含氟聚合物乳液的制备方法及在固液界面的应用

材料导报

2021, Vol. 35

Issue (Z1): 586-593

高分子与聚合物基复合材料

含氟聚合物乳液的制备方法及在固液界面的应用

梁雷^1,2, 王彦玲^1,2, 刘斌^1,2, 李永飞^1,2, 汤龙皓^1,2

1 中国石油大学(华东)石油工程学院,青岛 266580
2 非常规油气开发教育部重点实验室(中国石油大学(华东)),青岛 266580

A Review on the Preparation of Fluoropolymer Emulsion and Its Application in Solid-Liquid Interface

LIANG Lei^1,2, WANG Yanling^1,2, LIU Bin^1,2, LI Yongfei^1,2, TANG Longhao^1,2

1 School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China
2 Key Laboratory of Unconventional Oil & Gas Development of Ministry of Education (China University of Petroleum (East China)), Qingdao 266580, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 5407KB )
输出: BibTeX | EndNote (RIS)

摘要碳氟键拥有最低的自由能,使用含氟化合物能够显著改变固液界面的润湿性,使其达到疏水或超双疏的效果。然而,氟碳化合物拥有极低的自由能也使得其在制备过程中的分散问题成为难点,尤其是在聚合过程中单体原料的种类和成本问题等也阻碍了该领域的发展。本文通过对大量含氟聚合物乳液的制备和应用研究实例的分析,就含氟聚合物乳液制备体系中,包括聚合单体、聚合方法、乳化体系和引发体系等的研究现状进行了总结分析。同时,对该领域的研究进展进行了归纳并提出了相应的思考,探索了含氟聚合物的结构和性能,尤其是与纳米材料之间的相互作用关系等。旨在引起更多学者对氟碳界面材料的关注,期望对含氟聚合物乳液的制备和应用研究提供一定的理论价值和现实意义。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	梁雷
	王彦玲
	刘斌
	李永飞
	汤龙皓

关键词: 含氟聚合物乳液乳液聚合拓扑结构纳米涂层材料润湿性

Abstract: The C-F bond has the lowest free energy, and the wettability of solid-liquid interface can be significantly changed by using fluorine-containing compounds, which can achieve a hydrophobic or a super-amphiphobic effect. But due to the low free energy of fluorocarbons, the dispersion of fluorocarbons in the preparation process has become a difficult problem. Especially in the polymerization, the type and cost of monomer materials also hindered the development of this field. In recent years, the development of fluorine industry has promoted the process of fluoropolymer. Abundant fluorinated monomers have made corresponding breakthroughs in the research of fluoropolymers. In the preparation of fluoropolymer emulsion, fluorinated acrylic monomers have the most widely use. In the meantime, the diversification of emulsifier and emulsion polymerization mode has also effectively solved the dispersion problem of fluoropolymer in the copolymer system. After the problems solved, scholars have synthesized many fluoropolymer emulsions with different structures and properties.Through the analysis of the preparation and application of a large number of fluoropolymer emulsions, this article summarizes and analyzes the present situation of fluoropolymer emulsion preparation systems, including the polymerization monomers, polymerization methods, emulsification systems and initiating systems. The research progress in this field is summarized and the corresponding thinking is put forward. The structure and properties of fluoropolymers, especially the interaction between fluoropolymers and nanomaterials, are also explored. The aim is to attract more scholars' attention to fluorocarbon interfacial materials. It is expected that it will play a certain theoretical and practical significance in the preparation and application of fluoropolymer emulsions.

Key words: fluoropolymer emulsion emulsion polymerization topological structures coating nanomaterials wettability

发布日期: 2021-07-16

ZTFLH:

O632.2

通讯作者: wangyl@upc.edu.cn

作者简介: 梁雷,博士研究生,主要从事油气田开采过程中的化学助剂研发与应用等相关工作。2010年至2014年在西安石油大学化学化工学院化学专业学习(获理学学士学位);2015年至2018年在西安石油大学化学化工学院应用化学专业学习(获工学硕士学位);2018年至今在中国石油大学(华东)石油工程学院油气田开发专业学习(攻读博士学位)。王彦玲,教授、博士研究生导师,主要从事油气田开采过程中的化学助剂研发与应用等相关工作。1987年9月至1991年7月在南京大学化学系化学专业获理学学士学位;2001年9月至2006年7月在山东大学晶体材料国家重点实验室攻读博士学位(获工学博士学位);2007年至2011年在胜利石油管理局进行博士后科研工作研究;2006年作为引进人才到中国石油大学(华东)石油工程学院从事教学与科研工作。

引用本文:

梁雷, 王彦玲, 刘斌, 李永飞, 汤龙皓. 含氟聚合物乳液的制备方法及在固液界面的应用[J]. 材料导报, 2021, 35(Z1): 586-593.
LIANG Lei, WANG Yanling, LIU Bin, LI Yongfei, TANG Longhao. A Review on the Preparation of Fluoropolymer Emulsion and Its Application in Solid-Liquid Interface. Materials Reports, 2021, 35(Z1): 586-593.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/IZ1/586

1 周建华, 陈欣, 彭颖姗, 等. 材料导报, 2014, 28(15),1.
2 Kosec T, Skrlep L, Fabjan e S,et al. Progress in Organic Coatings, 2019, 131, 27.
3 Akihiko A, Masao U, Takao H,et al. Journal of Fluorine Chemistry, 2000, 104, 47.
4 Park I J, Lee S B, Choi C K. Macromolecules, 1998, 31(21), 7555.
5 Azhar U, Huyan C X, Wan X Z,et al. Arabian Journal of Chemistry, 2019, 12, 559.
6 Wang Y L, Jin J F, Bai B J,et al. PLoS One, 2015, 10(6),e0128414.
7 Brandsma S H, Koekkoek J C, Velzen M J M,et al. Chemosphere, 2019, 220, 493.
8 Wang Y L, Jin j F, Ma L,et al. Journal of Dispersion Science and Technology, 2015, 36, 1274.
9 Liang J H, Azhar U, Men P C,et al. Applied Surface Science, 2019, 487, 1000.
10 Closser R G, Lillethorup M, Bergsman D S,et al. Applied Materials & Interfaces. 2019, 11,21988.
11 Li Y F, Wang Y L, Wang Q,et al. Colloids and Surfaces A: Physicoche-mical and Engineering Aspects, 2018, 558, 438.
12 Li Y F, Wang Y L, Jin J F,et al. Energy & Fuels, 2018, 32, 1515.
13 Jin J F, Wang Y L, Nguyen T A H,et al. Industrial & Engineering Che-mistry Research, 2019, 58, 6747.
14 Cui J N, Guo J Y, Zhai Z H,et al. Chemosphere, 2019, 222, 637.
15 Dinh C V.ACS Omega, 2020, 5, 8825.
16 Mondal S, Pal S, Chaudhuri A,et al. Journal of the Textile Institute. 2019, 110, 1747.
17 Wang Y, Li Y F, Wang Q,et al. RSC Advance, 2018, 8, 7924.
18 Jin J, Wang Y, Wei M,et al. Journal of Dispersion Science and Technology, 2015, 37,1436.
19 Gilmore B, Luscher Z, Roberts K,et al. Polymer Degradation and Stability, 2019, 162, 122.
20 Li Y, Wang Y, Guo G,et al. Petroleum Science and Technology, 2018, 36, 951.
21 Kuang M X, Wang J X, Jiang L.Chemical Society Reviews, 2016, 45,6833.
22 Puah P Y, Lee D J H, Mak K H,et al. RSC Advances, 2019, 9,31918.
23 Merkel T C, Toy L G.Macromolecules, 2006, 39, 7591.
24 He Q, Wang K, Chen J G,et al. Separation and Purification Technology, 2020, 232, 115955.
25 Zhang Q H, Zhan X L, Chen F Q.Journal of Applied Polymer Science, 2007, 104(1),641.
26 Guyot B, Boutecvin B, Ameduri B. Macromolecular Chemistry and Physics, 1996, 197, 937.
27 Cuci M, Jmle E, Ski H M.Journal of Fluorine Chemistry, 1999, 96, 11.
28 Winter R, Nixon P G, Terjeson R J,et al. Journal of Fluorine Chemistry, 2002, 115, 107.
29 Hochart F, Levalois-Mitjaville J, Jaeger R D.Polymer, 2000, 41,3159.
30 Kameda N.Polymer Journal, 2006, 38,516.
31 Raihane M, Ameduri B.Journal of Fluorine Chemistry, 2006, 127(3), 391.
32 Meskini A, Raihane M, Ameduri B.European Polymer Journal, 2009, 45(3),804.
33 Wang S, Liu K, Yao X,et al. Chemical Reviews, 2015, 115, 8230.
34 Wen L, Tian Y, Jiang L.Angewandte Chemie International Edition, 2015, 54, 3387.
35 Zhang X, Shi F, Niu J,et al. Journal of Materials Chemistry, 2008, 18, 621.
36 Yan L, Li J, Li W,et al. Materials Letters, 2016, 163,247.
37 Hou J, Zhang H C, Yang Q,et al. Angewandte Chemie International Edition, 2014, 53, 5791.
38 Zheng Y M, Gao X F, Jiang L.Soft Matter, 2007, 3, 178.
39 Gundersen H, Leinaas H P, Thaulow C.PLoS One, 2014, 9, e86783.
40 Hensel R, Finn A, Helbig R,et al. Advanced Materials, 2014, 26, 2028.
41 Marlow F, Muldarisnu R, Sharifi P, et al. Angewandte Chemie International Edition, 2009, 48, 6212.
42 Chen S I, Shen Y L, Shen J L.Journal of Applied Polymer Science, 1998, 63(7), 903.
43 Linem A R F, Malner T E, Brandsch R.Macromolecules, 1999, 32(6), 1715.
44 邓宝祥, 解如阜.天津纺织工学院学报, 1996(1), 6.
45 程时远, 陈艳军, 王康丽.高分子学报, 2002(5), 560.
46 周文娟, 姜万超, 李峥嵘,等. 印染助剂, 2007(3), 31.
47 Hirboodvash Z, Khodami M, Fong N R,et al. Applied Optics, 2019, 58, 2994.
48 Castelvetro V, Vita C D, Giannini G,et al. Macromolecular Symposia, 2005, 226, 289.
49 Wei H Y, Li X X, Wang K,et al. Acta Chimica Sinica, 2008, 12, 1470.
50 Zhang Q Y, Pei H N, Jie A L,et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 242, 9.
51 陈艳军, 张钰英, 张超灿,等. 绿色建材, 2008(1),10.
52 Forsythe J S, Hill D J T, Calos N,et al. Journal of Applied Polymer Science, 1999, 73,169.
53 辛华, 刘建芳, 张辉,等. 涂料工业, 2019, 49(11), 12.
54 Chen L J, Wu F Q.Surface Engineering, 2012, 28(3), 225.
55 Grancio M R, Williams D J. Journal of Polymer Science Part A-1: Polymer Chemistry, 1970(8), 2617.
56 Kallitsis K, Thuau D, Soulestin T,et al. Macromolecules, 2019, 52, 5769.
57 唐敏锋, 范晓东, 刘涛,等. 高分子材料科学与工程, 2007(2),99.
58 Qu A L, Wen X F, Pi P H, et al. Colloid and Interface Science, 2008, 317, 62.
59 粟小理, 李慧, 李欣欣,等. 华东理工大学学报, 2007, 33(4), 496.
60 孙亮亮, 刘鹏飞, 杨盼星,等. 热固性树脂, 2019, 34(2), 26.
61 Hao L, An Q, Xu W,et al. Journal of Polymer Research, 2013, 20(7),174.
62 Meng Z, You H Y, Zhe W H,et al. Polymers, 2017, 9(11), 606.
63 Kim K, Jia X J, Fuentes H C,et al. ACS Applied Nano Materials, 2019, 2, 2525.
64 刘敏, 侯丽华, 卓虎,等. 有机氟工业, 2020(1), 14.
65 Guo W J, Tang X D, Xu J.Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49(7), 1528.
66 Luo Z H, Yu H J, Zhang W.Journal of Applied Polymer Science, 2009, 113(6),4032.
67 Young T J, Jackson J, Roy S,et al. Wear, 2017, 376, 1713.
68 Tang Y C, Yang J, Yin L T,et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 459,261.
69 Huang Q Z, Fang Y Y, Liu P Y,et al. Chemical Physics Letters, 2018, 692, 33.
70 Zhang H M, Yang J, Chen B B,et al. Applied Surface Science, 2015, 359, 905.
71 Guo L H, Jiang S J, Qiu T.Journal of Applied Polymer Science, 2014, 131(8), 40162.
72 Sun Y F, Zhao X F, Liu R P,et al. Progress in Organic Coatings, 2018, 123,306.
73 Yang Y, Zhang T, Yan J J,et al. Langmuir, 2018, 34(51),15812.
74 He L, Liang J Y, Zhao X, et al. Progress in Organic Coatings, 2010, 69(4),352.
75 Hou J, Ding W, Feng Y,et al. Polymers, 2017, 9(6), 217.
76 梁雷, 王彦玲, 张杉.化工进展, 2020, 39(3), 1070.
77 侯琳刚, 马利利, 周亦晨,等. 化学进展, 2018, 30(12), 1887.
78 邓瑾妮, 郝国庆, 郑朝晖,等. 高分子材料科学与工程, 2016, 32(5), 11.
79 史雅娜, 鲁佳伟, 杜自卫,等. 高分子材料科学与工程, 2019, 35(2), 1.
80 张越, 黄鑫, 姜崴,等. 精细化工, 2019, 36(5), 999.
81 王汉利, 单体美, 王磊. 有机氟工业, 2018(2),21.
82 Valipour M N, Birjandi F C, Sargolzaei J.Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 448, 93.
83 Xie Q, Xu J, Feng L.Advanced Materials, 2004, 16(4), 302.
84 Jiang W, Grozea C M, Shi Z.ACS Applied Materials & Interfaces, 2014, 6(4), 2629.
85 Goto Y, Takashima H, Takishita K,et al. Journal of Colloid and Interface Science, 2011, 362, 375.
86 Adam S, Ilker B, Eric L.Nano Letters, 2009, 9(1), 501.
87 冯春燕, 李玉国, 候影飞.合成化学, 2015, 23(2), 155.
88 Jin J F, Wang Y L, Ren J H,et al. Journal of Surfactants and Detergents, 2016, 19, 1241.

[1]	李磊, 刘晓莲, 王利媛, 康卫民, 庄旭品. 无机相拓扑结构对有机-无机复合质子交换膜性能的影响综述[J]. 材料导报, 2021, 35(Z1): 621-627.
[2]	王蒙, 张冠星, 钟素娟, 程战, 李文彬. Mg对Sn-0.7Cu钎料组织及性能的影响[J]. 材料导报, 2021, 35(10): 10147-10151.
[3]	王子伊, 薛松柏, 王剑豪, 刘晗, 温丽. 添加合金元素改善Au-Ge钎料组织及性能的研究进展[J]. 材料导报, 2020, 34(23): 23145-23153.
[4]	仇中柱, 李晟南, 魏丽东, 秦承芳, 姚远, 姜未汀, 郑莆燕, 张涛. 相变微胶囊悬浮液中颗粒润湿性对导热系数的影响[J]. 材料导报, 2019, 33(Z2): 623-626.
[5]	翟恒来, 齐宁, 孙逊, 张翔宇, 樊家铖. 一种新型纳米SiO₂降压增注剂的制备与评价[J]. 材料导报, 2019, 33(6): 975-979.
[6]	翟乐, 吉海峰, 姚艳梅, 瞿雄伟. 利用聚丙烯酸正丁酯@聚甲基丙烯酸甲酯核/壳结构聚合物增韧氰酸酯树脂[J]. 材料导报, 2019, 33(4): 705-708.
[7]	张贤琳, 王晓琳, 马建威, 李宝娥, 李海鹏, 刘世敏, 梁春永, 王洪水. 钛表面微弧氧化结构和成分对其润湿性的影响[J]. 材料导报, 2019, 33(24): 4035-4039.
[8]	刘晗, 薛松柏, 王刘珏, 林尧伟, 陈宏能. 金基中低温钎料的研究现状与展望[J]. 材料导报, 2019, 33(19): 3189-3195.
[9]	王剑豪, 薛松柏, 吕兆萍, 王刘珏, 刘晗. 纳米颗粒增强无铅钎料的研究进展[J]. 材料导报, 2019, 33(13): 2133-2145.
[10]	刘兆文, 李毅波, 黄明辉, 汪必升, 李剑. 阳极氧化处理增强Al-Li合金胶接板剪切强度的机理[J]. 材料导报, 2018, 32(18): 3181-3184.
[11]	毕玉保, 王慧芳, 赵万国, 梁峰, 张海军. 含碳浇注料用鳞片石墨的表面改性技术综述^*[J]. 《材料导报》期刊社, 2017, 31(15): 108-114.

[1]	Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[2]	Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[3]	WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[4]	HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[5]	ZHANG Le, ZHOU Tianyuan, CHEN Hao, YANG Hao, ZHANG Qitu, SONG Bo, WONG Chingping. Advances in Transparent Nd∶YAG Laser Ceramics[J]. Materials Reports, 2017, 31(13): 41 -50 .
[6]	CHEN Bida, GAN Guisheng, WU Yiping, OU Yanjie. Advances in Persistence Phosphors Activated by Blue-light[J]. Materials Reports, 2017, 31(21): 37 -45 .
[7]	ZHANG Yong, WANG Xiongyu, YU Jing, CAO Weicheng,FENG Pengfa, JIAO Shengjie. Advances in Surface Modification of Molybdenum and Molybdenum Alloys at Elevated Temperature[J]. Materials Reports, 2017, 31(7): 83 -87 .
[8]	JIN Chenxin, XU Guojun, LIU Liekai, YUE Zhihao, LI Xiaomin,TANG Hao, ZHOU Lang. Effects of Bulk Electrical Resistivity and Doping Type of Silicon on the Electrochemical Performance of Lithium-ion Batteries with Silicon/Graphite Anodes[J]. Materials Reports, 2017, 31(22): 10 -14 .
[9]	FANG Sheng, HUANG Xuefeng, ZHANG Pengcheng, ZHOU Junpeng, GUO Nan. A Mechanism Study of Loess Reinforcing by Electricity-modified Sodium Silicate[J]. Materials Reports, 2017, 31(22): 135 -141 .
[10]	ZHOU Dianwu, HE Rong, LIU Jinshui, PENG Ping. Effects of Ge, Si Addition on Energy and Electronic Structure of ZrO₂ and Zr(Fe,Cr)₂[J]. Materials Reports, 2017, 31(22): 146 -152 .

Viewed

Full text

Abstract

Cited

Shared

Discussed