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材料导报  2022, Vol. 36 Issue (13): 21020114-12    https://doi.org/10.11896/cldb.21020114
  无机非金属及其复合材料 |
基于镁热还原硅藻土的硅基复合材料在电子器件中的应用
张育新*, 葛广谞, 席乾, 刘川燕, 饶劲松, 姚克欣
重庆大学材料科学与工程学院,重庆 400044
Application of Diatomosilicate Matrix Composites via Magnesium Thermal Reduction in Electronic Devices
ZHANG Yuxin*, GE Guangxu, XI Qian, LIU Chuanyan, RAO Jinsong, YAO Kexin
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
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摘要 硅藻土凭借其天然的三维介孔及仿生结构、低合成成本等优势,逐渐成为了多学科交叉的研究热点之一。然而,其主要成分非晶态二氧化硅导致的高电阻率极大地限制了其在电子器件中的应用,通过改质处理的方法,硅藻土可以在保持原有结构的条件下转化为高电导率的硅藻硅,进而拓展其在电子器件中的应用。镁热还原法因操作简单、成本低且无污染而受到广泛关注。为了提高硅藻硅的产率与性能,减少Mg2SiO4、Mg2Si等中间产物的生成,研究者们在反应温度、反应时间、硅源与镁源的混合方式、原料物质的量比、慢化剂、原料种类等方面不断进行尝试和调控,最终确定了反应温度及反应时间等参数的最佳范围,促进了硅藻硅的高效规模化制备。
通过镁热还原制备的硅藻硅具有良好的结构稳定性、大的比表面积、天然的高孔隙率等优势,因此在锂电池、超级电容器、太阳能电池等电子器件中得到了极大的发展与应用。将镁热还原的硅藻硅作为锂离子电池的负极可有效解决电池在充放电过程中体积膨胀的问题。与其他的纳米结构相比,硅藻硅易于制备,在进一步负载电化学活性材料后拥有更高的电容量和循环稳定性。同时,硅藻硅的高孔隙率也促进了电化学活性材料的吸附和沉积,使其在超级电容器和太阳能电池的应用上展示出显著的优势。此外,硅藻硅良好的生物兼容性和发光特性使其在生物医药方面也有独特的应用。
本文综述了镁热还原硅藻土方法的发展和改进研究,各种电子器件(锂离子电池、超级电容器、太阳能电池、生物传感器等)应用硅藻硅的研究现状,最后展望了硅藻土镁热还原制备多孔硅的发展趋势。
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张育新
葛广谞
席乾
刘川燕
饶劲松
姚克欣
关键词:  硅藻土  镁热反应  复合材料  锂电池  电子器件    
Abstract: Diatomite has gradually become one of the hotspots in the interdisciplinary research by virtue of its natural three-dimensional mesoporous and bionic structure, low synthesis cost and other advantages. However, the main component of diatomite is amorphous SiO2, whose high resistivity greatly limits its application in electronic devices. Through the modifying process, diatomite can be converted into diatom-based silicon with high conductivity while maintaining the original structure, thereby promoting its application in electronic devices. The magnesiothermic reduction has attracted wide attention because of its simple operation, low cost and pollution-free. In order to promote the yield and performance of silicon and reduce the generation of intermediate products such as Mg2SiO4 and Mg2Si, researchers have experimented on the reaction temperature, the reaction time, the mixing mode of the silicon source and the magnesium source, the molar ratio of the raw materials, the moderator, the variety of raw materials, etc. Finally, the optimal range of parameters such as reaction temperature and reaction time are determined, which promotes the efficient large-scale preparation of diatom-based silicon.
Diatom-based silicon prepared by magnesiothermic reduction has been greatly developed and applied for electronic devices such as lithium batteries, supercapacitors and solar cells due to its excellent structural stability,large specific surface area, natural microporosity and so on. Moreover, it can be used as the negative electrode of lithium-ion batteries, effectively solving the problem of volume expansion during charging and discharging. The preparation of diatom-based silicon is simpler, compared with other nanostructures, and it has higher capacity and cycle stability after further loading electrochemically active materials. Besides, the high porosity of diatom-based silicon facilitates the adsorption and deposition of electrochemically active materials, giving it significant advantages in the application of supercapacitors and solar cells; in addition, it has unique application of biomedicine because of excellent biocompatibility and luminescence properties.
This paper summarizes the development and improvement of the magnesiothermic thermal reduction of diatomite, and the research status of the application of diatom-based silicon in various electronic devices (lithium ion batteries, supercapacitors, solar cells, biosensors, etc.). Finally, the development trend of the preparation of porous silicon from diatomite by magnesium thermal reduction is prospected.
Key words:  diatomite    magnesiothermic reduction    composite material    lithium ion battery    electronic device
出版日期:  2022-07-10      发布日期:  2022-07-12
ZTFLH:  TB34  
基金资助: 国家自然科学基金(U1801254)
通讯作者:  * zhangyuxin@cqu.edu.cn   
作者简介:  张育新,重庆大学材料科学与工程学院教授、博士研究生导师。分别于2000年和2003年本科和硕士毕业于天津大学化工学院,2008年博士毕业于新加坡国立大学化学与生物分子工程系,随后继续在曾华淳教授课题组从事博士后研究直到2009年。主要研究兴趣包括纳米材料的制备与应用、超级电容器电极材料的合成与形貌控制、光催化材料的先进设计及性能研究。在Nature Chemistry、Journal of the American Chemical Society、Advanced Materials、ACS Nano等期刊上共发表SCI论文190余篇。
引用本文:    
张育新, 葛广谞, 席乾, 刘川燕, 饶劲松, 姚克欣. 基于镁热还原硅藻土的硅基复合材料在电子器件中的应用[J]. 材料导报, 2022, 36(13): 21020114-12.
ZHANG Yuxin, GE Guangxu, XI Qian, LIU Chuanyan, RAO Jinsong, YAO Kexin. Application of Diatomosilicate Matrix Composites via Magnesium Thermal Reduction in Electronic Devices. Materials Reports, 2022, 36(13): 21020114-12.
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http://www.mater-rep.com/CN/10.11896/cldb.21020114  或          http://www.mater-rep.com/CN/Y2022/V36/I13/21020114
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