A Review of Corrosion Resistance of Fe-based Amorphous Coatings: Influencing Factors and Enhancing Methods
ZHAI Jianshu1, LI Chunyan1,2, TIAN Lin1, LU Yu1, KOU Shengzhong1,2
1 School of Materials Science and Engineering, Lanzhou University of Technology,Lanzhou 730050, China; 2 State Key Laboratory of Advanced Processing and Reuse of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
Abstract: The structural characteristics of amorphous alloys are short-range order, long-range disorder, and no crystal defects such as grain boundaries and dislocations. Fe-based bulk amorphous alloys own lots of merits including ultra-high hardness and strength, excellent corrosion resis-tance and wear resistance, and low cost, nevertheless exist mostly in the forms of powders, thin strips, millimeter bars, etc. due to low glass forming ability and room-temperature brittleness. This intrinsic shortcoming has become the obstacle to the promotion and application of Fe-based amorphous alloys. Fabricating alloy coatings instead of bulks, despite being regarded as a good solution to this problem, can retain the inherent merits of bulk amorphous alloys, and has found wide application in the manufacturing and remanufacturing fields of petrochemical industry, automotive machinery, and marine engineering. Though high velocity oxy-fuel (HVOF) spraying and air plasma spraying (APS) have been proven competent to coat Fe-based amorphous alloys on surface of steel substrate, the corrosion resistance of the obtained coatings depend on various factors. According to relevant researches, properties of the coating such as amorphous constituents (elements of Cr, Mo, Ni, Nb, etc.), porosity, crystalline phases, oxides generated, and the spraying process including size of particles fed, type of spraying technique, spraying parameters, as well as external factors, all of them influence directly or indirectly the protective effect of Fe-based amorphous alloy coatings against corrosive media. Furthermore, researchers have also acquired helpful outputs in methods to improve corrosion resistance, exemplified by heat treatment, pore-sealing treatment, laser remelting, oxidation treatment, ion injection, and polarization treatment. These achievements benefit largely the practical application of Fe-based amorphous coatings to the corrosion protection of marine equipment. This paper provides a summary of the factors affecting the corrosion resistance of Fe-based amorphous coatings and the measures to improve the corrosion resistance of the coating in the post-treatment. It also gives a brief discussion on the existent problems and the future prospect.
作者简介: 翟建树,2019年6月毕业于兰州理工大学,在材料成型与控制工程专业获得学士学位。现为兰州理工大学硕士研究生,在李春燕教授的指导下进行研究。目前主要研究领域为Fe基非晶涂层。 李春燕,兰州理工大学材料学院教授、硕士研究生导师。2006年获得兰州理工大学材料学专业硕士学位并留校任教,2013年获得兰州理工大学材料加工工程专业博士学位。2018年被评为“甘肃省优秀学位论文指导教师”,2019年获得“西部地区人才培养特别项目”出国访学资助。2020年被评为兰州理工大学“科研工作先进个人”。中国材料研究学会高级会员,甘肃省材料学会会员,《精密成形工程》期刊编委。Applied Surface Science、Rare Metals、Journal of Non-Crystalline Solids、Physics B等国际权威期刊审稿人。长期从事非晶合金、高熵合金等相关领域的研究。近年来,在非晶合金和高熵合金领域发表论文50余篇,包括Intermetallics、Journal of Materials Science、Journal of Non-Crystalline Solids、Surface Engineering、Progress in Nature Science等。申请国家发明专利10项。获得甘肃省冶金有色工业协会科技进步二等奖1项、甘肃省自然科学技术奖三等奖2项。
引用本文:
翟建树, 李春燕, 田霖, 卢煜, 寇生中. Fe基非晶涂层耐腐蚀性能的影响因素及提升措施综述[J]. 材料导报, 2021, 35(3): 3129-3140.
ZHAI Jianshu, LI Chunyan, TIAN Lin, LU Yu, KOU Shengzhong. A Review of Corrosion Resistance of Fe-based Amorphous Coatings: Influencing Factors and Enhancing Methods. Materials Reports, 2021, 35(3): 3129-3140.
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2021, Vol. 35 
