Research Progress of Graphene as Additives of Water-based Lubricants
WANG Yongxin1, HU Yiwen1, ZHAO Haichao1, LI Jinlong1, WANG Chunting1, MAO Jinming2, WANG Liping1, XUE Qunji1
1 Key Laboratory of Marine New Materials and Related Technologies, Key Laboratory of Marine Materials and Protective Technologies of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo 315201, China 2 Zhejiang Fashion Institute of Technology, Ningbo 315201, China
Abstract: With the rapid development of industry and people's increasing emphasis on environmental protection, traditional lubricants can no longer meet people's needs in terms of avoiding environmental pollution,therefore, the environmentally friendly lubricants become an important direction in tribological research.Water-based lubricant has been used as green and eco-friendly lubricant to meet the needs of certain special environments and protect ecological requirements due to the advantages of low cost, excellent cooling performance, biodegradability, and safety performance. However, the shortcomings of water-based lubricant such as low kinematic viscosity, limited lubricating properties and easy corrosion limit the development of water lubrication technology in practical applications, so it is necessary to introduce nano-additives to solve these problems. The graphene-based material is a sheet-structured nanomaterial with excellent mechanical properties, and the sliding between the sheets belongs to ultra-lubricated sliding, so it can be used as a water-based lubricating additive. However, graphene is a stable material composed of a benzene-like ring unit and there is a strong π-π interaction between the sheets, which easily causes aggregate precipitation in water. Therefore, in recent years, many researchers have used different methods to functionally modify graphene-based materials. It has been found that the modified graphene-based materials have better dispersion stability in water-based solutions and maintain the original mechanics of graphene. So it can be used as an additive to significantly improve the lubrication properties of water-based solutions. This paper summarizes the current methods of graphene modification for potential applications of water lubricating additives: (1) the covalently modification of graphene-based materials prepared by chemical reaction between the modified molecule and the oxygen-containing group of graphene oxide. (2) Functional modification of graphene-based materials obtained by non-covalent bonding of π-π interaction, ionic interaction and hydrogen bonding between modified molecules and graphene-based materials.(3) The size control of graphene-based materials. The modified graphene-based water-lubricating additive can effectively reduce the friction coefficient and wear rate of workpieces, and improve the corrosion inhibition efficiency of water-based lubricants. However, the graphene-based materials are used as a water-based lubricant additive which achieve long-term dispersion stability in water also has some challenges. At present, the evaluation system of water-based lubricants mostly adopts the evaluation system of oil-based lubricants, and lacks the test standards and methods for cooling performance and biodegradability. Therefore, it is necessary to establish a complete and systematic evaluation system for graphene-based water lubricating additives.
作者简介: 王永欣,中国科学院宁波材料技术与工程研究所研究员、博士研究生导师。2011年博士毕业于中国科学院兰州化学物理研究所固体润滑国家重点实验室材料学专业,随后就职于中国科学院宁波材料技术与工程研究所表面工程事业部,德国科布伦茨兰道大学访问学者。主要研究方向为摩擦学表界面行为及苛刻工况减摩耐磨涂层材料。在ACS Applied Materials and Interfaces、Carbon、Applied Surface Science、Surface and Coatings Technology、Wear、 Tribology Letters、Tribology International、《表面工程学报》《摩擦学学报》等国内外权威学术期刊上发表论文80余篇。
引用本文:
王永欣, 胡艺纹, 赵海超, 李金龙, 王春婷, 毛金明, 王立平, 薛群基. 石墨烯基水润滑添加剂研究进展[J]. 材料导报, 2021, 35(19): 19055-19061.
WANG Yongxin, HU Yiwen, ZHAO Haichao, LI Jinlong, WANG Chunting, MAO Jinming, WANG Liping, XUE Qunji. Research Progress of Graphene as Additives of Water-based Lubricants. Materials Reports, 2021, 35(19): 19055-19061.
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2021, Vol. 35 
