Abstract: Molecular sieve, also known as zeolite, the study of zeolite began in the 1850s.Swedish mineralogists Cronstedt found that there was a class of natural aluminosilicate minerals in the burning will produce bubble boiling phenomenon, called zeolite. The ion exchange of zeolite was first observed and applied by Eichhorn in 1883. In 1936, pickled natural clay was used as the catalyst for petroleum cracking, which was the forerunner of molecular sieve catalyst. Subsequently, amorphous silicon oxide-alumina solid was used to obtain high cracking effect. During the 1950s, United Carbide Company (UCC) first developed synthetic zeolite molecular sieve, which was mainly used as desiccant, purifying agent and hydrocarbon separation. Subsequently, various types of molecular sieve catalysts were synthesized or discovered and widely used in petro-leum and chemical industries.Molecular sieve catalyst is a green, efficient and controllable catalyst, which plays an important strategic role in the development of national economy. However, for a long time, the synthesis of molecular sieve catalysts is not environmentally friendly, economical, energy consumption is high, thermal stability and hydrothermal stability are poor, catalytic efficiency is not high. The research of synthesis methods is mainly based on experience, and the main uses are limited to refining and chemical synthesis. In recent years, the research of mole-cular sieve catalyst has made great progress, the synthesis method is more economical, environmental protection, energy saving, using digital and information means, the research and synthesis of molecular sieve catalyst is more efficient, the application scope is unprecedented, widely used in medical, environmental protection, electronics and other new fields.The development history, preparation methodsof zeolite catalysts are reviewed. The future development trend of zeolite catalysts is also introduced.
1 Cejka J, Corma A, Zones S, Eds. Zeolites and catalysis: synthesis, reactions and applications, WILEY-VCH Verlag GmbH ＆ Co. , 2010. 2 王辉,臧亮鹏,朱鋆珊,等.化工科技,2019,27(2),70. 3 GB/T 36203-2018 分子筛 分类. 4 李飒英.化学工程与装备,2010(6),151. 5 孙锦宜.化学工业与工程技术,1996(1),47. 6 王直.石油知识,2018(1),21. 7 汪慧智.化学工程师,2006(2),27. 8 Chen C, Wang X, Zhang J, et al.Catal Today,2015,258,190. 9 涂盛辉,林立,骆中璨,等.材料导报,2017,31(24),114. 10 边超群,孟祥举,肖丰收,等.第18届全国分子筛学术大会论文集(下),2015, pp. 63. 11 Lok B M, Mssina C A, Patton R L. Journal of the American Chemical Society,1984,106, 6092. 12 杨淼.微孔硼磷酸盐化合物的合成、结构与性质研究.硕士学位论文,吉林大学,2006. 13 Taramasso M. Perego G. Notari B.US Pat.,1983,4410:501. 14 刘云凌,肖丰收,庞文琴. 中国科学基金,2000(5),54. 15 王亮,张建,肖丰收.中国专利,CN106000454B, 2019-01-08. 16 孟祥举,章凌,肖丰收.中国专利,CN106540741A,2017-03-29. 17 于吉红,孙启明.中国专利,CN106669768A,2017-05-17. 18 Corma A. Chemical Reviews, 1995, 95,559. 19 Karger J, Ruthven D M. Diffusion in zeolites and other microporous mate-rials, John New York : Wiley and Sons, 1992. 20 王胤,李君华,黄钟扬,等.天津化工,2016,30(4),1. 21 Yang P, Zhao D, Margolese D, Chmelka B F, Stucky G D. Nature, 1998, 396,152. 22 Han Y, Xiao F S, Wu S, et al. Journal of Physical Chemistry B, 2001, 105 ,7963. 23 刘军,章晓中,韩宇,等.电子显微学报,2002(5),627. 24 麻生明,杨青,肖丰收. 中国专利,CN1727349A,2006-02-01 . 25 肖丰收,林凯峰,孟凡艳,等. 中国专利,CN1749165A,2006-03-22. 26 孟岩,屠波,赵东元. 2005年纳米和表面科学与技术全国会议论文摘要集.中国真空学会,2005. 27 万颖,冯翠苗,钱旭芳,等. 第五届全国环境催化与环境材料学术会议论文集.中国化学会,2007. 28 Davis M E, Saldarriaga C, Montes C,et al. Nature, 1988,331,698. 29 Holland B T,Abrams L,Stein A. Journal of the American Chemical Society,1999,121,308. 30 Iskandar F,Mikrajuddin,Okuyama K,Nano Letters,2001,1,231. 31 邸建城,王洋,于吉红. 第十三届固态化学与无机合成学术会议论文摘要集.中国化学会:中国化学会,2014. 32 邓勇辉,刘翀,屠波,等.中国专利,CN101153051A, 2008-04-02. 33 Velev O D,Jede T A, Lobo R F,Lenhoff A M,Nature,1997,389,447. 34 吴勤明,孟祥举,雷驰,等.中国专利,CN106542539A,2017-03-29. 35 肖丰收,王利丰,单志超,等.中国专利,CN1749161A, 2006-03-22. 36 赵东元,钱旭芳,牛国兴,等.中国专利,CN101890363A,2010-11-24. 37 肖丰收,阳晓宇,李正强,等.中国专利,CN1766101A,2006-05-03 . 38 于吉红,王宁,孙启明,等.中国专利,CN 104973608A,2015-10-14. 39 颜岩,李激扬,齐妙,等.中国科学(B辑:化学),2009,39(11),1308. 40 于吉红.第十七届全国分子筛学术大会会议论文集.中国化学会分子筛专业委员会:中国化学会,2013. 41 卢君然,李乙,于吉红,等.物理化学学报,2013,29(8),1661. 42 冯晓娜.化工设计通讯,2018,44(11),134. 43 Acobe J.Molecular sieves principles of synthesis and identifica-tion, AIME, New York, 1992. 44 李三妹,陕绍云,贾庆明,等.硅酸盐通报,2013,32(6),1082. 45 董秀芳,曹端林,李裕,等.化学工程师,2010,24(5),43. 46 孙敬方,张雷,葛成艳,等.催化学报,2014,35(8),1347. 47 银董红,彭建兵,秦亮生,等.湖南师范大学自然科学学报,2003,26(1),48. 48 李丽华,王鹏,张金生,等.化工新型材料,2019,47(1),19. 49 崔岩,郭成玉,王晓化,等.工业催化,2016,24(3),1. 50 徐晨瑀,张海燕,马宇彤,等.能源化工,2017,38(1),51. 51 窦涛,冯芳霞,萧墉壮,等.燃料化学学报,1997(1),17. 52 孟祥举,金银樱,孙琦,等.中国专利,CN103121698A,2013-05-29. 53 孟祥举,王叶青,肖丰收. 中国专利,CN104671252A, 2015-06-03 . 54 B·耶尔马兹,U·米勒,F·厄扎克瑞姆,等.中国专利,CN103917492A, 2014-07-09 . 55 M·费延,S·毛雷尔,U·米勒包信,等.中国专利,CN 106061900 A, 2016-10-26. 56 王叶青,吴勤明,孟祥举,等.工程(英文) ,2017,3(4),292. 57 田红丽,刘荣杰.广东化工,2013,40(17),100. 58 冯晓娜.化工设计通讯,2018,44(11),134. 59 张智敏,苏慧,庄壮.化工技术与开发,2018,47(3),34.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2021, Vol. 35 
