Research Progress of Polymer Nano-array Thin Films Based on AAO Templates
LU Yawen1, CHANG Shengnan1, LIU Yuanjun1, LIU Hao1,2, ZHAO Xiaoming1, LI Xiaojiu1
1 School of Textile Science and Engineering, Tianjin Polytechnic University, Tianjin 300387 2 Institute of Smart Wearable Electronic Textiles, Tianjin Polytechnic University, Tianjin 300387
Abstract: Nanomaterials refer to an ultra-fine material with a characteristic size or crystal size on the order of nanometers, which is a solid material composed of extremely fine particles. Due to the nanometer size and large specific surface area, nanomaterials have many unique physical and chemical properties, which are widely used in ceramics, catalysis, optics, biomedicine, environmental protection and other fields. Nanomaterials are classified into regular nanomaterials and irregular nanomaterials according to the degree of regularity. Non-regular nanomaterials, such as nanofiber materials prepared by electrospinning, have a high aspect ratio. However, the diameter accuracy of nanofibers having a diameter of less than 100 nm is very difficult. Moreover, the irregular nanomaterials have a low structural orientation. The regular nanomaterials are generally presented in the form of arrays, such as nanorods, nanopillars, nanofibers, nanospheres, and core-shell structure, which have the advantages of high order structure, uniform size, and uniform distribution of nanostructures. The preparation method of the nanomaterial is mainly classified into a physical method (physical pulverization method and physical coagulation method) and a chemical method (precipitation method, sol-gel method, template synthesis method, self-assembly method) according to the preparation means. The size of the nanomaterials produced by the template synthesis method can be precisely controlled, and the template can be reused in a large amount. Therefore, the template synthesis method is often used to prepare regular nanomaterials. In recent years, flexible sensors, nano-generators, supercapacitors, and biomedical detection devices, which are prepared by using nano-array as sensitive components, have attracted much attention due to their high sensitivity, high precision, and miniaturization. In this paper, the preparation methods of porous anodized aluminum oxide (AAO) template and polymer nano-array film are systematically summarized. The advantages, disadvantages and applications of the polymer nano-array film preparation method are summarized. The existing problems and application prospects of polymer nano-array film are also discussed, which provides a reference for the preparation and application of AAO template and polymer nano-array.
鲁亚稳, 常胜男, 刘元军, 刘皓, 赵晓明, 李晓久. 基于AAO模板的高聚物纳米阵列薄膜的研究进展[J]. 材料导报, 2019, 33(23): 3990-3998.
LU Yawen, CHANG Shengnan, LIU Yuanjun, LIU Hao, ZHAO Xiaoming, LI Xiaojiu. Research Progress of Polymer Nano-array Thin Films Based on AAO Templates. Materials Reports, 2019, 33(23): 3990-3998.
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