Research Progress of Ferromagnetic Material/Graphene Composite Wave Absorbing Coating Fabrics
WANG Yi1, GUO Shunde2, LIU Yuanjun1,3,4, ZHAO Xiaoming1,3,4
1 School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China 2 School of Art and Costume, Tiangong University, Tianjin 300387, China 3 Tianjin Key Laboratory of Advanced Textile Composites, Tiangong University, Tianjin 300387, China 4 Tianjin Key Laboratory of Advanced Fiber and Energy Storage Technology, Tianjin 300387, China
Abstract: With the arrival of the information age, electromagnetic(EM) wave has been everywhere in our life. While it bringing convenience to people’s lives, the threat to human health cannot be ignored. EM wave absorbing fabric can be used to make protective clothing for human beings to protect them from the harm of EM waves. Ferromagnetic materials are a kind of absorbing materials with magnetic loss(hysteresis loss, eddy current loss), and partial dielectric loss, which have the advantages of high absorption strength and wide absorption band. However, it has poor oxidation resistance and acid-base pro-perty, high density, large matching thickness, and poor temperature stability. By coating ferromagnetic materials with other functional materials to form a shell core structure, the oxidation resistance and corrosion resistance can be improved, the interfacial polarization between the shell cores can improve the wave absorption performance as well. Graphene has attracted the attention of scholars since its appearance. It has a huge specific surface area, a high proportion of atoms on the surface, and plenty of hanging bonds, it can absorb electromagnetic waves through interfacial polarization and multiple scattering. However, due to its excessive specific surface area and intermolecular forces, it is easy to agglomerate with other substances when recombined, which limits its application. Reduced graphene oxide is usually prepared by the Hummers method and then reduced by reducing agents, which have some structural defects and oxygen-containing functional group residues, solubility and dispersibility. The two excellent materials, ferromagnetic material and graphene, can be used to fabricate the absorbent coated fabric with double loss and a wide absorption band. Most researchers focus on the types of absorbing materials but ignore the effect of absorbing coating on absorbing effect. The magnetic and corrosivity properties of ferromagnetic materials can be used to treat the coating with roughness to enhance multiple reflections or form active sites, to further improve the absorbing performance of coated fabrics. In this paper,based on the research status of ferromagnetic/graphene composite EM wave-absorbing coated fabrics, the structure and EM wave absorbing principle of ferromagnetic materials and graphene are briefly discussed; the methods and research progress of loading ferromagnetic materials and graphene absorbing coatings onto fabrics are described. Finally the optimization methods of the absorbing coating process are summarized.
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2021, Vol. 35 
