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材料导报  2022, Vol. 36 Issue (21): 21040196-8    https://doi.org/10.11896/cldb.21040196
  无机非金属及其复合材料 |
SrTiO3基可逆固体氧化物电池电极材料的研究进展
刘峥嵘, 杨甲铭, 付磊, 周礼凯, 吴可, 李晴皓, 王璇, 周峻*, 吴锴
西安交通大学电气工程学院,新型储能与能量转换纳米材料研究中心,西安 710049
Research Progress of SrTiO3-based Electrodes for Reversible Solid Oxide Cells
LIU Zhengrong, YANG Jiaming, FU Lei, ZHOU Likai, WU Ke, LI Qinghao, WANG Xuan, ZHOU Jun*, WU Kai
Research Center of Novel Energy Storage and Energy Conversion Nanomaterials, School of Electrical Engineering, Xi'an Jiaotong University, Xi'an 710049, China
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摘要 可逆固体氧化物电池(RSOC) 因具备高效可逆的发电和电解产氢性能,被认为是一种具有良好发展前景的能源转化设备。然而,缺乏高活性和稳定性的电极材料是限制RSOC广泛应用的主要因素之一。传统的燃料电极一般采用浸镍的氧化钇稳定氧化锆(Ni-YSZ)材料,而氧电极则以钙钛矿型的氧化物居多。目前使用的燃料电极和氧电极的电化学性能都存在一定的不足。近期,诸多研究报道SrTiO3基钙钛矿材料具有良好的稳定性和电化学性能,有望成为RSOC电极的热门候选材料。近年来,虽然对RSOC电极的研究较多,但是缺乏对该类材料系统的归纳和总结。因此,本文综述了SrTiO3基钙钛矿材料在RSOC电极方面的应用进展。首先,系统分析了SrTiO3基钙钛矿材料在RSOC燃料电极和氧电极的研究现状,介绍了目前常用的SrTiO3改性的手段和策略,如掺杂其他元素、构建非ABO3化学计量比氧化物、构建复合材料以及利用原位纳米颗粒出溶技术等;其次,探讨了SrTiO3基钙钛矿材料应用于对称结构RSOC电极的可行性;最后,结合构建未来新一代RSOC高性能能源互联器件,展望了SrTiO3基钙钛矿材料在RSOC中的应用前景,并提出了亟需解决的问题。
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刘峥嵘
杨甲铭
付磊
周礼凯
吴可
李晴皓
王璇
周峻
吴锴
关键词:  可逆固体氧化物电池(RSOC)  固体氧化物燃料电池(SOFC)  固体氧化物电解池(SOEC)  钛酸锶    
Abstract: Reversible solid oxide cell (RSOC) is an energy conversion device with high efficiency of reversible power generation and electrolytic hydrogen generation, which is considered as a new energy conversion device with good development prospects. However,there are still some technical problems to be solved, as the lack of highly active and stable electrode materials currently limits the wide application of RSOC. Traditionally, the fuel electrode generally uses nickel-yttrium-stabilized zirconia (Ni-YSZ) materials, while there are many types of oxides that can be used as the oxygen electrode. The electrochemical properties of both fuel electrodes and oxygen electrodes have to be further improved. In recent years lots of works reported that SrTiO3-based perovskite material is a typical of electrode material with good performance in RSOC, which has become a popular candidate material to solve the RSOC electrode problem. However, there is a lack of systematic summary of this kind of materials. Therefore, the application progress of SrTiO3-based perovskite materials as the RSOC electrode is reviewed in this paper. Firstly, the study of SrTiO3-based perovskite materials used as RSOC fuel and oxygen electrodes is systematically analyzed, and the methods and measures commonly used for SrTiO3 modification, such as doping, nonstoichiometric ratio, recombination and a new method: in situ precipitation, are introduced. Secondly, the feasibility of applying SrTiO3-based perovskite for RSOC electrodes with a symmetrical structure is discussed. Finally, from the perspective of the construction of a new generation of high-performance RSOC for energy internet in the future, the application prospect and the problems to be solved of SrTiO3-based perovskite materials in RSOC are predicted.
Key words:  reversible solid oxide cell (RSOC)    solid oxide fuel cell (SOFC)    solid oxide electrolysis cell (SOEC)    strontium titanate
出版日期:  2022-11-10      发布日期:  2022-11-03
ZTFLH:  TQ152  
基金资助: 国家自然科学基金(51737011;51877173);国家电网有限公司科技项目(SGSDJN00FZQT1700446)
通讯作者:  * zhoujun@mail.xjtu.edu.cn   
作者简介:  刘峥嵘,2020年6月毕业于西安交通大学,获得工学和管理学学士学位。现为西安交通大学电气工程学院硕士研究生,在周峻副教授的指导下进行科研工作。目前主要从事固体氧化物燃料电池高性能材料研究。
周峻,2007年毕业于兰州理工大学,获得工学学士学位。2010年毕业于兰州大学,获得材料物理学硕士学位。2014年毕业于西安交通大学,获得电气工程博士学位。现为西安交通大学电气工程学院副教授、博士研究生导师。研究方向为新能源系统的优化、新能源器件及材料。发表SCI、EI论文60余篇。
引用本文:    
刘峥嵘, 杨甲铭, 付磊, 周礼凯, 吴可, 李晴皓, 王璇, 周峻, 吴锴. SrTiO3基可逆固体氧化物电池电极材料的研究进展[J]. 材料导报, 2022, 36(21): 21040196-8.
LIU Zhengrong, YANG Jiaming, FU Lei, ZHOU Likai, WU Ke, LI Qinghao, WANG Xuan, ZHOU Jun, WU Kai. Research Progress of SrTiO3-based Electrodes for Reversible Solid Oxide Cells. Materials Reports, 2022, 36(21): 21040196-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21040196  或          http://www.mater-rep.com/CN/Y2022/V36/I21/21040196
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