基于丁二胺盐酸盐钝化的高效钙钛矿/晶硅叠层电池

doi:10.11896/cldb.23070073

材料导报

2024, Vol. 38

Issue (20): 23070073-4 https://doi.org/10.11896/cldb.23070073

无机非金属及其复合材料

基于丁二胺盐酸盐钝化的高效钙钛矿/晶硅叠层电池

何永才^1,2, 丁蕾², 杨莹², 刘江², 何博², 张永哲¹, 严辉^1,*, 徐希翔²

1 北京工业大学材料与制造学部,北京 100124
2 隆基绿能科技股份有限公司隆基中央研究院,西安 710100

High Performance Perovskite/Silicon Tandem Solar Cells Based on 1, 4-Diaminobutane Dihydrochloride

HE Yongcai^1,2, DING Lei², YANG Ying², LIU Jiang², HE Bo², ZHANG Yongzhe¹, YAN Hui^1,*, XU Xixiang²

1 The Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China
2 LONGi Central Research and Development Institute, LONGi Green Energy Technology Co., Ltd., Xi’an 710100, China

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摘要钙钛矿/硅异质结叠层电池技术是突破晶体硅太阳电池极限效率的重要途径。在叠层电池中,多晶钙钛矿膜层内缺陷中心将诱导光生载流子复合损失,因而对钙钛矿膜层内缺陷进行钝化是提升叠层电池光电转换效率的有效策略。本工作采用在钙钛矿前驱体内掺入1,4-丁二胺盐酸盐的方法,通过引入氯离子实现结晶调控提高钙钛矿结晶质量,同时发现丁二胺阳离子对钙钛矿膜层缺陷中心显示出良好的钝化效果,两者协同作用显著提升叠层电池的开路电压(V_oc)和填充因子(FF),并最终成功获得了28.77%的NREL认证效率。

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	何永才
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	何博
	张永哲
	严辉
	徐希翔

关键词: 1,4-丁二胺盐酸盐缺陷钝化钙钛矿叠层电池

Abstract: Perovskite/silicon heterojunction tandem solar cell has been regarded as a promising strategy to break the inherent Shockley-Queisser limit imposed on single-junction solar cells. However, the existence of defects within the multi-crystalline perovskite active layer would form additional recombination centers for photo-generated carriers, and bring about unfavorable losses to the performance of solar cells. Therefore, it is both necessary and significant to explore effective passivation approaches. In this work, we adopt 1, 4-diaminobutane dihydrochloride by mixing it into the perovskite precursor and found this could optimize the performance of monolithic perovskite/silicon tandem solar cells. Ultimately, the synergistic effects contributed by the component chloride ion and diaminobutane of 1, 4-diaminobutane dihydrochloride improve both the open-circuit voltage and fill factor, and this help us to achieve a certified PCE of 28.77% by NREL.

Key words: 1, 4-diaminobutane dihydrochloride defect passivation perovskite tandem solar cell

出版日期: 2024-10-25 发布日期: 2024-11-05

ZTFLH:

TK514

基金资助: 国家自然科学基金(62034001)

通讯作者: * 严辉,北京工业大学材料科学与工程学院教授、博士研究生导师。目前主要从事新型电子材料、高效光伏材料及器件等方面的研究工作,在Nature Energy、Nature Communications、Advanced Materials、Advanced Energy Materials、Small、Solar Energy等学术期刊发表论文1 000余篇。hyan@bjut.edu.cn

作者简介: 何永才,2015年6月、2018年6月分别于西华大学和北京工业大学获得工学学士学位和硕士学位。现为北京工业大学信息科学与工程学院博士研究生,在严辉教授的指导下进行研究。目前主要研究领域为高效光伏器件结构及材料研究。

引用本文:

何永才, 丁蕾, 杨莹, 刘江, 何博, 张永哲, 严辉, 徐希翔. 基于丁二胺盐酸盐钝化的高效钙钛矿/晶硅叠层电池[J]. 材料导报, 2024, 38(20): 23070073-4.
HE Yongcai, DING Lei, YANG Ying, LIU Jiang, HE Bo, ZHANG Yongzhe, YAN Hui, XU Xixiang. High Performance Perovskite/Silicon Tandem Solar Cells Based on 1, 4-Diaminobutane Dihydrochloride. Materials Reports, 2024, 38(20): 23070073-4.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23070073 或 http://www.mater-rep.com/CN/Y2024/V38/I20/23070073

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