层层自组装法制备超疏水/超亲油棉织物及其油水分离性能

doi:10.11896/cldb.20060194

材料导报

2021, Vol. 35

Issue (12): 12190-12195 https://doi.org/10.11896/cldb.20060194

高分子与聚合物基复合材料

层层自组装法制备超疏水/超亲油棉织物及其油水分离性能

杨福生¹, 张振宇¹, 李云清¹, 陈永哲¹, 任永忠¹, 马乐¹, 杨武²

1 兰州工业学院土木工程学院,兰州 730050
2 西北师范大学化学化工学院生态环境相关高分子材料教育部重点实验室,兰州 730070

Fabrication of Superhydrophobic-Superlipophilic Cotton Fabric by Layer Self-assembly Method and Its Oil-water Separation Performance

YANG Fusheng¹, ZHANG Zhenyu¹, LI Yunqing¹, CHEN Yongzhe¹, REN Yongzhong¹, MA Le¹, YANG Wu²

1 School of Civil Engineering, Lanzhou Institute of Technology, Lanzhou 730050, China
2 Key Laboratory of Ecological-environment-related Polymer Materials of Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

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摘要被油污染的水资源严重影响人类健康和生态系统。为得到具有优异油水分离性能的材料,利用层层自组装法,在棉织物表面组装纳米银薄层,随后用十二烷基硫醇修饰,制备了具有超疏水/超亲油性能的棉织物。通过扫描电子显微镜、X射线衍射仪、接触角测试仪、分离效率表征超疏水/超亲油棉织物的微观形貌、表面化学组成、润湿性及油水分离性能。改性后的棉织物表面负载致密的纳米银薄层,水在该表面的接触角高达160°,而油的接触角为0°,显示出其良好的超疏水/超亲油性能;纳米银牢固地附着在棉织物的表面,使其表现出良好的抗磨损性、耐腐蚀性。油水分离测试显示,该棉织物对不同类型油品和水混合物的分离效率达88%以上,且具有较好的循环利用性。此外,该棉织物不仅能分离水上轻油、水下沉油,还能分离轻油-水-沉油三相所形成的混合物。

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	杨福生
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	陈永哲
	任永忠
	马乐
	杨武

关键词: 棉织物超疏水超亲油纳米银油水分离

Abstract: Water resources polluted by oil seriously affect human health and ecosystem. In order to obtain materials with excellent oil-water separation performance, assembling nanometre silver thin layer on the surface of cotton fabric by layer self-assembly method, and modified it with dodecyl mercaptan, then cotton fabric with superhydrophobic-superoleophilic performance is prepared. The microstructure, surface chemical composition, wettability and oil-water separation performance of superhydrophobic- superlipophilic cotton fabric are characterized by scanning electron microscope, X-ray diffractometer, contact angle tester and separation efficiency. The modified cotton fabric is loaded up with dense nano silver layers, the water contact angle is up to 160° and the oil contact angle is 0° on the surface, showing excellent superhydrophobic-superlipophilic performance. Nano-silver is firmly attached to the surface of cotton fabric, showing fine wear resistance and corrosion resistance. The oil-water separation test shows that the cotton fabric not only have a good recycling ability,but also having separation efficiency of different types of oil and water mixtures, and separation efficiency is over 88%. In addition, the cotton fabric can not only separate light oil on water and water sinking oil from water, but also can separate the mixture formed by three phases of light oil-water-sinking oil.

Key words: cotton fabric superhydrophobic superoleophilic nano silver oil-water separation

出版日期: 2021-06-25 发布日期: 2021-07-01

ZTFLH:	TG174.451
	O647.5

基金资助: 2020年度甘肃省省级重点人才项目;甘肃省陇原青年创新创业人才(团队)项目(2020RCXM196);甘肃省高等学校产业支撑项目(2020C-30);甘肃省高等学校创新能力提升项目(2019B-180;2020A-149);国家级大学生创新创业训练计划项目(202011807007);兰州工业学院青年科技创新项目(2020KJ-12;2020KJ-14);兰州工业学院“启智”人才培养计划基金(2019QZ-05;2020QZ-03)

通讯作者: zhzhyu428@163.com;2313907790@qq.com

作者简介: 杨福生,2013年6月毕业于西北师范大学,获得理学硕士学位。于2014年10月至今在兰州工业学院任教,主要从事功能材料领域的研究。
杨武,西北师范大学,教授,博士研究生导师。1998年7月毕业于中国科学兰州化学物理研究所,获理学博士学位。德国马普高分子研究所(美因兹)博士后。主要从事纳米材料、功能材料的制备和表征以及应用研究。发表SCI收录100余篇,申报发明专利8余项,出版专著2部,教材1部。
张振宇,工学博士,教授。2007年5月进入中国科学院兰州化学物理研究所固体润滑国家重点实验室从事博士后研究工作。主要从事耐磨损材料的制备及应用研究。主持和参与国家自然科学资金项目10余项,发表SCI论文30余篇,被邀请为国际材料期刊Tribology Internatio-nal、Suface & Coatings Technology审稿人。

引用本文:

杨福生, 张振宇, 李云清, 陈永哲, 任永忠, 马乐, 杨武. 层层自组装法制备超疏水/超亲油棉织物及其油水分离性能[J]. 材料导报, 2021, 35(12): 12190-12195.
YANG Fusheng, ZHANG Zhenyu, LI Yunqing, CHEN Yongzhe, REN Yongzhong, MA Le, YANG Wu. Fabrication of Superhydrophobic-Superlipophilic Cotton Fabric by Layer Self-assembly Method and Its Oil-water Separation Performance. Materials Reports, 2021, 35(12): 12190-12195.

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http://www.mater-rep.com/CN/10.11896/cldb.20060194 或 http://www.mater-rep.com/CN/Y2021/V35/I12/12190

1 Liu S Z, Liu N, Xiao W Y, et al. Chemical Research in Chinese Universities, 2020, 41(3), 521(in Chinese).
刘帅卓, 刘宁, 肖文艳,等. 高等学校化学学报, 2020, 41(3), 521.
2 Yu T L, Lu S X, Xu W G. Journal of Alloys and Compounds, 2018, 769, 576.
3 Zhao W J, Xiao X Y, Pan G M, et al. Journal of Coatings Technology and Research, 2020, 17(3), 657.
4 Zhang T, Xiao C F, Zhan J, et al. ACS Omega, 2019, 4, 7237.
5 Seth M, Khan H, Bhowmik R, et al. Journal of Sol-Gel Science and Technology, 2020, 94, 127.
6 Ge B, Ren G N, Zhao P F, et al. Science China-Technological Sciences, 2019, 62(12), 2236.
7 Yang M P, Liu W Q, Liang L Y, et al. Cellulose, 2020, 27, 2847.
8 Zhang D G, Li L H, Wu Y L, et al. China Surface Engineering, 2019, 32(1), 31(in Chinese).
张东光, 李陵汉, 吴亚丽, 等. 中国表面工程, 2019, 32(1), 31.
9 Wang B, Lei B H, Tang Y, et al. Journal of Coatings Technology and Research, 2018, 15(3), 611.
10 Hu J T, Gao Q H, Xu L, et al. Fibers and Polymers, 2018, 19(7), 1522.
11 Jiang C, Liu W Q, Yang M P, et al. Journal of Materials Science, 2019, 54, 7369.
12 Liu G Y, Wang W, Yu D. Cellulose, 2019, 26,3529.
13 Li G Q, Mai Z H, Shu X, et al. Advanced Composites and Hybrid Mate-rials, 2019,n2, 254.
14 Mai Z H, Shu X, Li G Q, et al. Cellulose, 2019, 26, 6349.
15 Yang J, Pu Y, He H W, et al. Cellulose, 2019, 26,7507.
16 Yang F S, Zhang Y, Liu X B, et al. Materials Review B: Research Papers, 2020, 34(2), 4132(in Chinese).
杨福生, 张妍, 刘小斌,等. 材料导报:研究篇, 2020, 34(2), 4132.
17 Dashairya L, Barik D D, Saha P J. Journal of Coatings Technology and Research, 2019, 16(4), 1021.
18 Wang M, Peng M, Weng Y X, et al. Cellulose, 2019, 26, 8121.
19 Satilmis B, Uyar T. ACS Applied Nano Materials, 2018, 1(4), 1631.
20 Su X J, Li H Q, Lai X J, et al. ACS Applied Materials & Interfaces, 2017, 33(9), 28089.
21 Jiang H J, Zhang L, Chen J, et al. ACS Nano, 2017, 11(12), 12453.
22 Yu Z P, Zhan B, Dong L M, et al. ACS Applied Nano Materials, 2019, 2(3), 1505.
23 Zhan Z B, Li Z, Yu Z, et al. ACS Omega, 2018, 12(3), 17425.
24 Dimitrakellis P, Patsidis A C, Smyrnakis A,et al. ACS Applied Nano Materials, 2019, 2(5), 2969.
25 Zhang G D, Wu Z H, Xia Q Q, et al. ACS Applied Materials & Interface, 2021, 13(19), 23161.
26 Zhao X, Hao H, Duan Y P, et al. Progress in Organic Coatings, 2019, 135, 417.
27 Li X Y, Zhao S P, Hu W H, et al. Applied Surface Science, 2019, 481, 374.
28 Zhou X, Yu S R, Wang J, et al. Journal of the Taiwan Institute of Che-mical Enginerrs, 2019, 105, 124.
29 Liu S M, Cai T L, Shen X Y, et al. Ceramics International , 2019, 45(17), 21263.
30 Li Y S, Jian J, Jia C S. Langmuir, 2008, 24(18), 9962.
31 Sun Y H, Huang J X, Gao Z G. Chemical Communications, 2019, 55, 13876.
32 Wang Z C, Liu X Q, Guo J, et al.Chemical Communications, 2019, 55, 14486.
33 Wang L, Liu C Y, Huang Q M, et al. Soft Matter, 2019, 15, 9066.
34 Wang Q Z, Liu Y N, Bai Y W, et al. Analytica Chimica Acta, 2019, 1049, 170.
35 Hassan N, Lu S X, Xu W G, et al. Journal of Solid State Chemistry, 2018, 266, 121.
36 Lv Y F, Li Q R, Hou Y T, et al. ACS Sustainable Chemistry & Enginee-ring, 2019, 7, 15002.
37 Hou K, Jin Y, Chen J H, et al. Materials Letters, 2017, 202, 99.
38 Lin Y L, Yi P, Yu M G, et al. Materials Letters, 2018, 230, 219.
39 Liu P S, Niu L Y, Tao X H, et al. Applied Surface Science, 2018, 447, 656.
40 Li J, Kang R, Zhang Y. RSC Advances, 2016, 6, 90824.
41 Guo Z, Zheng X, Tian D. Nanoscale, 2014, 6, 12822.

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