导电炭黑和热处理对Al-Bi复合材料产氢性能的影响

doi:10.11896/cldb.22050247

材料导报

2023, Vol. 37

Issue (20): 22050247-8 https://doi.org/10.11896/cldb.22050247

金属与金属基复合材料

导电炭黑和热处理对Al-Bi复合材料产氢性能的影响

陈卓¹, 谢志雄^1,*, 肖述广¹, 陈琪¹, 董仕节^1,2

1 湖北工业大学绿色轻工材料湖北省重点实验室,武汉 430068
2 武汉轻工大学机械工程学院,武汉 430023

Effect of Conductive Carbon Black and Heat Treatment on Hydrogen Production Performance of Al-Bi Composites

CHEN Zhuo¹, XIE Zhixiong^1,*, XIAO Shuguang¹, CHEN Qi¹, DONG Shijie^1,2

1 Hubei Key Laboratory of Green Light Industrial Materials, Hubei University of Technology, Wuhan 430068, China
2 College of Mechanical Engineering, Wuhan Polytechnic University, Wuhan 430023, China

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摘要采用机械球磨法制备Al-Bi-CB复合材料,研究了导电炭黑和热处理对Al-Bi复合材料产氢性能的影响,用扫描电子显微镜和X射线衍射仪分析了复合材料的组织形貌和物相结构。实验结果表明,当导电炭黑含量为5%时,复合材料的产氢性能最佳。在30 ℃时,1 g Al-3%Bi-5%CB复合材料5 min产生865 mL氢气,最大产氢速率达到107.15 mL·s^-1。导电炭黑细化铝粉体颗粒、提高Al-Bi复合材料的导电性以及与水接触时导电炭黑能迅速从复合材料表面剥落是其提高Al-Bi复合材料产氢量和产氢速率的主要原因。球磨Al-Bi-CB粉体材料经热处理后,在30 min内,1 g Al-3%Bi-1%CB材料的最大产氢量从220 mL增至840 mL,热处理后嵌入Al中的Bi重新熔化与再结晶而覆盖在Al表面形成活性位点是提高复合材料产氢性能的主要原因。

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关键词: Al-Bi复合材料导电炭黑气氛热处理产氢性能产氢机理

Abstract: Al-Bi-CB composites were designed by mechanical ball milling and heat treatment, the influence of conductive carbon black and heat teatment on hydrogen generation performance of Al-Bi-CB composites was studied. The morphology and structures of the composites were investigated by sanning electron microscope (SEM) and X-ray diffraction (XRD). The experiment results indicated that the composites acquired the best hydrogen production performance when the content of conductive carbon black was 5%. At the reaction temperature of 30 ℃, 1 g Al-3%Bi-5%CB composites for 5 min resulted in a hydrogen productin amount of 865 mL and the maximum hydrogen production rate was 107.15 mL·s^-1. The main reasons for increased the hydrogen production and hydrogen production rate of Al-Bi composites by conductive carbon black are refined the powder particles, improved the electrical conductivity of Al-Bi composites and quickly exfoliated from the surface of the composites when in contact with water. After heat treatment of ball milled powder, the maximum hydrogen production of Al-3%Bi-1%CB increased from 220 mL·g^-1 to 840 mL·g^-1 in 30 min. After heat treatment, Bi which embedded in Al remelted, recrystallized and form active sites on Al surface are the main reasons for improving hydrogen production performance of the composites.

Key words: Al-Bi composite conductive carbon black atmosphere heat treatment hydrogen production performance hydrogen production mechanism

出版日期: 2023-10-25 发布日期: 2023-10-19

ZTFLH:

TK91

基金资助: 国家自然科学基金(51771071)

通讯作者: *谢志雄,工学博士,湖北工业大学讲师、硕士研究生导师,材料成型及控制工程系副主任兼党支部书记,2012 年6 月于上海交通大学材料加工工程专业获工学博士学位。发表论文20 余篇,其中SCI/EI 收录论文15 余篇,主持和参与湖北省自然科学基金项目、国家自然科学基金项目,主要从事高强高导铜合金的制备、组织、性能和强化机理,产氢铝合金的制备,产氢机理,超薄壁钛管、不锈钢管、铝合金管的高频感应焊接研究。xzx@hbut.edu.cn

作者简介: 陈卓,湖北工业大学材料与化学工程学院硕士研究生,在谢志雄老师的指导下进行研究,目前主要研究领域为铝基复合材料的产氢性能。

引用本文:

陈卓, 谢志雄, 肖述广, 陈琪, 董仕节. 导电炭黑和热处理对Al-Bi复合材料产氢性能的影响[J]. 材料导报, 2023, 37(20): 22050247-8.
CHEN Zhuo, XIE Zhixiong, XIAO Shuguang, CHEN Qi, DONG Shijie. Effect of Conductive Carbon Black and Heat Treatment on Hydrogen Production Performance of Al-Bi Composites. Materials Reports, 2023, 37(20): 22050247-8.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22050247 或 http://www.mater-rep.com/CN/Y2023/V37/I20/22050247

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