铁氮化工艺、氮化铁的性质及氧化行为的研究现状与展望

doi:10.11896/cldb.21100038

材料导报

2023, Vol. 37

Issue (14): 21100038-16 https://doi.org/10.11896/cldb.21100038

金属与金属基复合材料

铁氮化工艺、氮化铁的性质及氧化行为的研究现状与展望

刘嘉琴, 王晓方, 刘柯钊^*

表面物理与化学重点实验室,四川绵阳 621908

Research Status and Prospect of Iron Nitriding Techniques, Properties and Oxidation Behavior of Iron Nitrides

LIU Jiaqin, WANG Xiaofang, LIU Kezhao^*

Science and Technology on Surface Physics and Chemistry Laboratory, Mianyang 621908, Sichuan, China

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摘要氮化铁作为一种典型的填隙合金,具有较为丰富的相结构、优良的抗腐蚀性及耐磨性、高的热稳定性,在铁及其合金的表面腐蚀防护领域具有重要的应用价值。本文系统地综述了铁表面氮化工艺的方法、工艺原理以及不同技术的优缺点,同时归纳了氮化铁薄膜材料的制备技术,包括气相沉积法、溅射法以及分子束外延法,并详细介绍了氮化铁的物相结构及其转化规律,最后重点对氮化铁的氧化行为及氧化模型研究进展进行总结,以期为氮化铁的实验研究和腐蚀防护应用提供参考。

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关键词: 氮化铁氮化工艺氧化行为动力学模型

Abstract: Iron nitrides with rich structures have attracted wide attention in the field of material surface corrosion protection due to their high thermal stability, excellent corrosion resistance and wear resistance. In this paper, the nitridation processing techniques and the related studies on the formation mechanism of the nitride layers, as well as the advantages and disadvantages of different technologies are systematically reviewed. At the same time, the preparation technologies of iron nitrides film materials, including vapor deposition, sputtering and molecular beam epitaxy, are summarized. Then the phase structure and its transition behavior are introduced in detail. Finally, the research progress of oxidation behavior and kinetic model of iron nitride are summarized in order to provide reference for experimental research and corrosion protection application of iron nitrides.

Key words: iron nitrides nitriding technology oxidation behavior kinetic model

出版日期: 2023-07-25 发布日期: 2023-07-24

ZTFLH:

TG174.4

基金资助: 国家自然科学基金(22172148)

通讯作者: *刘柯钊,现任中国工程物理研究院材料研究所副所长、核燃料循环与材料领域教授、博士研究生导师,核学会光化材料分会常务副理事。1990年7月本科毕业于浙江大学材料科学专业,一直工作于中国工程物理研究院材料研究所。2000—2001年,日本静冈大学访问学者,2013年获浙江大学材料学专业工学博士学位。2004年,被选举为四川省学术人才后备人选。2011年被评为四川省有突出贡献的优秀专家。2012年,他被授予享受政府特殊津贴的专家称号。一直从事高温超导材料应用、铀合金表面性能、表面涂层技术和锕系元素(如铀及其合金)表面改性技术领域的基础研究和工程技术开发。近年来,主持了多项国防研究项目,发表了40篇科学论文。曾获军事科技进步一等奖4项、军事科技进步二等奖6项、军事科技进步一等奖6项。liukezhaosaf@163.com

作者简介: 刘嘉琴,2020年6月毕业于华东师范大学,获得理学硕士学位。现为中国工程物理研究院材料研究所博士研究生,在刘柯钊教授的指导下进行研究。目前主要研究领域为金属的腐蚀与防护。

引用本文:

刘嘉琴, 王晓方, 刘柯钊. 铁氮化工艺、氮化铁的性质及氧化行为的研究现状与展望[J]. 材料导报, 2023, 37(14): 21100038-16.
LIU Jiaqin, WANG Xiaofang, LIU Kezhao. Research Status and Prospect of Iron Nitriding Techniques, Properties and Oxidation Behavior of Iron Nitrides. Materials Reports, 2023, 37(14): 21100038-16.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21100038 或 http://www.mater-rep.com/CN/Y2023/V37/I14/21100038

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