高比电容MOF衍生的介孔球状Co3O4/NiO/CuO

doi:10.11896/cldb.22110033

材料导报

2024, Vol. 38

Issue (12): 22110033-7 https://doi.org/10.11896/cldb.22110033

无机非金属及其复合材料

高比电容MOF衍生的介孔球状Co₃O₄/NiO/CuO

高雅倩¹, 赵亚娟¹, 谢会东^1,*, 胡昌宇¹, 王逸博¹, 王康康¹, 杨厂²

1 西安建筑科技大学化学与化工学院,西安 710055
2 西安建筑科技大学工程综合实训中心,西安 710055

Mesoporous Spherical Co₃O₄/NiO/CuO Derived from MOF with High Specific Capacitance

GAO Yaqian¹, ZHAO Yajuan¹, XIE Huidong^1,*, HU Changyu¹, WANG Yibo¹, WANG Kangkang¹, YANG Chang²

1 School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
2 Engineering Comprehensive Training Center, Xi'an University of Architecture and Technology, Xi'an 710055, China

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摘要通过溶剂热合成了CoNiCu-MOF金属有机框架化合物,并通过后续的煅烧制备了Co₃O₄/NiO/CuO电极材料。对材料的形貌和比表面积进行表征,并测量了材料在不同扫描速率下的循环伏安曲线和不同电流密度下的恒流充放电曲线以及循环稳定性。将所得材料作为正极,活性炭作为负极组装了超级电容器器件,测量了器件的电化学性能。结果表明:Co₃O₄/NiO/CuO材料具有多孔结构和较大的可用比表面积(50.24 m²·g^-1)。当电流密度为1 A·g^-1时,Co₃O₄/NiO/CuO的比电容高达3 682.2 F·g^-1。所组装的Co₃O₄/NiO/CuO∥AC非对称超级电容器的能量密度在1.45 V的电势窗口内达到186.8 Wh·kg^-1,功率密度高达7 249.8 W·kg^-1。Co₃O₄/NiO/CuO是一种性能优良的超级电容器电极材料,具有广阔的应用前景。

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	王康康
	杨厂

关键词: 超级电容器金属有机框架电化学活性炭

Abstract: CoNiCu-MOF metal-organic frames were synthesized by a solvothermal method, and the Co₃O₄/NiO/CuO electrode materials were prepared by a subsequent calcination of CoNiCu-MOF. The morphology, specific surface area, cyclic voltammetric curves at different scanning speeds, galvanostatic charge/discharge curves at different current densities, and the cyclic stability of the materials were measured. An asymmetric supercapacitor device was assembled with Co₃O₄/NiO/CuO and activated carbon as the positive and negative electrodes, respectively, and its electrochemical properties were measured. Results showed that the Co₃O₄/NiO/CuO material had a porous structure and a large specific surface area (50.24 m²·g^-1). The specific capacitance of Co₃O₄/NiO/CuO was as high as 3 682.2 F·g^-1 at a current density of 1 A·g^-1. The maximum energy density of the assembled Co₃O₄/NiO/CuO∥AC asymmetric supercapacitor achieved up to 186.8 Wh·kg^-1 within a potential window of 1.45 V and a power density of 7 249.8 W·kg^-1. The excellent performance of Co₃O₄/NiO/CuO as a supercapacitor electrode material makes it have a wide application prospect as energy storage devices.

Key words: supercapacitor metal-organic frame electrochemistry activated carbon

出版日期: 2024-06-25 发布日期: 2024-07-17

ZTFLH:

O614

基金资助: 山东省重大科技创新项目(2019JZZY010343)

通讯作者: *谢会东,西安建筑科技大学化学与化工学院教授。1996年7月清华大学化学系物理化学专业本科毕业,2007年7月清华大学化学系化学专业博士毕业到西安建筑科技大学工作至今,目前从事化学与材料方面的研究工作,发表论文100余篇,包括Adv.Funct.Mater.、J.Eur.Ceram.Soc.、Appl.Surf.Sci.、《无机材料学报》等。xiehuidong@tsinghua.org.cn

作者简介: 高雅倩,2022年7月在榆林学院获得工学学士学位,现为西安建筑科技大学化学与化工学院硕士研究生,在谢会东教授和赵亚娟副教授的指导下进行研究,目前主要的研究领域为超级电容器。

引用本文:

高雅倩, 赵亚娟, 谢会东, 胡昌宇, 王逸博, 王康康, 杨厂. 高比电容MOF衍生的介孔球状Co₃O₄/NiO/CuO[J]. 材料导报, 2024, 38(12): 22110033-7.
GAO Yaqian, ZHAO Yajuan, XIE Huidong, HU Changyu, WANG Yibo, WANG Kangkang, YANG Chang. Mesoporous Spherical Co₃O₄/NiO/CuO Derived from MOF with High Specific Capacitance. Materials Reports, 2024, 38(12): 22110033-7.

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http://www.mater-rep.com/CN/10.11896/cldb.22110033 或 http://www.mater-rep.com/CN/Y2024/V38/I12/22110033

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