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材料导报  2023, Vol. 37 Issue (23): 22100019-7    https://doi.org/10.11896/cldb.22100019
  无机非金属及其复合材料 |
油酸改性石墨相氮化碳的制备、表征及摩擦学性能研究
杨长兴1, 王固霞1,2,3,*, 郭生伟4
1 北方民族大学化学与化学工程学院,银川 750021
2 宁夏太阳能化学转化技术重点实验室,银川 750021
3 化工技术基础国家民委重点实验室,银川 750021
4 北方民族大学材料科学与工程学院,银川 750021
Preparation, Characterization and Tribological Properties of Oleic Acid Modified Graphitic Phase Carbon Nitride
YANG Changxing1, WANG Guxia1,2,3,*, GUO Shengwei4
1 School of Chemistry & Chemical Engineering, North Minzu University, Yinchuan 750021, China
2 Ningxia Key Laboratory of Solar Chemical Conversion Technology, Yinchuan 750021, China
3 Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission, Yinchuan 750021, China
4 School of Materials Science & Engineering, North Minzu University, Yinchuan 750021, China
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摘要 石墨相氮化碳(g-C3N4)具有高比表面积、超低的层间剪切强度以及表面化学稳定性,在润滑领域具有巨大的应用潜力。本工作采用冷凝回流法制备了油酸表面改性石墨相氮化碳(g-C3N4/OA)纳米片,并利用FTIR、XRD、SEM、AFM、TGA、BET等手段对其结构、形貌进行表征,利用四球法考察了含有g-C3N4/OA的150BS再生基础油的摩擦学性能。结果表明,0.03%(质量分数,下同) g-C3N4/OA作为润滑油添加剂,可使基础油平均摩擦系数(AFC)和平均磨斑直径(AWSD)最低,与纯150BS再生基础油相比,分别降低了27.7%和9.2%。机理分析表明,在摩擦过程中层状结构诱导的自润滑展现出良好的润滑性能,在摩擦接触界面形成含有铁、氧、氮和碳元素的自修复油膜有效提高了基础油的减摩、抗磨性能。
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杨长兴
王固霞
郭生伟
关键词:  g-C3N4纳米片  再生基础油  表面改性  摩擦学性能    
Abstract: Graphite phase carbon nitride (g-C3N4) has great potential application in the lubrication field due to its high specific surface area, ultra-low interlaminar shear strength and surface chemical stability. In this work, oleic acid modified graphite phase carbon nitride (g-C3N4/OA) nano sheets were prepared by condensation reflux method. FTIR, XRD, SEM, AFM, TGA, BET was employed to characterize the structure and morphology of g-C3N4/OA. And the tribological properties of 150BS regenerated base oil containing g-C3N4/OA were investigated by four ball method. The results show that the average friction coefficient (AFC) and average wear scar diameter (AWSD) can be minimized when 0.03wt% g-C3N4/OA as lubricating oil additive was used. Compared with the pure 150BS regenerated base oil, AFC and AWSD were reduced by 27.7% and 9.2%, respectively. The mechanism analysis shows that the self-lubrication induced by layered structure shows good lubrication performance during the friction process. The self-repairing oil film containing iron, oxygen, nitrogen and carbon elements is formed at the friction contact interface, which effectively improves the antifriction and anti-wear performance of the lubricating oil.
Key words:  g-C3N4 nanosheet    recycled base oil    surface modification    tribological property
出版日期:  2023-12-10      发布日期:  2023-12-08
ZTFLH:  TQ646.2  
基金资助: 北方民族大学重点科研项目(2021KJCX03);宁夏回族自治区重点研发项目(2022BDE03003);北方民族大学引进人员科研启动项目(2020KYQD06)
通讯作者:  * 固霞,博士,硕士研究生导师。2018年毕业于合肥工业大学,获工学博士学位,2009年于北方民族大学化学与化学工程学院任教至今,主要研究方向为材料化学,在国内外学术期刊上发表论文20余篇,授权专利5项,出版专著1部。guxia511@163.com   
作者简介:  杨长兴,2020年5月毕业于天津理工大学,获工学学士学位。现为北方民族大学化学与化学工程学院硕士研究生,目前主要研究领域为润滑材料。
引用本文:    
杨长兴, 王固霞, 郭生伟. 油酸改性石墨相氮化碳的制备、表征及摩擦学性能研究[J]. 材料导报, 2023, 37(23): 22100019-7.
YANG Changxing, WANG Guxia, GUO Shengwei. Preparation, Characterization and Tribological Properties of Oleic Acid Modified Graphitic Phase Carbon Nitride. Materials Reports, 2023, 37(23): 22100019-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22100019  或          http://www.mater-rep.com/CN/Y2023/V37/I23/22100019
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