2-氨基苯并咪唑缩对甲基苯甲醛席夫碱的合成及缓蚀性能

doi:10.11896/cldb.20080210

材料导报

2021, Vol. 35

Issue (20): 20195-20199 https://doi.org/10.11896/cldb.20080210

高分子与聚合物基复合材料

2-氨基苯并咪唑缩对甲基苯甲醛席夫碱的合成及缓蚀性能

卢爽, 刘琳, 谢锦印, 武亚琪, 邢锦娟

渤海大学化学与材料工程学院,锦州 121013

Corrosion Inhibition Behavior and Synthetic of 2-aminobenzimidazole- p-tolualdehyde

LU Shuang, LIU Lin, XIE Jinyin, WU Yaqi, XING Jinjuan

College of Chemical and Material Engineering, Bohai University, Jinzhou 121013, China

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摘要采用静态失重、极化曲线、交流阻抗(EIS)方法测试席夫碱自组装膜在3.5%(质量分数) NaCl溶液中对铜的缓蚀作用,考察了浓度和时间两个因素。结果表明,当浓度为15 mmol/L,组装时间为14 h时,合成的缓蚀剂缓蚀性能较好,缓蚀率可达99.89%。表面形貌分析结果表明,席夫碱化合物在铜表面形成簇状物质。拉曼光谱分析结果表明,席夫碱通过咪唑环和C=N键垂直吸附于金属表面。光学接触角测量结果表明,缓蚀剂表面不易被浸润,疏水性较好。

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	卢爽
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	邢锦娟

关键词: 席夫碱自组装膜拉曼光谱原子力显微镜

Abstract: The corrosion inhibition performance of the Schiff self-assembled film (SAM) in 3.5% NaCl solution was examined by static weight loss, pola-rization curve and electrochemical impedance spectroscopy (EIS). Two factors of concentration and time were studied, respectively. The experiment result expresses when the concentration is 15 mmol/L, the assembly time is 14 h, the corrosion inhibition efficiency is up to 99.89%. Scanning electron microscope (SEM) and atomic force microscopy (AFM) analysis show that the areatus substance form on copper surface. Roman spectroscopy (Raman) analysis reveals that corrosion inhibitors adsorb vertically on the metal surface through the imidazole ring and C=N bond. Optical contact Angle (OCA) represent that corrosion inhibitor is not easily infiltrated.

Key words: Schiff base self-assembled film Raman spectrum atomic force microscope

出版日期: 2021-10-25 发布日期: 2021-11-12

ZTFLH:

TG174.42

基金资助: 国家自然科学基金资助项目(21878024);辽宁省高等学校创新团队项目(2018479-14)

通讯作者: liulin@bhu.edu.cn

作者简介: 卢爽,目前正就读于渤海大学应用化学专业,主要从事材料腐蚀与防护领域的研究。
刘琳,工学博士,教授。中国科学院金属研究所博士后。辽宁省高校“应用化学”重点实验室负责人,锦州市政协常委。主要研究功能材料的合成及制备工艺。先后主持完成军工项目、辽宁省自然科学基金等省部级以上项目15项。获国家授权发明专利11项。出版学术著作3部、发表学术论文百余篇。

引用本文:

卢爽, 刘琳, 谢锦印, 武亚琪, 邢锦娟. 2-氨基苯并咪唑缩对甲基苯甲醛席夫碱的合成及缓蚀性能[J]. 材料导报, 2021, 35(20): 20195-20199.
LU Shuang, LIU Lin, XIE Jinyin, WU Yaqi, XING Jinjuan. Corrosion Inhibition Behavior and Synthetic of 2-aminobenzimidazole- p-tolualdehyde. Materials Reports, 2021, 35(20): 20195-20199.

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http://www.mater-rep.com/CN/10.11896/cldb.20080210 或 http://www.mater-rep.com/CN/Y2021/V35/I20/20195

1 Huang H J, Wang Z Q, Gong Y L, et al. Corrosion Science,2017,123,339.
2 Kovačević N, Milošev I, Kokalj A. Corrosion Science,2015,98,457.
3 Sabet B K, Dehghanian C, Yari S. Corrosion Science,2017,126,272.
4 Pan Y C, Wen Y, Guo X Y, et al. Corrosion Science,2013,73,274.
5 Honesty N R, Kardşa G, Gewirth A A. Corrosion Science,2014,83,59.
6 Li L, Zhang X H, Gong S D, et al. Corrosion Science,2015,99,76.
7 Aoufir Y E. Materials and Environmental Sciences,2017,8(9),3290.
8 Finšgar M, Petovar B, Xhanari K, et al. Corrosion Science,2016,111,370.
9 Wang B, Xu L N, Li D Y, et al. Journal of Materials Engineering,2017,45(5),38(in Chinese).
王贝,许立宁,李东阳,等.材料工程,2017,45(5),38.
10 Wang Y, Hu J, Wang T T, et al. Journal of Materials Engineering,2019,47(2),122(in Chinese).
王赟,胡军,王甜甜,等.材料工程,2019,47(2),122.
11 Xie W C, Li J S. Materials Reports B: Research Papers,2019,33(4),1401(in Chinese).
谢婉晨,李建三.材料导报:研究篇,2019,33(4),1401.
12 Du J, Liu Q M, Wang F S, et al. Materials Reports B: Research Papers,2019,33(3),1000(in Chinese).
杜娟,刘青茂,王付胜,等.材料导报:研究篇,2019,33(3),1000.
13 Gao J L, Wu H X, Zhang C J, et al. Chinese Journal of Applied Chemistry,2014,31(3),348(in Chinese).
高金龙,吴海霞,张聪婧,等.应用化学,2014,31(3),348.
14 Zhang J, Liu Z, Liu J,et al. Corrosion & Protection,2014,35(8),775(in Chinese).
张菁,刘峥,刘进,等.腐蚀与防护,2014,35(8),775.
15 Chen X J, Hu Z Y, Zhu H L, et al. Applied Chemical Industry,2019,48(11),2555(in Chinese).
陈肖杰,胡志勇,朱海林,等.应用化工,2019,48(11),2555.
16 Zhao X Q. Applied Chemical Industry,2016,45(8),1509(in Chinese).
赵小庆.应用化工,2016,45(8),1509.
17 King F W, Van Duyne R P, Schatz G C. The Journal of Chemical Phy-sics,1978,69(10),4472.
18 Efrima S, Metiu H. The Journal of Chemical Physics,1979,70(4),1602.
19 Yao J L, Ren B, Huang Z F, et al. Electrochimica Acta,2003,48(9),1263.
20 Gu R A, Hu X W, He Z F. Spectroscopy and Spectral Analysis,1993,13(3),21(in Chinese).
顾仁敖,胡晓娓,何张飞.光谱学与光谱分析,1993,13(3),21.
21 He Z F, Gu R A. Chemical Journal of Chinese Universities,1993,14(1),102(in Chinese).
何张飞,顾仁敖.高等学校化学学报,1993,14(1),102.
22 LI Y, LI G. Journal of Henan Normal University (Natural Science Edition),2016,44(1),87(in Chinese).
李艳,李耿.河南师范大学学报(自然科学版),2016,44(1),87.

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