原位生成周期性层片结构镀层及其在NaCl溶液中的腐蚀形貌

doi:10.11896/cldb.22110026

材料导报

2024, Vol. 38

Issue (12): 22110026-7 https://doi.org/10.11896/cldb.22110026

金属与金属基复合材料

原位生成周期性层片结构镀层及其在NaCl溶液中的腐蚀形貌

张先满^*, 李星涛, 季坤鹏, 陈再雨, 罗洪峰

海南大学机电工程学院,海口 570228

Periodic Layered Structure Coating Formed In-situ and Its Corrosion Morphology in NaCl Solution

ZHANG Xianman^*, LI Xingtao, JI Kunpeng, CHEN Zaiyu, LUO Hongfeng

School of Mechanical and Electrical Engineering, Hainan University, Haikou 570228, China

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摘要金属在海洋氯离子环境中极易发生腐蚀,并造成巨大的经济损失。通过制备新型Fe-Cr-B铸钢,采用热浸镀铝-扩散热处理原位生成含有周期性层片结构(PLSs)的镀层,并利用扫描电子显微镜(SEM)、电子探针X射线显微分析仪(EPMA)等手段研究了该镀层的组织结构及其在3.5%(质量分数) NaCl溶液中的腐蚀行为。结果表明,该铸钢的显微组织主要由粗大的初生(Cr,Fe)₂B及α-Fe组成;热浸镀铝时在(Cr,Fe)₂B/Al界面上生成由FeAl₃和Cr-Al-B相组成的PLSs,在α-Fe/Al界面上生成FeAl₃;扩散热处理使得反应层增厚,且PLSs在反应层中大量生成;相比FeAl₃,镀层中的PLSs在腐蚀过程中充当阳极优先腐蚀,并表现出腐蚀各向异性,尤其是其中的Cr-Al-B相可明显阻挡氯离子腐蚀,使得PLSs通过延长腐蚀路径进而提高镀层的耐氯离子腐蚀性能。

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关键词: Fe-Cr-B铸钢热浸镀铝扩散热处理周期性层片结构(PLSs) 氯离子

Abstract: Metals corrode easily in marine environments containing chloride ions, thus causing considerable economic losses. A novel Fe-Cr-B cast steel was prepared, and the periodic layered structures (PLSs) coating was formed in-situ by hot-dip aluminizing and thermal diffusion treatment of the Fe-Cr-B cast steel. The microstructure and corrosion behavior of the coating in a 3.5wt% NaCl solution were studied using SEM and EPMA. The results showed that the cast steel microstructure was mainly composed of coarse primary (Cr, Fe)₂B and α-Fe. During hot-dip aluminizing, the PLSs composed of FeAl₃and Cr-Al-B phase formed at the (Cr, Fe)₂B/Al interface. While, FeAl₃ formed at the α-Fe/Al interface. The thermal diffusion treatment thickened the reaction layer, in which the PLSs were formed in large quantities. Compared with FeAl₃, the PLSs in the coating acted as the anode in the corrosion process and exhibited corrosion anisotropy. This study demonstrates that the Cr-Al-B phase in PLSs can significantly block chloride ion corrosion, so that the PLSs improve the chloride-ion corrosion resistance of the coating by prolonging the corrosion path.

Key words: Fe-Cr-B cast steel hot-dip aluminizing thermal diffusion treatment periodic layered structures (PLSs) chloride ion

出版日期: 2024-06-25 发布日期: 2024-07-17

ZTFLH:

TB37

基金资助: 海南省自然科学基金(420RC522;521RC503;517076);国家自然科学基金(42066003;51701053)

通讯作者: *张先满,海南大学机电工程学院副教授、博士、硕士研究生导师。2015年12月在华南理工大学机械与汽车工程学院材料加工工程专业获得博士学位。主要从事金属材料及其耐蚀性研究。近年来,在Corrosion Science等期刊上发表SCI论文多篇。xianman213@163.com

引用本文:

张先满, 李星涛, 季坤鹏, 陈再雨, 罗洪峰. 原位生成周期性层片结构镀层及其在NaCl溶液中的腐蚀形貌[J]. 材料导报, 2024, 38(12): 22110026-7.
ZHANG Xianman, LI Xingtao, JI Kunpeng, CHEN Zaiyu, LUO Hongfeng. Periodic Layered Structure Coating Formed In-situ and Its Corrosion Morphology in NaCl Solution. Materials Reports, 2024, 38(12): 22110026-7.

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http://www.mater-rep.com/CN/10.11896/cldb.22110026 或 http://www.mater-rep.com/CN/Y2024/V38/I12/22110026

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