用Ti板制备高比表面积TiO2纳米管的响应面实验设计

材料导报

2019, Vol. 33

Issue (Z2): 365-368

金属与金属基复合材料

用Ti板制备高比表面积TiO₂纳米管的响应面实验设计

程亮¹, 赵子龙²

1 山西经济管理干部学院,太原 030024;
2 重庆大学土木工程学院,重庆 400045

Experimental Design of Response Surface of TiO₂ Nanotubes with High SpecificSurface Area Prepared by Ti Plate

CHENG Liang¹, ZHAO Zilong²

1 Shanxi Institute of Economic Management, Taiyuan 030024;
2 School of Civil Engineering, Chongqing University, Chongqing 400045

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摘要本工作采用Ti板和Al箔为原料,通过阳极氧化法制备了高比表面积的TiO₂纳米管;介绍一种制备高比表面积纳米管的实验设计方法,通过控制氧化电压和离子液浓度的全因子实验设计拟合了模型参数,得出当氧化电压和乙二醇及氟化铵混合离子液浓度分别为70 V和9.25 g/L时,制得的TiO₂纳米管薄膜的比表面积最大,为51.165 m²/g。然后根据拟合模型进行了响应曲面设计,将纳米管薄膜的比表面积增大了3.1倍,为211.125 m²/g,并得出在纳米管壁上长出的微小颗粒的粒径为1~10 nm,这与大自然树干、树枝的垂直结构是一致的。

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关键词: 二氧化钛纳米管阳极氧化比表面积实验设计垂直结构

Abstract: TiO₂ nanotubes with high specific surface area were prepared by anodic oxidation using Ti plate and Al foil as raw materials. A method of experimental design was introduced. The model parameters were fitted by the full factor experimental design of control voltage and ionic liquid concentration. The TiO₂ nanotube film with the largest specific surface area was found at 70 V and 9.25 g/L, which was 51.165 m²/g. Then response surface design was carried out according to the fitting model. The specific surface area of the nanotube film was increased by 3.1 times to 211.125 m²/g. It was found that tiny particles grew on the wall of the nanotube, ranging from 1 to 10 nm, which was consistent with the vertical structure of natural tree trunk branches.

Key words: TiO₂ nanotubes anodic oxidation specific surface area design of experiment vertical structure

出版日期: 2019-11-25 发布日期: 2019-11-25

ZTFLH:

TQ134

基金资助: 中国(重庆)新加坡博士后国际培训交流项目([2017]78; [2017]154)

通讯作者: 94583374@qq.com

作者简介: 程亮,山西经济管理干部学院讲师。2002年9月至2006年6月,在西南交通大学获得电子科学与技术专业工学学士学位。2006年9月至2009年6月,在电子科技大学获得微电子学与固体电子学专业工学硕士学位。以第一作者在国内外学术期刊上发表论文10余篇,授权国家专利2项。研究工作主要围绕国家重点发展的纳米材料及半导体材料,开展关于半导体材料加工工艺以及纳米材料的基础理论和应用研究。
赵子龙,博士,重庆大学土木工程学院博士后。2018年4月至2019年5月在新加坡南洋理工大学访问纳米功能材料的制备。以第一作者或通讯作者在国内外学术期刊上发表论文20余篇,其中SCI收录8篇,授权国家专利1项。研究工作主要围绕国家重点发展的纳米材料及半导体材料,主要方向为金属材料的纳米强韧化和表面腐蚀防护、纳米功能材料的制备技术。

引用本文:

程亮, 赵子龙. 用Ti板制备高比表面积TiO₂纳米管的响应面实验设计[J]. 材料导报, 2019, 33(Z2): 365-368.
CHENG Liang, ZHAO Zilong. Experimental Design of Response Surface of TiO₂ Nanotubes with High SpecificSurface Area Prepared by Ti Plate. Materials Reports, 2019, 33(Z2): 365-368.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2019/V33/IZ2/365

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