高结晶度g-C3N4在光催化领域的研究进展

doi:10.11896/cldb.23060180

材料导报

2024, Vol. 38

Issue (21): 23060180-13 https://doi.org/10.11896/cldb.23060180

无机非金属及其复合材料

高结晶度g-C₃N₄在光催化领域的研究进展

徐杨^1,2, 刘成宝^1,2,3,*, 郑磊之^1,2,3, 陈丰^1,2,3, 钱君超^1,2,3, 邱永斌⁴, 孟宪荣⁵, 陈志刚^1,2,3

1 苏州科技大学江苏省环境功能材料重点实验室, 江苏苏州 215009
2 苏州科技大学材料科学与工程学院, 江苏苏州 215009
3 苏州科技大学江苏水处理技术与材料协同创新中心, 江苏苏州 215009
4 江苏省陶瓷研究所有限公司, 江苏宜兴 214221
5 苏州市环境科学研究所, 江苏苏州 215007

Research Progress of High Crystallinity g-C₃N₄ in Photocatalysis

XU Yang^1,2, LIU Chengbao^1,2,3,*, ZHENG Leizhi^1,2,3, CHEN Feng^1,2,3, QIAN Junchao^1,2,3, QIU Yongbin⁴, MENG Xianrong⁵, CHEN Zhigang^1,2,3

1 Jiangsu Key Laboratory for Environment Functional Materials, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
2 School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
3 Jiangsu Collaborative Innovation Center of Technology and Material for Water Treatment, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
4 Jiangsu Province Ceramics Research Institute Co., Ltd.,Yixing 214221, Jiangsu, China
5 Suzhou Institute of Environmental Science, Suzhou 215007, Jiangsu, China

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摘要石墨相氮化碳(g-C₃N₄)作为具有典型二维层状结构和窄带隙的聚合物半导体,表现出优异的可见光吸收能力、稳定的物理化学性能和优良的光催化活性。然而,传统含氮前驱体热诱导聚合产生的g-C₃N₄结构不完全,主体是非晶或半晶质结构的melon基氮化碳,其体相和表面存在较多缺陷,导致电导率低、限制光激发电荷的分离以及电子-空穴对重组率较高,大幅降低了其催化活性,因此提高g-C₃N₄的结晶度是非常有必要的。本文主要总结了高结晶度氮化碳(CCN)的优势和近年来的研究进展,提高g-C₃N₄的结晶度不仅能在共轭平面之间建立电荷转移通道,从而提高层内电荷转移效率,而且可以与其他改性手段糅合以实现高效的协同效应。同时,通过介绍CCN的结构、表征、制备方法、改性策略和应用领域对CCN近年来的研究进展进行总结。最后,简要总结了CCN光催化材料面临的挑战和本领域未来的发展方向。

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	徐杨
	刘成宝
	郑磊之
	陈丰
	钱君超
	邱永斌
	孟宪荣
	陈志刚

关键词: 半导体光催化技术石墨相氮化碳高结晶度

Abstract: Graphite phase carbon nitride (g-C₃N₄), a polymer semiconductor with a typical two-dimensional layered structure and narrow band gap, has excellent visible light absorption capacity, stable physical and chemical properties and good photocatalytic properties. However, the structure of g-C₃N₄ produced by the heat-induced polymerization from traditional nitrogen-containing precursor is incomplete. The main body is melon-based carbon nitride with amorphous or semi-crystalline structure. There are many defects in its phase and surface, which lead to lower conductivity, higher electron-hole pairs recombination rate, resulting in lower catalytic activity. Therefore, it is necessary to improve the crystallinity of g-C₃N₄. This paper mainly summarizes the advantages of high crystalline carbon nitride (CCN) and the research progress in recent years. Increasing the crystallinity of g-C₃N₄ can provide charge transfer channels between the conjugated planes to improve the charge transfer efficiency, and also introduce other modification methods to achieve efficient synergies. Then, the structure, characterization, preparation, modification strategy and application fields of CCN in recent years were reviewed. Finally, the challenges and future development directions of CCN photocatalysts are summarized briefly.

Key words: semiconductor photocatalytic technology graphite carbon nitride high crystallinity

出版日期: 2024-11-10 发布日期: 2024-11-11

ZTFLH:

TB34

基金资助: 江苏省自然科学基金(BK20180103;BK20180971);苏州市科技发展计划项目(SS202036)

通讯作者: *王林山,中国有研科技集团有限公司正高级工程师、硕士研究生导师。2000年7月和2003年6月毕业于中南大学粉末冶金研究院分别获工学学士学位和工学硕士学位。主要从事粉末冶金材料与零件、金属粉末高效热管理材料等方面的研究、产品开发和产业化。截至目前,已发表论文40余篇,作为副主编出版“十一五”国家重点图书《铜及铜合金粉末与制品》,制修订国家或行业标准10项,获得省部级奖5项。Lcb@mail.usts.edu.cn

作者简介: 徐杨,2022年6月毕业于常熟理工学院,获得工学学士学位。现为苏州科技大学材料科学与工程学院硕士研究生,在刘成宝副教授的指导下进行研究。目前主要研究领域为二维基功能材料的结构设计及性能评价。

引用本文:

徐杨, 刘成宝, 郑磊之, 陈丰, 钱君超, 邱永斌, 孟宪荣, 陈志刚. 高结晶度g-C₃N₄在光催化领域的研究进展[J]. 材料导报, 2024, 38(21): 23060180-13.
XU Yang, LIU Chengbao, ZHENG Leizhi, CHEN Feng, QIAN Junchao, QIU Yongbin, MENG Xianrong, CHEN Zhigang. Research Progress of High Crystallinity g-C₃N₄ in Photocatalysis. Materials Reports, 2024, 38(21): 23060180-13.

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http://www.mater-rep.com/CN/10.11896/cldb.23060180 或 http://www.mater-rep.com/CN/Y2024/V38/I21/23060180

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