one of the shielding materials for the small modular lead-cooled fast reactor. The gadolinium-containing ODS-316L steel was prepared through the powder metallurgy process of mechanical alloying-spark plasma sintering. It was found that the speed of ball-milling affected the types of precipitated phases in the steel. Nano-sized Gd-Si-O precipitates distributed in the ODS-316L steel at a low ball-milling speed of 220 r/min, while hundred-nanometers sized M₂₃C₆ clusters and Gd-Si-O precipitates both distributed in the steel fabricated with high ball-milling speed of 300 r/min. A certain number of nanometer gadolinium-containing oxides distributed in M₂₃C₆ clusters. The segregation of elements and the accumulation of internal stress caused by the high ball-milling speed in as-milled powders were conducive to the nucleation of M₂₃C₆ precipitates, and the temperature of the powder sintering process provided a driving force for the growth of M₂₃C₆ precipitates. This study can provide certain experimental experience and theoretical foundation for the microstructure control of powder metallurgy gadolinium-containing ODS-316L steel.

Key words: neutron shielding alloy gadolinium-containing oxide dispersion strengthening steel powder metallurgy ball mill speed M₂₃C₆ precipitates

出版日期: 2023-09-10 发布日期: 2023-09-05

ZTFLH:	TL344
	TF124

基金资助: 国家重点研发计划项目(2020YFB1901900);中国科学院国际合作局国际伙伴计划(116134KYSB20200056);安徽省“115”产业创新团队项目

通讯作者: *黄群英,中国科学院合肥物质科学研究院二级研究员,博士研究生导师,研究所副总工,享受国务院政府津贴专家。主持先进反应堆结构材料中国低活化马氏体CLAM钢研发、新型屏蔽材料研发、先进堆液态重金属回路研发及相关实验研究等工作。公开发表学术论文220余篇,多篇论文入选“ESI十年全球TOP 1%的高被引论文”“中国百篇最具影响国内学术论文”“第五届中国科协期刊优秀学术论文奖”等,获授权国家发明专利90余项、国际发明专利2项、国家及团体标准5项。qunying.huang@inest.cas.cn

作者简介: 杨新异,2022年4月于中国科学技术大学获得博士学位。从事氧化物弥散强化钢与中子屏蔽合金研究。

引用本文:

杨新异, 黄群英. 球磨转速对含钆ODS钢中M₂₃C₆析出的影响研究[J]. 材料导报, 2023, 37(17): 22030003-6.
YANG Xinyi, HUANG Qunying. Effect of Ball Milling Speed on Precipitation of M₂₃C₆ in Gadolinium-containing ODS Steel. Materials Reports, 2023, 37(17): 22030003-6.

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http://www.mater-rep.com/CN/10.11896/cldb.22030003 或 http://www.mater-rep.com/CN/Y2023/V37/I17/22030003

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