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《材料导报》期刊社  2017, Vol. 31 Issue (6): 38-44    https://doi.org/10.11896/j.issn.1005-023X.2017.06.009
  材料研究 |
马尾藻基高比表面积活性炭的制备及表征
李诗杰, 韩奎华, 韩旭东, 路春美
山东大学能源与动力工程学院, 济南 250061
Preparation and Characterization for High Specific Surface Area
Activated Carbon from Gulfweed
LI Shijie, HAN Kuihua, HAN Xudong, LU Chunmei
School of Energy and Power Engineering, Shandong University, Jinan 250061
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摘要 以马尾藻为原料,采用KOH活化法制备高比表面积活性炭。探索制备马尾藻基活性炭的实验方案和最佳工艺条件。采用正交实验法研究了炭化温度、炭化时间、低温活化温度、低温活化时间和浸渍时间对制得活性炭比表面积和孔容的影响。采用N2吸附、SEM表征考察了活性炭的孔隙结构和表面形貌。通过正交实验法分析发现,制备马尾藻基高比表面积活性炭的最佳工艺条件为:炭化温度600 ℃,炭化时间180 min,低温活化温度400 ℃,低温活化时间45 min,浸渍时间2 h。在16组实验条件下,制备的活性炭比表面积最大为3 122 m2/g,所有样品的孔径几乎全部分布在6 nm以内。
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李诗杰
韩奎华
韩旭东
路春美
关键词:  马尾藻  KOH活化法  高比表面积活性炭  孔隙结构    
Abstract: High specific surface area activated carbons were prepared by chemical activation of gulfweed with KOH as a chemical activation agent. Orthogonal experiment was adopted to discuss the influences of carbonization temperature, carbonization time, pre-activating temperature, pre-activating time and impregnation time on products′ specific surface area and pore volume, by conducting the characterizations for pore structure and surface morphology through N2 adsorption and SEM. From orthogonal experiment results, the optimum preparation conditions can be fixed as: carbonization temperature 600 ℃, carbonization time 180 min, pre-activating temperature 400 ℃, pre-activating time 45 min and impregnation time 2 h. The biggest specific surface area of the as-synthesized activated carbons in this work was 3 122 m2/g, and the pore sizes mainly concentrated within 6 nm.
Key words:  gulfweed    KOH activation method    high specific surface area activated carbon    pore structure
               出版日期:  2017-03-25      发布日期:  2018-05-02
ZTFLH:  TB34  
基金资助: 国家自然科学基金(51206096);山东大学基本科研业务费专项资金(2016JC005)
通讯作者:  韩奎华:男,1978年生,博士,副教授,研究方向为生物质热转化,E-mail:hankh@163.com   
作者简介:  李诗杰:男,1990年生,博士研究生,研究方向为生物质热转化,E-mail:675767978@163.com
引用本文:    
李诗杰, 韩奎华, 韩旭东, 路春美. 马尾藻基高比表面积活性炭的制备及表征[J]. 《材料导报》期刊社, 2017, 31(6): 38-44.
LI Shijie, HAN Kuihua, HAN Xudong, LU Chunmei. Preparation and Characterization for High Specific Surface Area
Activated Carbon from Gulfweed. Materials Reports, 2017, 31(6): 38-44.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.06.009  或          http://www.mater-rep.com/CN/Y2017/V31/I6/38
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