Abstract: Compared with traditional cement-based materials, cement matrix reinforced by functional fillers can not only have improved mechanical and physical properties and durability, but also obtain thermoelectric attributes. Such attributes can convert thermal heat into electric energy and vice versa, which have demonstrated great potential in the application for structural health monitoring, energy collection and de-icing. With the initiate of carbon peaking and carbon neutrality goals, thermoelectric cement-based composites (TECCs) have been attracting extensive attention from academic and industrial communities. Such TECC materials can generate electricity while reducing temperature of structural surfaces and alleviating the so-called urban island effect. With the potential of improving the structure of energy supply in urban areas, TECC has been emerging as one of the most promising construction material candidates for future. Recently, researchers have conducted extensive work to improve the thermoelectric performances of TECC through adding different fillers and employing various preparation processes and dispersion methods. The results obtained suggest that the type and the content of functional fillers are the major factors affecting the thermoelectric properties of TECC, followed by preparation process and dispersion method. Among the work conducted, the highest Seebeck coefficient of TECC was achieved by adding nano metal oxide into cement matrix. The value is two orders of magnitude larger when compared to nano carbon fillers. However, the TECC with nano carbon fillers has higher ZT value and electrical conductivity. Alternatively, some researchers dispersed metal fillers (including their oxides) and nano carbon filler into cement-based materials, and achieved significant improved thermoelectric performances with balance between Seebeck coefficient and ZT value. The highest ZT value is 0.01 at 70 ℃, and the energy conversion efficiency is 0.24%, which is sufficient to supply energy for low-power electronic devices such as structural health monitoring sensors. However, the current development of TECC is still facing great challenges and critical issues, particularly for large-scale application in practical engineering. Enhancing the thermoelectric properties and the performances of TECC while keeping its competitive mechanical properties has become the research focus recently. In this paper, the principle of the thermoelectric effect of cement-based composites is presented. Then the effects of different preparation processes and dispersion methods on the thermoelectric properties of TECC are discussed. The methods for characterizing and measuring the thermoelectric properties are summarized. The effects of various functional fillers on the thermoelectric properties of cement-based composites are elaborated, and the potential application of TECC in practical engineering is envisaged. This review also proposes some challenges and problems to be solved for further development of thermoelectric cement-based materials. Moreover, the paper proposes some directions for theoretical modelling and experimental work, in order to provide guidelines for developing TECC with good dispersion of functional fillers and excellent thermoelectric properties.
通讯作者:
*冯闯,南京工业大学土木工程学院教授、博士研究生导师。2014年获得西安大略大学(加拿大)机械与材料工程博士学位。2015年至2019年于皇家墨尔本理工大学工作。2019年入选国家海外高层次人才青年项目,回国入职南京工业大学土木工程学院,2020年起担任江苏省力学学会理事。目前主要从事智能复合材料与结构的研究与开发工作,发表SCI论文60余篇,包括Computer Methods in Applied Mechanics and Engineering、Composites Part A、Composites Part B、Cement and Concrete Composites等相关领域内顶级和主流期刊,其中三篇入选ESI高被引。chuang.feng@njtech.edu.cn
作者简介: 樊宇澄,2021年6月毕业于江苏科技大学,获得工学学士学位。现为南京工业大学土木工程学院硕士研究生,在冯闯教授的指导下进行研究。目前主要研究领域为智能复合材料与结构,以第一作者在Cement and Concrete Composites、International Journal of Mechanical Sciences等发表SCI论文四篇。
引用本文:
樊宇澄, 冯闯. 热电水泥基复合材料研究现状及展望[J]. 材料导报, 2023, 37(17): 21110105-22.
FAN Yucheng, FENG Chuang. Current Status and Prospect of the Research of Thermoelectric Cement-based Composites. Materials Reports, 2023, 37(17): 21110105-22.
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2023, Vol. 37 
