LIU Jing1, GAO Zhengyang1, WANG Jie2, CHEN Peiru1, Yang Lubing1
1 School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250100, China 2 Shandong Engineering of Consulting Institute, Jinan 250014, China
Abstract: TiO2 has the advantages of good chemical stability, high catalytic activity, no pollution, and low price, and has broad development prospects in the field of photocatalysis. The bandgap of TiO2 affects its absorption of visible light, which is not conducive to the promotion and utilization of TiO2 in production and life. The research progress of co-doping modified TiO2 in the field of photocatalysis was reviewed and the photocatalysis mechanism of nano-TiO2 was introduced. The influences of different modification methods such as metal/metal co-doping, non-metal/non-metal co-doping and metal/non-metal co-doping on the photocatalytic properties of TiO2 were analyzed and compared. The co-doping modification can improve the photocatalytic activity of TiO2 by reducing the band gap, producing visible light effect and inhibiting the recombination of electron and hole. Finally, the research results of the mechanism of co-doping and the coordination between ions were summarized, the shortco-mings of the current research on co-doped TiO2 were pointed out, and the future research direction was put forward.
1 Fujishima A, Honda K.Nature, 1972, 238(5358),37. 2 Binas V, Venieri D, Kotzias D, et al. Journal of Materiomics, 2017, 3(1), 3. 3 Lyu J, Zhou L, Shao J, et al.Chemical Engineering Journal, 2020, 400,125927. 4 Yang X, Koziel J A, Laor Y, et al.Catalysts, 2020, 10(6),607. 5 Zhang G, Peyravi A, Hashisho Z, et al.Catalysis Science & Technology, 2020, 10(8), 2378. 6 Lee Y E, Chung W C, Chang M B. Environmental Science and Pollution Research, 2019, 26(20), 20908. 7 Ajmal A, Majeed I, Malik R N, et al.RSC Advances, 2014, 4(70), 37003. 8 D'Amato C A, Giovannetti R, Zannotti M, et al.Applied Surface Science, 2018, 441, 575. 9 Zhu P, Ren Z, Wang R, et al.Frontiers of Materials Science, 2020, 14(1), 33. 10 Oh W C, Nguyen D C T, Ullah K, et al.Separation Science, 2020, 55(8),1544. 11 El-Deen S E A S, Zhang F S.Journal of Experimental Nanoscience, 2015, 11(4),1. 12 Popa N, Visa M.Materials Chemistry and Physics, 2021, 258,123927. 13 Zendehzaban M, Ashjari M, Sharifnia S. International Journal of Energy Research, DOI:10.1002/er.5072. 14 Haq I U, Ahmad W, Ahmad I, et al.Water Environment Research, 2020, 92(12),2086. 15 Martin S T, Lee A T, Hoffmann M R. Environmental Science & Technology, 1995, 29(10),2567. 16 Tian F, Zhu R, Ouyang F.Journal of Environmental Sciences, 2013, 25(11), 2299. 17 Cai J, Wu X, Li Y, et al. Journal of Colloid and Interface Science, 2018,514, 791. 18 Li S, Cai J, Wu X, et al. Applied Surface Science, 2018, 443, 603. 19 Kuvarega A T, Krause R W M, Mamba B B.The Journal of Physical Chemistry C, 2011, 115(45), 22110. 20 Reszczyńska J, Grzyb T, Sobczak J W, et al.Applied Catalysis B, Environmental, 2015, 163, 40. 21 Vaiano V, Sacco O, Sannino D, et al.Applied Catalysis B, Environmental, 2015, 170, 153. 22 Chu S Z, Inoue S, Wada K, et al.The Journal of Physical Chemistry B, 2003, 107(27), 6586. 23 Subramanian V, Wolf E, Kamat P V.The Journal of Physical Chemistry B, 2001, 105(46), 11439. 24 Liu Z, Ma Z. Materials Research Bulletin, 2019, 118,110492. 25 Vinodgopal K, Wynkoop D E, Kamat P V. Environmental Science & Technology, 1996, 30(5), 1660. 26 Yang C, Dong W, Cui G, et al.Electrochimica Acta, 2017, 247, 486. 27 Dil M A, Haghighatzadeh A, Mazinani B.Bulletin of Materials Science, DOI: 10.1007/s12034-019-1927-9. 28 戴超. 锐钛矿型TiO2本征缺陷、掺杂的第一性原理研究. 硕士学位论文, 武汉理工大学, 2012. 29 Linsebigler A L, Lu G, Yates J R J T.Chemical Reviews, 1995, 95(3), 735. 30 Nosaka Y, Fox M A. Journal of Physical Chemistry, 1988, 92(7),1893. 31 Fotou G P, Pratsinis S E. Chemical Engineering Communications, 1996, 151(1), 251. 32 Choi W, Termin A, Hoffmann M R.The Journal of Physical Chemistry, 1994, 98(51), 13669. 33 Asahi R, Morikawa T, Ohwaki T, et al.Science, 2001, 293(5528), 269. 34 Kaleji B K, Mirzaee S, Ghahramani S, et al. Journal of Materials Science, Materials in Electronics, 2018, 29(14), 12351. 35 王杰,汪莉,贺拴玲,等. 应用化工, 2019,48(12),2821. 36 Xu A W, Gao Y, Liu H Q. Journal of Catalysis, 2002, 207(2), 151. 37 He J J, Du H L, Liu J, et al. Materials Science Forum, 2015, 809,878. 38 Darshana B, Parikh S, Shah M. Energy, Ecology and Environment, 2020,5(5),344. 39 Benjwal P, Kar K K.RSC Advances, 2015, 5(119),98166. 40 Valentin C D, Finazzi E, Pacchioni G, et al.Chemical Physics, 2007, 339(1-3),44. 41 Dong F, Guo S, Wang H, et al. The Journal of Physical Chemistry C, 2011, 115(27), 13285. 42 Ho W, Jimmy C Y, Lee S. Chemical Communications, 2006,111 (10), 1115. 43 Ohno T, Mitsui T.Chemistry Letters, 2003, 32(4), 364. 44 Deng L, Chen Y, Yao M, et al.Journal of Sol-Gel Science and Technology, 2010, 53(3), 535. 45 Dong X, Sun Z, Zhang X, et al.Australian Journal of Chemistry, 2018, 71(5), 315. 46 Zhang J, Xing Z, Cui J, et al.Dalton Transactions, 2018, 47(14), 4877. 47 赵林,谢艳招,陈日华,等. 人工晶体学报, 2018,47(12),2663. 48 Khoiriah K, Wellia D V, Gunlazuardi J, et al.Indonesian Journal of Chemistry, 2020, 20(3),587. 49 Dhamaniya B P, Kumar A, Srivastava A K, et al.Research on Chemical Intermediates, 2017, 43(1), 387. 50 邢锦娟,彭亮亮,冉林涛,等.材料科学与工程学报,2017,35(2),274. 51 Ouyang W, Ji Y.Micro & Nano Letters, 2020, 15(8), 566. 52 杨荣,靳映霞,高洪林,等. 功能材料, 2016,47(10),10142. 53 张鹏会,李艳春,张小琳,等. 水处理技术, 2019,45(5),52. 54 Liu W, Lang Z. RSC Advances, 2020, 10(7),3844. 55 于佳辉. Fe、N共掺杂负载型TiO2光催化氧化硝基苯废水的试验研究. 硕士学位论文, 沈阳建筑大学,2019. 56 Isari A A, Hayati F, Kakavandi B, et al.Chemical Engineering Journal, 2019,392,123685. 57 Li Z, Ma C Y. Key Engineering Materials, 2020, 853, 235. 58 Mohd Yatim A A, Ismail N A, Hamid M R Y, et al.Journal of Nanoscience and Nanotechnology, 2020, 20(2), 741. 59 崔天伊,李帅宏,梁鹏举,等. 精细化工, 2020,37(6),1145. 60 沈晓玲. Fe/I共掺杂TiO2的制备及其光催化降解气相苯的研究. 硕士学位论文, 中国矿业大学,2019. 61 Bayan E M, Lupeiko T G, Pustovaya L E, et al.Journal of Alloys & Compounds, 2020,822,153662. 62 Wang R, An S, Zhang J, et al.Journal of Rare Earths, 2020, 38(1), 39. 63 Borzyszkowska A F, Pieczyńska A, Ofiarska A, et al. International Journal of Environmental Science and Technology, 2020,17(4),2163.