共掺杂改性TiO2光催化剂的研究进展

材料导报

2021, Vol. 35

Issue (Z1): 42-47

无机非金属及其复合材料

共掺杂改性TiO₂光催化剂的研究进展

刘静¹, 高正阳¹, 王杰², 陈霈儒¹, 杨璐冰¹

1 山东建筑大学市政与环境工程学院,济南 250100
2 山东省环科院环境工程有限公司,济南 250014

Research Progress of Co-doped TiO₂ Photocatalyst

LIU Jing¹, GAO Zhengyang¹, WANG Jie², CHEN Peiru¹, Yang Lubing¹

1 School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250100, China
2 Shandong Engineering of Consulting Institute, Jinan 250014, China

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摘要 TiO₂具备化学稳定性好、催化活性高、无污染、价格低廉等优点,在光催化领域有广阔的发展前景,但禁带宽度较大、可见光吸收能力差等缺点影响了TiO₂在生产生活中的推广利用。本文综述了共掺杂改性TiO₂在光催化领域的研究进展,介绍了纳米TiO₂的光催化机理,分析比较了金属与金属共掺杂、非金属与非金属共掺杂、金属与非金属共掺杂三种改性方式对TiO₂光催化性能的影响;指出共掺杂改性可以通过降低禁带宽度、产生可见光效应、抑制光生电子空穴复合等方式提高TiO₂的光催化活性;总结了有关共掺杂作用机理和离子间协同作用的研究成果,提出了当下共掺杂改性TiO₂研究存在的不足之处,并对今后的研究方向进行了展望。

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	刘静
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关键词: 二氧化钛共掺杂催化剂纳米材料环境

Abstract: TiO₂ has the advantages of good chemical stability, high catalytic activity, no pollution, and low price, and has broad development prospects in the field of photocatalysis. The bandgap of TiO₂ affects its absorption of visible light, which is not conducive to the promotion and utilization of TiO₂ in production and life. The research progress of co-doping modified TiO₂ in the field of photocatalysis was reviewed and the photocatalysis mechanism of nano-TiO₂ was introduced. The influences of different modification methods such as metal/metal co-doping, non-metal/non-metal co-doping and metal/non-metal co-doping on the photocatalytic properties of TiO₂ were analyzed and compared. The co-doping modification can improve the photocatalytic activity of TiO₂ by reducing the band gap, producing visible light effect and inhibiting the recombination of electron and hole. Finally, the research results of the mechanism of co-doping and the coordination between ions were summarized, the shortco-mings of the current research on co-doped TiO₂ were pointed out, and the future research direction was put forward.

Key words: TiO₂ co-doping catalyst nanomaterials environment

发布日期: 2021-07-16

ZTFLH:

TQ034

通讯作者: liujing99@sdu.edu.cn

作者简介: 刘静,山东建筑大学教授,硕士研究生导师。2004年9月至2007年12月,在山东大学环境科学与工程学院学习,获工学博士学位。科研主要集中在环境介质中环境激素类有机污染物的分析方法、来源解析、迁移转化规律及去除技术研究、环境管理与规划研究两大领域。发表学术论文30篇, SCI检索5篇,EI检索6篇;主持和参与国家级省部厅局级环境工程类科研项目10余项;主持和参与山东省环境规划与管理类项目和课题10余项。获山东省科技进步三等奖一项、获“山东省环境保护科学技术二等奖”一项、获“山东省环境保护优秀论文一等奖”一项、获“山东省教育厅科技进步三等奖”一项。授权专利两项。学术兼职:担任山东环境科学学会理事、济南市化工协会理事、山东省环保产业协会理事等职务。

引用本文:

刘静, 高正阳, 王杰, 陈霈儒, 杨璐冰. 共掺杂改性TiO₂光催化剂的研究进展[J]. 材料导报, 2021, 35(Z1): 42-47.
LIU Jing, GAO Zhengyang, WANG Jie, CHEN Peiru, Yang Lubing. Research Progress of Co-doped TiO₂ Photocatalyst. Materials Reports, 2021, 35(Z1): 42-47.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/IZ1/42

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