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材料导报  2023, Vol. 37 Issue (17): 22030061-6    https://doi.org/10.11896/cldb.22030061
  金属与金属基复合材料 |
Al含量对CoCrFeNiTi0.5高熵合金涂层耐冲蚀和耐腐蚀性能的影响
赵建华1, 金荣华2,*, 纪秀林3, 段天泽1, 庄曙东1, 赵占西1
1 河海大学机电工程学院,江苏 常州 213022
2 中国特种设备检测研究院,北京 100013
3 汕头大学工学院,广东 汕头 515063
Effect of Al Content on Erosion Wear Resistance and Corrosion Resistance of CoCrFeNiTi0.5 High-entropy Alloy Coatings
ZHAO Jianhua1, JIN Ronghua2,*, JI Xiulin3, DUAN Tianze1, ZHUANG Shudong1, ZHAO Zhanxi1
1 College of Mechanical and Electrical Engineering, Hohai University, Changzhou 213022, Jiangsu, China
2 China Special Equipment Inspection ＆ Research Institute, Beijing 100013, China
3 College of Engineering, Shantou University, Shantou 515063, Guangdong,China
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摘要 利用激光熔覆技术制备了AlxCoCrFeNiTi0.5 (x=1.0、1.5、2.0、2.5(原子比),简记为Alx)高熵合金涂层,研究Al含量对涂层组织结构、显微硬度、耐冲蚀和耐腐蚀性能的影响。实验结果表明,随着Al含量的增加,AlxCoCrFeNiTi0.5高熵合金涂层的相结构由简单的FCC+BCC无序固溶体逐渐转变为无序BCC+有序BCC的混合结构,同时涂层的硬度显著提高。AlCoCrFeNiTi0.5高熵合金涂层表现出塑性材料的冲蚀磨损特征,在低冲蚀角(30°)、中冲蚀角(60°)和高冲蚀角(90°)下,其冲蚀磨损率仅分别为同条件下06Cr16Ni5Mo不锈钢的56.09%、59.33%和60%,耐冲蚀磨损性能优异。AlxCoCrFeNiTi0.5高熵合金涂层的耐蚀性随着Al含量的增加逐渐降低。适当添加Al不仅可以提高CoCrFeNiTi0.5高熵合金涂层的耐冲蚀磨损性能,而且合金具有很好的耐腐蚀性能。
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赵建华
金荣华
纪秀林
段天泽
庄曙东
赵占西
关键词:  高熵合金涂层  组织结构  耐冲蚀性能  耐腐蚀性能    
Abstract: AlxCoCrFeNiTi0.5 (x—molar ratio, x=1.0, 1.5, 2.0, 2.5, denoted as Alx) high-entropy alloy (HEA) coatings were fabricated by laser cladding. The effect of Al content on microstructure, microhardness, erosion wear resistance and corrosion resistance of CoCrFeNiTi0.5 HEA coatings was studied. The results show the phases of AlxCoCrFeNiTi0.5 HEA coatings evolve gradually from simple FCC+BCC mixed disordered solid solution to mixed structure of disordered BCC+ordered BCC. The hardness of the coatings increases significantly with the increase of Al content. Al1.0 HEA coating follows ductile erosion mode. Al1.0 HEA coating has good erosion resistance at different impact angles. The erosion wear rate of Al1.0 HEA coating is only 56.09%, 59.33% and 60% that of 06Cr16Ni5Mo stainless steel at low impact angle (30°), middle impact angle (60°) and high impact angle (90°), respectively. The corrosion resistance of AlxCoCrFeNiTi0.5 HEA coatings gradually reduces with the increase of Al content. Proper Al addition can not only improve erosion wear resistance of CoCrFeNiTi0.5 HEA coating, and the alloy also has good corrosion resistance.
Key words:  high-entropy alloy coating    microstructure    erosion wear resistance    corrosion resistance
出版日期:  2023-09-10      发布日期:  2023-09-05
ZTFLH:  TG174.4  
基金资助: 国家自然科学基金(51875169);河海大学大学生创新训练项目(202110294032)
通讯作者:  *金荣华,工程师,2003年6月毕业于河海大学获学士学位。现任职于中国特种设备检测研究院,主要研究方向为特种设备检验检测及表面工程。已发表论文四篇。398178411@qq.com   
作者简介:  赵建华,高级实验师,2020年毕业于河海大学获博士学位。目前主要从事材料强化与防护、焊接工艺及设备等方面的研究工作,在国内外期刊发表论文10余篇。
引用本文:    
赵建华, 金荣华, 纪秀林, 段天泽, 庄曙东, 赵占西. Al含量对CoCrFeNiTi0.5高熵合金涂层耐冲蚀和耐腐蚀性能的影响[J]. 材料导报, 2023, 37(17): 22030061-6.
ZHAO Jianhua, JIN Ronghua, JI Xiulin, DUAN Tianze, ZHUANG Shudong, ZHAO Zhanxi. Effect of Al Content on Erosion Wear Resistance and Corrosion Resistance of CoCrFeNiTi0.5 High-entropy Alloy Coatings. Materials Reports, 2023, 37(17): 22030061-6.
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http://www.mater-rep.com/CN/10.11896/cldb.22030061  或          http://www.mater-rep.com/CN/Y2023/V37/I17/22030061
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