全无机铯铅卤钙钛矿纳米晶的表面包覆策略及白光LED应用研究进展

doi:10.11896/cldb.22120172

材料导报

2024, Vol. 38

Issue (11): 22120172-11 https://doi.org/10.11896/cldb.22120172

无机非金属及其复合材料

全无机铯铅卤钙钛矿纳米晶的表面包覆策略及白光LED应用研究进展

梁梦标¹, 陈婷^1,*, 秦喆¹, 谢志翔¹, 徐彦乔², 温鹏¹, 林坚¹, 郭春显¹

1 苏州科技大学材料科学与工程学院,江苏苏州 215009
2 景德镇陶瓷大学材料科学与工程学院,江苏景德镇 333001

Surface Coating Strategy and White LED Applications Progress of All-inorganic Cesium Lead Halide Perovskites Nanocrystals

LIANG Mengbiao¹, CHEN Ting^1,*, QIN Zhe¹, XIE Zhixiang¹, XU Yanqiao², WEN Peng¹, LIN Jian¹, GUO Chunxian¹

1 School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
2 School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, Jiangsu, China

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摘要全无机铯铅卤钙钛矿纳米晶CsPbX₃(X=Cl、Br、I)具有量子产率高、载流子寿命长、带隙窄、光谱可调范围广等优异的光电性能,在发光二极管(LED)、太阳能电池、光电探测等领域有着广阔的应用前景。然而,由于离子化合物的本征特性,其在水分、光照以及温度的作用下不能稳定存在,严重阻碍了该纳米晶在光电领域的应用。近年来,科研工作者相继报道了各种提高钙钛矿纳米晶稳定性的方法,如离子掺杂、表面钝化和表面包覆等策略。与离子掺杂和表面钝化相比,表面包覆策略不仅隔离了环境因素对CsPbX₃纳米晶的影响,还阻止了不同阴离子组分的钙钛矿纳米晶间的阴离子交换,提高了纳米晶的稳定性。因此,本文详细介绍了全无机铯铅卤钙钛矿纳米晶的包覆机理,同时重点从聚合物薄膜、氧化物、金属有机框架和沸石等包覆材料层面介绍表面包覆策略的优越性,最后总结了复合材料在照明和显示领域的应用。

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	梁梦标
	陈婷
	秦喆
	谢志翔
	徐彦乔
	温鹏
	林坚
	郭春显

关键词: 全无机铯铅卤钙钛矿纳米晶稳定性表面包覆荧光

Abstract: All-inorganic cesium lead halide perovskite nanocrystals CsPbX₃ (X=Cl,Br,I) exhibit excellent photoelectric properties, such as high photoluminescence quantum yield, long carrier lifetime, narrow emission line width, and adjustable band gap. They show great application prospects in the fields of light-emitting diodes (LED), solar cells, photoelectric detection, etc. However, perovskite nanocrystals present poor stability under the conditions of water, light and temperature due to the inherent ionic features, which seriously hinders the application of nanocrystals in the field of optoelectronics. In recent years, researchers have reported various methods to improve the stability of perovskite nanocrystals, including ion doping, surface passivation and surface coating. Compared with ion doping and surface passivation, the surface coating strategy not only isolates the CsPbX₃ nanocrystals from the environment, but also avoids their anion exchange from different anionic components of perovskite nanocrystals, and thus significantly improves the stability of nanocrystals. Therefore, we introduce the coating mechanism of all inorganic cesium lead halide perovskite nanocrystals in detail, and focus on the advantages of this strategy from the aspects of polymer films, oxides, metal orga-nic frameworks, zeolite and other coating materials. Finally, the applications of coating materials in lighting and display are summarized.

Key words: all-inorganic cesium lead halide perovskite nanocrystals stability surface coating fluorescence

发布日期: 2024-06-25

ZTFLH:	O471.1
	TB383

基金资助: 国家自然科学基金(52062019;22001187);江苏省高校青蓝工程

通讯作者: *陈婷,苏州科技大学副教授、硕士研究生导师。2005年云南大学材料物理专业本科毕业,2008年云南大学材料学专业硕士毕业,2012年北京科技大学材料学专业博士毕业。2020年到苏州科技大学工作至今。目前主要从事荧光量子点方面的研究工作。以第一作者和通信作者身份在国内外高质量期刊上发表70篇原创高水平科研论文。chenting@mail.usts.edu.cn

作者简介: 梁梦标,2018年毕业于江苏科技大学,获得工学学士学位。现为苏州科技大学材料科学与工程学院硕士,在陈婷副教授的指导下进行研究。目前主要研究领域为全无机铯铅卤钙钛矿纳米晶。

引用本文:

梁梦标, 陈婷, 秦喆, 谢志翔, 徐彦乔, 温鹏, 林坚, 郭春显. 全无机铯铅卤钙钛矿纳米晶的表面包覆策略及白光LED应用研究进展[J]. 材料导报, 2024, 38(11): 22120172-11.
LIANG Mengbiao, CHEN Ting, QIN Zhe, XIE Zhixiang, XU Yanqiao, WEN Peng, LIN Jian, GUO Chunxian. Surface Coating Strategy and White LED Applications Progress of All-inorganic Cesium Lead Halide Perovskites Nanocrystals. Materials Reports, 2024, 38(11): 22120172-11.

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http://www.mater-rep.com/CN/10.11896/cldb.22120172 或 http://www.mater-rep.com/CN/Y2024/V38/I11/22120172

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