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材料导报  2024, Vol. 38 Issue (12): 22100251-9    https://doi.org/10.11896/cldb.22100251
  无机非金属及其复合材料 |
功能化MXene在锂硫电池中应用研究进展
姜宇1,2, 杨蓉1,2,*, 张乾伟1,2, 樊潮江1,2, 董鑫1,2, 蒋百铃2, 燕映霖1
1 西安理工大学复合材料及其产品智能制造技术国际联合研究中心,西安 710048
2 西安理工大学材料科学与工程学院,西安 710048
Research Progress of the Use of Functionalized MXene in Lithium-Sulfur Batteries
JIANG Yu1,2, YANG Rong1,2,*, ZHANG Qianwei1,2, FAN Chaojiang1,2, DONG Xin1,2, JIANG Bailing2, YAN Yinglin1
1 China International Research Center for Composite and Intelligent Manufacturing Technology, Xi'an University of Technology, Xi'an 710048, China
2 School of Materials Science and Engineering, Xi'an University of Technology, Xi'an 710048, China
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摘要 MXene作为新兴的二维导电材料,在储能器件的电极和电解质设计及应用等方面引起了科研人员的兴趣。近年来,在锂硫电池研究中,MXene材料优异的导电性及对多硫化物的吸附作用使锂硫电池的性能明显提升。功能化设计可避免MXene材料自堆叠等缺陷,调控其对多硫化物的吸附强度,并赋予MXene催化多硫化物氧化还原反应的功能。本文综述了功能化MXene材料目前主要的制备方式及其对表面官能团的影响,分析了功能化MXene对多硫化物的吸附作用和对穿梭效应的抑制机制及对氧化还原反应动力学的提升机理,讨论了MXene材料在锂硫电池应用中可能存在的问题和改性前景。
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姜宇
杨蓉
张乾伟
樊潮江
董鑫
蒋百铃
燕映霖
关键词:  MXene材料  制备  锂硫电池  穿梭效应  催化    
Abstract: As a rising two-dimensional conductive material, MXene has attracted researchers' interest in the design and application of electrodes and electrolytes of energy storage devices. In recent years, the performance of lithium sulfur batteries have significantly improved for the excellent conductivity of MXene material and its adsorption to polysulfides. The functionalized design of MXene can avoid the defects of self-stacking, regulate the adsorption strength of polysulfides, and catalyze the redox reaction of polysulfides. From the perspective of functionalized MXene, the main preparations and their influence on the surface functional group of MXene are reviewed. The adsorption to polysulfides and mechanism of shuttle effect inhibition, and the enhancement mechanism of redox kinetics of functionalized MXene are analyzed. The possible problems and modification prospects of MXene in the application of lithium sulfur batteries are discussed.
Key words:  MXene material    preparation    lithium-sulfur battery    shuttle effect    catalysis
出版日期:  2024-06-25      发布日期:  2024-07-17
ZTFLH:  O646  
基金资助: 国家自然科学基金(51974242);陕西省科技厅一般项目-工业领域(2024GX-YBXM-33);咸阳市科技局重点研发项目(2021ZDYF-GY-0029);中国博士后面上资助项目( 2019M653706)
通讯作者:  *杨蓉,西安理工大学材料科学与工程学院教授、博士研究生导师。2009年于西安交通大学材料物理与化学专业获博士学位,2011年公派至韩国国立庆尚大学中韩博士后交流,2012年公派至美国佐治亚理工学院交流访问。目前主要从事锂硫电池电极材料及电解液、锂硫电池全电池技术、电化学腐蚀与防护等方面的研究工作。近年来,在电池领域发表论文60余篇,包括ACS Applied Materials & Interfaces、Materials Characterization、Journal of Alloys and Compounds、 Electrochimica Acta等。yangrong@xaut.edu.cn   
作者简介:  姜宇,2018年6月、2021年6月于宝鸡文理学院获得工学学士学位和理学硕士学位。现为西安理工大学材料科学与工程学院博士研究生,在蒋百灵教授及杨蓉教授的指导下进行研究。目前主要研究领域为二维MXene材料在锂硫电池中的应用研究。
引用本文:    
姜宇, 杨蓉, 张乾伟, 樊潮江, 董鑫, 蒋百铃, 燕映霖. 功能化MXene在锂硫电池中应用研究进展[J]. 材料导报, 2024, 38(12): 22100251-9.
JIANG Yu, YANG Rong, ZHANG Qianwei, FAN Chaojiang, DONG Xin, JIANG Bailing, YAN Yinglin. Research Progress of the Use of Functionalized MXene in Lithium-Sulfur Batteries. Materials Reports, 2024, 38(12): 22100251-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22100251  或          http://www.mater-rep.com/CN/Y2024/V38/I12/22100251
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